Mercury removal apparatus and method

• US 5,409,522 A
• Filed: 04/20/1994
• Issued: 04/25/1995
• Est. Priority Date: 04/20/1994
• Status: Expired due to Term

• Current Assignee: ADA Technologies, Inc.
• Original Assignee: ADA Technologies, Inc.
• Inventors: Hyatt, David E., Durham, Michael D., Stewart, Robin M., Schlager, Richard J.
• Primary Examiner(s): ROSENBERG, PETER
• Application Number:
  US08/230,055
• Time in Patent Office: 370 Days
• Field of Search: 75/670, 423/210, 210/65
• US Class Current: 75/670
• CPC Class Codes: B01D 2253/306 Surface area, e.g. BET-specific surface
• CPC Class Codes: B01D 2257/602 Mercury or mercury compounds
• CPC Class Codes: B01D 46/0036 by adsorption or absorption
• CPC Class Codes: B01D 46/10 Particle separators, e.g. dust precipitators, using filter plates, sheets or pads having plane surfaces
• CPC Class Codes: B01D 46/2425 characterized by parameters related to the physical properties of the honeycomb structure material
• CPC Class Codes: B01D 46/2429 of the honeycomb walls or cells
• CPC Class Codes: B01D 46/24492 Pore diameter
• CPC Class Codes: B01D 46/24494 Thermal expansion coefficient, heat capacity or thermal conductivity
• CPC Class Codes: B01D 46/2451 characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
• CPC Class Codes: B01D 46/2482 Thickness, height, width, length or diameter
• CPC Class Codes: B01D 46/2484 Cell density, area or aspect ratio
• CPC Class Codes: B01D 46/44 controlling filtration
• CPC Class Codes: B01D 46/62 connected in series
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: B01D 53/64 Heavy metals or compounds thereof, e.g. mercury

Abstract

The present invention discloses an apparatus and process for removing particulate material and mercury-containing compounds from a gas stream. The apparatus includes a particulate removal means to remove the particulate material and a mercury collection means to remove the mercury-containing compounds. The apparatus can selectively remove particulate material and mercury-containing compounds which may be disposed of separately. The mercury collection means is positioned downstream of the particulate removal means and includes a regenerable sorbent. The sorbent is regenerated by elevating the temperature of the sorbent to release the mercury-containing compounds from the sorbent.

Claims

1. A system for removing particulate material and mercury-containing compounds from an input gas stream, comprising:

channel means for defining the flow of the input gas stream between an inlet and an outlet of the channel means;

particulate removal means positioned across the input gas stream in the channel means for removing the particulate material from the input gas stream;

mercury collection means for removing the mercury-containing compounds from the input gas stream, the mercury collection means being positioned downstream of the particulate removal means within a defined region of the channel means and including a mercury collection surface;

means for selectively elevating the temperature within the defined region to release the mercury-containing compounds from the collection surface, the means for selectively elevating the temperature being in operative contact with the defined region; and

means for removing the mercury-containing compounds from the defined region after the mercury-containing compounds are released from the collection surface.

2. The system as claimed in claim 1, wherein:

the mercury-containing compounds are selected from the group consisting of elemental mercury, mercuric chloride, organomercuric compounds, and mixtures thereof.

3. The system as claimed in claim 1, wherein:

the particulate removal means is a filter having a pore size less than about 5.0 microns.

4. The system as claimed in claim 1, wherein:

the particulate removal means is composed substantially of a material that is thermally stable at temperatures no less than about 800°

F.

5. The system as claimed in claim 1, wherein:

the particulate removal means is composed substantially of a material selected from the group consisting of ceramics, glass bonded ceramics, glasses, sintered metals, cermets, resins or organic polymers, and mixtures thereof.

6. The system as claimed in claim 1, wherein:

the particulate removal means is positioned within the defined region.

7. The system as claimed in claim 1, wherein:

the mercury collection surface has a mercury adsorptive capacity no less than about 0.1 microgram/cm².

8. The system as claimed in claim 1, wherein:

the mercury collection surface has a mercury adsorption temperature that is no less than about 500°

F.

9. The system as claimed in claim 1, wherein:

the mercury collection surface has an ability to be regenerated no less than about 10 times with no more than a 50% decrease in mercury adsorptive capacity.

10. The system as claimed in claim 1, wherein:

the mercury collection surface has a thickness ranging from about 5 to about 500 angstroms.

11. The system as claimed in claim 1, wherein:

the mercury collection surface includes a metal selected from the group consisting of gold, silver, cesium, sodium, palladium, platinum, potassium, copper, and mixtures thereof.

12. The system as claimed in claim 1, wherein:

the pressure drop across the mercury removal means is no less than about 1.0 psi.

13. The system as claimed in claim 1, wherein:

the mercury collection means contacts a surface of the particulate removal means.

14. The system as claimed in claim 1, wherein:

the mercury collection means is defined by separate mercury collection surfaces on separate carriers.

