Highly available waste based nitrogen fertilizer

• US 5,411,568 A
• Filed: 05/25/1994
• Issued: 05/02/1995
• Est. Priority Date: 05/25/1994
• Status: Expired due to Fees

• Current Assignee: Duke Energy Royal, LLC (Duke Energy Corporation)
• Original Assignee: Harmony Products, Inc. (Environmental Fertilizer Corp.)
• Inventors: Moore, William P.
• Primary Examiner(s): Lander, Ferris
• Application Number:
  US08/249,223
• Time in Patent Office: 342 Days
• Field of Search: 71/1, 71/11, 71/22, 71/28-30, 71/64.01, 71/64.03, 71/64.06, 71/64.11, 71/64.13
• US Class Current: 71/22
• CPC Class Codes: C05C 9/02 containing urea-formaldehyde condensates
• CPC Class Codes: C05F 3/00 Fertilisers from human or animal excrements, e.g. manure
• CPC Class Codes: C05F 7/00 Fertilisers from waste water, sewage sludge, sea slime, ooze or similar masses
• CPC Class Codes: C05G 1/00 Mixtures of fertilisers belonging individually to different subclasses of C05
• CPC Class Codes: Y02P 60/21 Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures

Abstract

A new method of preparing granular slow release nitrogen fertilizer, exhibiting substantially complete nitrogen availability as a plant nutrient, from nitrogenous organic wastes, such as animal excretia, by coreacting particulate dry conditioned nitrogenous organic waste and reactive ureaformaldehyde oligomer; and the slow release fertilizer exhibiting improved nitrogen availability prepared by the new method. The preconditioning of the waste and the preparation of the reactive oligomer are arranged so that the method for forming the new composition is effectively carried out in a damp dry, free flowing particulate system. Parameters are provided for: dry conditioning the wastes, oligomer forming, coreacting, and granulating.

Claims

1. A method of preparing granular slow release nitrogen fertilizer, exhibiting substantially complete nitrogen availability, by coreacting dry conditioned nitrogenous particulate wastes, and reactive ureaformaldehyde oligomer as free flowing solids, the method comprising:

(a) dry conditioning an organic nitrogenous waste by drying and comminuting until it forms a mass of individual particles, comprising between 1 and 25 percent moisture, and between 1 and 13 percent nitrogen, and exhibits properties of tumbling freely in a rotating cylinder and passing through a U.S. Standard 4 Mesh Screen;

(b) forming a reactive ureaformaldehyde liquid oligomer by heating aqueous urea and formaldehyde combined in a molecular ratio between 1.3 and 3.0 to 1, at a pH between 5 and 8, at a temperature between 40 and 95°

C., until the liquid oligomer is sufficiently reactive to solidify in a period of time between 1 and 20 minutes when heated to 105°

C.;

(c) charging the dry conditioned organic nitrogenous particulate waste to a cylinder rotating around its center axis at a speed sufficient to form the waste into granules, while concomitantly adding to the waste an amount of reactive ureaformaldehyde liquid oligomer sufficient to provide between 15 and 85 percent of the nitrogen of the fertilizer, and continuing to rotate the cylinder until the reactive oligomer is evenly distributed in the waste granules;

(d) initiating the coreaction of the dry conditioned nitrogenous waste and the reactive ureaformaldehyde oligomer by admixing therewith sufficient mineral acid in the rotating cylinder to provide therein a pH between 1.5 and 6.5, and heating the admixture to a temperature between 45 and 110°

C.;

(e) continuing the coreaction until between 35 and 75 percent of the nitrogen is insoluble in water; and

(f) neutralizing the coreacted waste and ureaformaldehyde oligomer to a pH between 6 and 8 and cooling to a temperature lower than 45°

C. after a coreaction time between 4 and 30 minutes, while the availability of the slow release nitrogen is substantially complete.

2. The method of claim 1 wherein the organic nitrogenous wastes are animal excretia selected from the group consisting of sewage sludge, composted sewage sludge, industrial waste solids, poultry waste, composted poultry waste, municipal waste solids, and combinations thereof.

3. The method of claim 1 wherein the dry conditioned nitrogenous waste and the reactive ureaformaldehyde liquid oligomer are charged to the rotating cylinder and coreacted in a continuous manner.

4. The method of claim 1 wherein the dry conditioned nitrogenous waste comprises between 10 and 25 percent moisture, and on a dry basis between 2 and 6 percent nitrogen, and is sufficiently fine to substantially pass through a U.S. Standard 6 Mesh Screen.

5. The method of claim 1 wherein the reactive ureaformaldehyde oligomer is formed by heating aqueous urea and formaldehyde combined in a molecular ratio between 1.5 and 2.0 to 1.0 at a temperature between 60 and 90°

C., until the liquid oligomer is sufficiently reactive to solidify in a period of time between 4 and 8 minutes when heated to 105°

C.

6. The method of claim 1 wherein ureaformaldehyde concentrate is used as the source of the requisite amount of formaldehyde in preparing the reactive ureaformaldehyde oligomer.

