Apparatus for deposition of thin-film, solid state batteries

• US 5,411,592 A
• Filed: 06/06/1994
• Issued: 05/02/1995
• Est. Priority Date: 06/06/1994
• Status: Expired due to Term

• Current Assignee: ChevronTexaco Technology Ventures LLC (Chevron Corp.)
• Original Assignee: Ovonic Battery Company, Inc (BASF SE)
• Inventors: Ovshinsky, Herbert, Ovshinsky, Stanford R., Young, Rosa
• Primary Examiner(s): BUEKER, RICHARD R
• Application Number:
  US08/254,392
• Time in Patent Office: 330 Days
• Field of Search: 118/719, 118/50, 118/314, 118/325, 118/718, 429/162, 429/127, 204/298.25, 204/298.26
• US Class Current: 118/718
• CPC Class Codes: C23C 14/562 for coating elongated substrates
• CPC Class Codes: C23C 16/545 for coating elongated substrates
• CPC Class Codes: H01M 10/345 Gastight metal hydride accumulators
• CPC Class Codes: H01M 6/181 with polymeric electrolytes
• CPC Class Codes: H01M 6/188 Processes of manufacture
• CPC Class Codes: H01M 6/40 Printed batteries , e.g. thin film batteries
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

A multi-chambered deposition apparatus for depositing solid-state, thin-film battery materials onto substrate material. The apparatus minimally includes at least three distinct evacuable deposition chambers, which are physically interconnected in series. The first deposition chamber is adapted to deposit a layer of battery electrode material having a first polarity onto the substrate. The second deposition chamber is adapted to deposit a layer of solid-state electrolyte material onto the layer of battery electrode material deposited in the first chamber. The third deposition chamber is adapted to deposit a layer of battery electrode material having an opposite polarity from that deposited in the first chamber onto the solid-state electrolyte. The deposition chambers are interconnected by gas gates such that the substrate material is allowed to proceed from one deposition chamber to the next, while maintaining gaseous segregation between the chambers.

Claims

1. A multi-chambered deposition apparatus for depositing solid-state, thin-film battery materials onto substrate material, said apparatus including:

at least three distinct evacuable deposition chambers, said deposition chambers physically interconnected in series;

the first of said deposition chambers adapted to deposit battery electrode material having a first polarity onto the substrate;

the second of said deposition chambers adapted to deposit solid-state electrolyte material onto the battery electrode material deposited in the first chamber;

the third of said deposition chambers adapted to deposit battery electrode material of the opposite polarity from that deposited in the first chamber; and

at least two gas gates, each gas gate interconnecting two of said deposition chambers such that the substrate material is allowed to proceed from one deposition chamber to the next, while maintaining gaseous segregation between the chambers.

2. A deposition apparatus as in claim 1, further including an evacuable payout chamber, said payout chamber physically interconnected in series to said first deposition chamber and holding a roll of substrate material, which is unrolled and passed to said first deposition chamber;

and

a gas gate interconnecting said payout chamber and said first deposition chamber.

3. A deposition apparatus as in claim 2, further including an evacuable take-up chamber, said take-up chamber physically interconnected in series to said third deposition chamber and holding a take-up mandrel for the roll of substrate material upon which the solid-state battery material is deposited, the substrate passing from said third deposition chamber into said take-up chamber;

and

a gas gate interconnecting said take-up chamber and said third deposition chamber.

4. A deposition apparatus as in claim 3, wherein said deposition apparatus is adapted to deposit a plurality of solid state battery cells onto said substrate, and to that end, said first and said third deposition chambers and said payoff and take-up chambers are, respectively, reversible, such that when said roll of substrate material has undergone one pass through said deposition chambers, the direction of said substrate can be reversed and said substrate can undergo another pass through the deposition chambers, when this reversal occurs:

1) the take-up chamber becomes the payoff chamber;

2) the payoff chamber becomes the take-up chamber;

3) the third deposition chamber becomes the first deposition chamber and deposits said battery electrode material having said first polarity onto the substrate; and

4) the first deposition chamber becomes the third deposition chamber and deposits said opposite polarity battery electrode material onto the substrate.

5. A deposition apparatus as in claim 3, further including a fourth evacuable deposition chamber between said third deposition chamber and said take-up chamber, said fourth chamber being adapted to deposit a top conductive battery terminal upon the second battery electrode layer.

6. A deposition apparatus as in claim 4, further including a fourth evacuable deposition chamber between said first deposition chamber and said payoff chamber;

and a fifth evacuable deposition chamber between said third deposition chamber and said take-up chamber, said fourth and fifth deposition chambers being adapted to deposit current collector layers between the second electrode layer of a first deposited battery and the first electrode of the next deposited battery and a top conductive battery terminal upon the second battery electrode layer of the last deposited battery.

7. A deposition apparatus as in claim 1, further including an evacuable substrate insertion chamber, said insertion chamber physically interconnected in series to said first deposition chamber and adapted to hold one or more individual substrates and pass them to said first deposition chamber;

and

a gas gate interconnecting said insertion chamber and said first deposition chamber.

8. A deposition apparatus as in claim 7, further including an evacuable substrate retraction chamber, said retraction chamber physically interconnected in series to said third deposition chamber and adapted to hold one or more individual substrates and remove them from said third deposition chamber;

and

a gas gate interconnecting said retraction chamber and said third deposition chamber.

9. A deposition apparatus as in claim 8, further including an interconnective passageway connecting said retraction chamber and said insertion chamber such that the substrate may undergo multiple depositions by recycling the previously deposited substrate from the retraction chamber to the insertion chamber.

10. A deposition apparatus as in claim 8, further including a fourth evacuable deposition chamber between said third deposition chamber and said retraction chamber, said fourth chamber being adapted to deposit a top conductive battery terminal upon the second battery electrode layer.

11. A deposition apparatus as in claim 3, wherein said deposition apparatus is adapted to deposit a plurality of solid state battery cells onto said substrate, said payoff and take-up chambers are reversible so that when said roll of substrate material has undergone one pass through said deposition chambers, the direction of travel of said substrate can be reversed and said substrate can undergo another pass through the deposition chambers, to that end, two additional deposition chambers, identical to said first and said third deposition chambers, are included in the apparatus, the additional chambers are activated when the direction of travel of said roll of substrate material is reversed and the additional reverse direction deposition chambers are positioned on the opposite side of said second chamber from its forward direction counterpart.

12. A deposition apparatus as in claim 11, further including an additional set of evacuable deposition chambers, each chamber of said set being positioned on opposite sides of said second deposition chamber and adapted to deposit a conductive layer atop a deposited battery cell, one chamber is positioned to deposit the conductive layer when the substrate is traveling in the forward direction and the other to deposit the conductive layer when the substrate is traveling in the reverse direction.

13. A deposition apparatus as in claim 1, wherein said deposition chambers are adapted to deposit materials by at least one method selected from the group consisting of evaporation, chemical vapor deposition, physical vapor deposition, microwave plasma enhanced chemical vapor deposition, sputtering, laser ablation, spray coating, or plasma spraying.

14. A deposition apparatus as in claim 1, wherein said first deposition chamber is adapted to deposit a positive electrode material.

15. A deposition apparatus as in claim 1, wherein said first deposition chamber is adapted to deposit a negative electrode material.