15. The system as claimed in claim 14, wherein:

the mercury collection means comprises a bed of separate mercury collection surfaces on separate carriers.

16. The system as claimed in claim 14, wherein:

the carrier has a surface area from about 1 to about 100 m² /gram.

17. The system as claimed in claim 14, wherein:

the carrier has a coefficient of thermal expansion less than about 1×

10^-5 cm/cm.

18. The system as claimed in claim 14, wherein:

the carrier has an average size from about 0.1 to about 10 mm.

19. The system as claimed in claim 14, wherein:

the carrier is thermally stable at temperatures below about 800°

F.

20. The system as claimed in claim 14, wherein:

the carrier is selected from the group consisting of carbons, zeolites, ceramics, spun materials, metal sinters, aluminas, and mixtures thereof.

21. The system as claimed in claim 14, wherein:

the separate carriers are supportably engaged by a surface of the particulate removal means.

22. The system as claimed in claim 1, wherein:

the particulate removal means includes a plurality of first and second interconnected channels extending longitudinally relative to the direction of flow of the input gas stream, the first interconnected channels having an inlet for the input gas stream and a porous surface to remove particulate materials from the input gas stream to yield a treated gas stream and the second interconnected channels having an outlet to discharge the treated gas stream.

23. The system as claimed in claim 22, wherein:

the mercury collection means is disposed within the second interconnected channels.

24. The system as claimed in claim 22, wherein:

the porous wall separates the first and second interconnected channels and the mercury collection means is located adjacent to the porous wall.

25. The system as claimed in claim 22, wherein:

the mercury collection means is disposed within the porous wall.

26. The system as claimed in claim 22, wherein:

the mercury collection means is removably disposed within the second interconnected channels and the outlet of the second interconnected channels includes retaining means for holding the mercury collection means in the second interconnected channels.

27. The system as claimed in claim 26, wherein:

the retaining means has a plurality of pores having a size smaller than the separate carriers.

28. The system as claimed in claim 1, wherein:

the means for selectively elevating the temperature within the defined region includes a heater in contact with at least one of the following;

the channel means, the particulate removal means, and the mercury collection means.

29. The system as claimed in claim 1, wherein:

the means for removing the mercury-containing compounds from the defined region comprises an injection means for injecting a carrier gas into the defined region to entrain the mercury-containing compounds therein and a means for removing the carrier gas from the defined region.

30. The system as claimed in claim 1, wherein:

the mercury-containing compounds released from the mercury collection surface are substantially elemental mercury vapor;

and further comprising;

mercury recovery means for recovering elemental mercury released from the mercury collection surface, the mercury recovery means including a condensation surface having a temperature no more than the dew point of the elemental mercury vapor.

31. A method for removing particulate material and mercury-containing compounds from an input gas stream, comprising the steps of:

directing the input gas stream containing the particulate material and mercury-containing compounds through a particulate removal device to collect the particulate material and provide a treated gas stream with a reduced content of the particulate material;

contacting the treated gas stream with a mercury collection surface;

adsorbing the mercury-containing compounds on the mercury collection surface to provide an output gas stream;

elevating the temperature of the mercury collection surface to release the mercury-containing compounds from the mercury collection surface; and

collecting the mercury-containing compounds released from the mercury collection surface.

32. The method as claimed in claim 31, wherein the adsorbing step comprises:

amalgamating elemental mercury with a metal selected from Groups IA, IB and III of the Periodic Table of Elements.

33. The method as claimed in claim 31, wherein the elevating step comprises:

elevating the temperature from a first temperature of no more than about 600°

F. to a second temperature greater than the first temperature and no less than about 500°

F.

34. The method as claimed in claim 31, wherein the elevating step comprises:

sealing the mercury collection surface from the input gas stream; and

removing the mercury-containing compounds released from the mercury collection surface.

35. The method as claimed in claim 34, wherein the removing step comprises:

contacting the mercury-containing compounds released from the mercury collection surface with a carrier gas to remove the released mercury-containing compounds.

36. The method as claimed in claim 31, wherein:

the mercury-containing compounds released from the mercury collection surface substantially comprise elemental mercury vapor and the collecting step comprises condensing the elemental mercury vapor on a condensation surface.

37. The method as claimed in claim 36, wherein:

the condensation surface has a temperature no more than the dew point of the elemental mercury vapor.

38. The method as claimed in claim 36, wherein the collecting step comprises:

separating the mercury condensate from water that condensed with the mercury during the condensing step.

39. The method as claimed in claim 31, further comprising:

contacting the filter with a cleaning gas stream having a direction of flow opposite the direction of flow of the input gas stream to remove the particulate material from the filter.

40. The method as claimed in claim 31, wherein:

the mercury-containing compounds have a concentration in the input gas stream ranging from about 0.1 to about 1,000 ppb(v/v).