7. The method of claim 1 wherein the granulating cylinder rotating around its center axis is arranged with its center axis in a horizontal configuration, exhibits an axis length to cylinder diameter ratio between 3 and 10, and is operated at a cylinder rim speed between 0.2 and 2.0 meters per second.

8. The method of claim 1 wherein the organic waste granule formation, the blending to evenly distribute the reactive oligomer in the waste granules, the coreaction, and the neutralization are carried out in a mechanically fluidized cylinder.

9. The method of claim 1 wherein the amount of reactive ureaformaldehyde liquid oligomer is sufficient to provide between 40 and 80 percent of the fertilizer nitrogen.

10. The method of claim 1 wherein sufficient mineral acid is admixed with organic waste and the liquid oligomer to provide a pH between 2.0 and 4.0 in the admixture and wherein the admixture is heated to a temperature between 70 and 95°

C.

11. The method of claim 1 wherein the mineral acid is selected from the group consisting of phosphoric acid, sulfuric acid, nitric acid, polyphosphoric acid, ammonium acid sulfate, magnesium chloride and hydrochloric acid.

12. The method of claim 1 wherein the coreaction is continued until between 45 and 70 percent of the fertilizer nitrogen is insoluble in water.

13. The method of claim 1 wherein the coreacted organic nitrogenous waste and the ureaformaldehyde oligomer is neutralized to a pH between 6.5 and 7.2, and cooled to a temperature lower than 45°

C after a coreaction time between 10 and 20 minutes while water insoluble nitrogen Availability Index is between 60 and 95.

14. The method of claim 1 wherein other primary nutrients are added to the dry conditioned nitrogenous organic wastes, the primary nutrients being selected from the group consisting of triple superphosphate, ammonium phosphate, phosphate rock, potassium chloride, potassium sulfate, potassium nitrate, and sunflower seed ash.

15. The method of claim 1 wherein secondary and micronutrients are added to the dry conditioned nitrogenous organic waste, the secondary and micronutrients being selected from the group consisting of salts of iron, zinc, manganese, copper, and magnesium.

16. The improved granular slow release nitrogen fertilizer composition prepared by the method of claim 1 which provides slow release nitrogen substantially completely available for plant nutrition.

17. A continuous method of preparing spheroid controlled release nitrogen fertilizer exhibiting substantially complete nitrogen availability in one growing season, by coreacting dry conditioned nitrogenous animal excretia and reactive ureaformaldehyde liquid oligomer, the method comprising:

(a) dry conditioning the nitrogenous animal excretia by drying and comminuting until a mass of individual, free flowing, particles are formed comprising between 10 and 20 percent moisture and between 2 and 5 percent nitrogen, and exhibiting properties of tumbling freely in a rotating cylinder and passing through a U.S. Standard 6 Mesh Screen;

(b) forming a reactive ureaformaldehyde liquid oligomer by heating aqueous urea and formaldehyde combined in a molecular ratio between 1.3 and 2.0 at a temperature between 1.5 and 2.0 at a temperature between 60 and 95°

C., until the liquid oligomer is sufficiently reactive to solidify in a period of time between 4 and 8 minutes when heated to 105°

C.;

(c) continuously charging the dry conditioned animal excretia to a rotating horizontal cylinder, exhibiting a length to diameter ratio between 3 and 6, rolling said excretia therein at a cylinder rim speed between 0.2 and 2.0 meters per second to form the excretia into spheroids, concomitantly applying to the excretia granules an amount of reactive ureaformaldehyde oligomer sufficient to provide between 45 and 70 percent of the fertilizer nitrogen, and continuing to rotate the cylinder until the reactive oligomer is evenly distributed in the excretia spheroids;

(d) initiating the coreaction of the dry conditioned animal excretia and the reactive ureaformaldehyde oligomer by continuously admixing therewith sufficient mineral acid to provide a pH in the rotating cylinder between 2.0 and 4.0, and heating to a temperature between 70 and 90°

C.;

(e) continuing the coreaction until between 45 and 70 percent of the fertilizer nitrogen is insoluble in water;

(f) neutralizing the coreacted animal excretia and ureaformaldehyde oligomer spheroids to a pH between 6.5 and 7.2 by continuously admixing in the rotating cylinder sufficient base, and cooling to a temperature lower than 45°

C. after a coreaction time between 10 and 20 minutes while the Availability Index of the nitrogen is between 65 and 85 percent.

18. The method of claim 17, wherein the neutralized coreacted excretia and oligomer spheroids are dried in an external dryer to a moisture content between 1 and 10 percent and screened, with fines recycled for continuous charging with the dry conditioned animal excretia to the rotating horizontal cylinder for inclusion in the coreacted granules.

19. The improved spheroid controlled release fertilizer composition exhibiting water insoluble nitrogen Availability Indices between 65 and 85 prepared from dry conditioned animal excretia and reactive ureaformaldehyde oligomer by the method of claim 17.