Light-emitting device of gallium nitride compound semiconductor

• US 5,408,120 A
• Filed: 01/22/1993
• Issued: 04/18/1995
• Est. Priority Date: 07/23/1992
• Status: Expired

• Current Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho (Toyota Motor Corporation), Toyoda Gosei Company Limited (Toyota Motor Corporation)
• Original Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho (Toyota Motor Corporation), Toyoda Gosei Company Limited (Toyota Motor Corporation)
• Inventors: Manabe, Katsuhide, Hashimoto, Masafumi, Tamaki, Makoto, Kotaki, Masahiro
• Primary Examiner(s): James, Andrew J.
• Assistant Examiner(s): ARROYO, TERESA M
• Application Number:
  US08/006,301
• Time in Patent Office: 816 Days
• Field of Search: 257/431, 257/103, 257/76, 257/94, 257/189, 257/200, 257/201, 257/86, 257/613, 257/615, 257/21, 257/22, 257/11, 257/453, 257/745, 257/766
• US Class Current: 257/431
• CPC Class Codes: H01L 33/0037 having a MIS barrier layer
• CPC Class Codes: H01L 33/32 containing nitrogen
• CPC Class Codes: H01L 33/38 with a particular shape
• CPC Class Codes: H01L 33/382 the electrode extending partially in or entirely through the semiconductor body
• CPC Class Codes: H01L 33/40 Materials therefor

Abstract

A light-emitting diode of GaN compound semiconductor emits a blue light from a plane rather than dots for improved luminous intensity. This diode includes a first electrode associated with a high-carrier density n⁺ layer and a second electrode associated with a high-impurity density i_H -layer. These electrodes are made up of a first Ni layer (110 Å thick), a second Ni layer (1000 Å thick), an Al layer (1500 Å thick), a Ti layer (1000 Å thick), and a third Ni layer (2500 Å thick). The Ni layers of dual structure permit a buffer layer to be formed between them. This buffer layer prevents the Ni layer from peeling. The direct contact of the Ni layer with GaN lowers a drive voltage for light emission and increases luminous intensity.

Claims

1. A light-emitting device of gallium nitride compound semiconductor material comprising:

an n-layer of n-type gallium nitride compound semiconductor material (Al_x Ga_1-x N, x≧

0); and

an i-layer of i-type gallium nitride compound semiconductor material (Al_x Ga_1-x N, x≧

0) doped with a p-type impurity;

wherein a first electrode layer including Ni is formed in contact with said i-layer and functions as an electrode therefore; and

wherein said first electrode layer is a multi-layer structure having a first Ni layer of predetermined thickness formed over said i-layer, a second Ni layer which is thicker than said first Ni layer and formed thereon, an Al layer formed over said second Ni layer, a Ti layer formed over said Al layer, and a third Ni layer which is thicker than said first Ni layer formed over said Ti layer.

2. A light-emitting device of gallium nitride compound semiconductor material comprising:

an n-layer of n-type gallium nitride compound semiconductor (Al_x Ga_1-x N, x≧

0) material; and

an i-layer of i-type gallium nitride compound semiconductor (Al_x Ga_1-x N, x≧

0) material doped with a p-type impurity;

wherein each of said n-layer and said i-layer include respective electrodes formed on a same relative surface, the electrode for said i-layer being composed of at least one layer with each said at least one layer being made of one of Ni, Ag, Ti, an alloy including Ni, an alloy including Ag, and an alloy including Ti; and

wherein the electrode for said i-layer has an over layer formed thereon which is made of one of Al and an alloy containing Al.

3. A light-emitting device of gallium nitride compound semiconductor, comprising:

at least two layers of gallium nitride compound semiconductor material (Al_x Ga_1-x N, x≧

0);

a first electrode layer for one layer of said at least two layers; and

a second electrode layer for another of said at least two layers;

said first and second electrode layers provide an improved luminous intensity of said light-emitting device;

wherein at least one layer of said first and second electrode layers includes a contact layer made of one of Ni, Ag, an alloy including Ni, an alloy including Ag, and an alloy including Ti, said contact layer being directly contacted with any of said at least two layers of gallium nitride compound semiconductor material (Al_x Ga_1-x N, x≧

0).

4. A light-emitting device of gallium nitride compound semiconductor according to claim 3, wherein said contact layer of said first electrode layer is uniformly formed on a light emitting surface of said one layer, said one layer being an i-layer of semi-insulation doped with a p-type impurity and said another layer being an n-layer with n-type conduction.

5. A light-emitting device of gallium nitride compound semiconductor according to claim 3, wherein said second electrode layer includes a contact layer made of one of Ni, Ag, an alloy including Ni, an alloy including Ag, and an alloy including Ti, said contact layer being directly contacted with said another layer and said another layer being an n-layer with n-type conduction.

6. A light-emitting device of gallium nitride compound semiconductor according to claim 3, wherein said first electrode layer is a multi-layer structure having a first Ni layer of predetermined thickness formed over said one layer, a second Ni layer which is thicker than said first Ni layer and formed thereon, an Al layer formed over said second Ni layer, a Ti layer formed over said Al layer, and a third Ni layer which is thicker than said first Ni layer formed over said Ti layer.

7. A light-emitting device of gallium nitride compound semiconductor according to claim 3, wherein at least one layer of said first and second electrode layers has an over layer which is made of one of Ni, Ag, Ti, an alloy including Ni, an alloy including Ag, and an alloy including Ti.

8. A light-emitting device of gallium nitride compound semiconductor material according to claim 4, wherein at least one layer of said first and second electrode layers has an over layer which is made of one of Ni, Ag, Ti, an alloy including Ni, an alloy including Ag, and an alloy including Ti.

9. A light-emitting device of gallium nitride compound semiconductor according to claim 3, wherein at least one layer of said first and second electrode layers has over layer formed thereon which is made of one of Al and an alloy containing Al.

10. A light-emitting device of gallium nitride compound semiconductor according to claim 4, wherein at least one layer of said first and second electrode layers has over layer formed thereon which is made of one of Al and an alloy containing Al.

11. A light-emitting device of gallium nitride compound semiconductor according to claim 7, wherein at least one layer of said first and second electrode layers has over layer formed thereon which is made of one of Al and an alloy containing Al.

12. A light-emitting device of gallium nitride compound semiconductor according to claim 8, wherein at least one layer of said first and second electrode layers has over layer formed thereon which is made of one of Al and an alloy containing Al.

13. A light-emitting device of gallium nitride compound semiconductor according to claim 4, wherein said second electrode layer is made of one of Al and an alloy containing Al, and said first electrode has an over layer which is made of one of Ni, Ag, Ti, an alloy including Ni, an alloy including Ag, and an alloy including Ti.

14. A light-emitting device of gallium nitride compound semiconductor material according to claim 4, wherein said first electrode layer is a multi-layer structure having a first Ni layer of predetermined thickness formed over said i-layer, a second Ni layer which is thicker than said first Ni layer and formed thereon, an Al layer formed over said second Ni layer, a Ti layer formed over said Al layer, and a third Ni layer which is thicker than said first Ni layer formed over said Ti layer.