Silver catalyst

• US 5,407,888 A
• Filed: 05/10/1993
• Issued: 04/18/1995
• Est. Priority Date: 05/12/1992
• Status: Expired due to Fees

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Plueckhan, Juergen, Boehning, Karl-Heinz, Mross, Wolf D., Gallei, Ewald, Boeck, Stefan, Herzog, Klaus
• Primary Examiner(s): MCFARLANE, ANTHONY R
• Application Number:
  US08/059,538
• Time in Patent Office: 708 Days
• Field of Search: 502/371, 502/344, 502/348
• US Class Current: 502/317
• CPC Class Codes: B01J 23/687 with tungsten
• CPC Class Codes: C07D 301/10 with catalysts containing silver or gold

Abstract

A silver catalyst containing one or more alkali metals and also tungsten as promotors for the direct oxidation of ethylene with oxygen to form ethylene oxide, on a porous support substantially consisting of α-aluminum oxide and having a specific surface area (BET) of from 0.3 to 3 m² /g, which contains tungsten in a concentration of from 60 to 330 ppmwt, based on the total catalyst, per m² of surface area for each gram of supporting material.

Claims

1. An improved catalyst in which silver is applied to an aluminum oxide support for the direct oxidation of ethylene with oxygen to form ethylene oxide which comprises:

a catalyst consisting essentially of silver together with at least one alkali metal as a first promoter and tungsten as a second promoter applied to a porous support substantially consisting of α

-aluminum oxide having a specific surface area (BET) of from 0.3 to 3 m² /g, the amount of said tungsten applied to the support being from 60 to 280 ppmwt, based on the total catalyst, per m² of surface area for each gram of said support.

2. An improved catalyst as claimed in claim 1, wherein the silver content, based on the total catalyst, is from 10 to 30% by weight.

3. An improved catalyst as claimed in claim 1, wherein the alkali metal is selected from the group consisting of lithium, rubidium, cesium and mixtures thereof.

4. An improved catalyst as claimed in claim 1, wherein the alkali metal is a mixture of lithium and cesium.

5. An improved catalyst as claimed in claim 1, wherein the content of rubidium, cesium or mixtures thereof is from 200 to 2000 ppmwt and the content of lithium is from 100 to 1000 ppmwt, based in each case on the total catalyst.

6. An improved catalyst as claimed in claim 1, wherein the purity of the α

-aluminum oxide support is more than 99 wt %.

7. An improved catalyst as claimed in claim 1, wherein the purity of the α

-aluminum oxide support is more than 99.5 wt %.

8. An improved catalyst as claimed in claim 7, wherein the α

-aluminum oxide support has a specific surface area (BET) of from 0.5 to 2.0 m² /g.