Silicone polymer, paste-like silicone composition, and w/o-type cosmetic composition comprising the same

• US 5,412,004 A
• Filed: 02/25/1994
• Issued: 05/02/1995
• Est. Priority Date: 11/21/1991
• Status: Expired due to Term

• Current Assignee: KOSE Corporation, Shin-Etsu Chemical Company Limited
• Original Assignee: KOSE Corporation, Shin-Etsu Chemical Company Limited
• Inventors: Tachibana, Kiyomi, Sakuta, Koji, Isobe, Kenichi
• Primary Examiner(s): Marquis, Melvyn I.
• Application Number:
  US08/202,086
• Time in Patent Office: 431 Days
• Field of Search: 524/267, 524/379, 524/385, 524/389, 524/56, 524/58, 524/27, 514/844, 514/845, 514/846
• US Class Current: 524/27
• CPC Class Codes: A61K 8/06 Emulsions
• CPC Class Codes: A61K 8/064 Water-in-oil emulsions, e.g. Water-in-silicone emulsions
• CPC Class Codes: A61K 8/375 the alcohol moiety containing more than one hydroxy group
• CPC Class Codes: A61K 8/891 saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
• CPC Class Codes: A61K 8/894 modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
• CPC Class Codes: A61Q 1/02 Preparations containing skin colorants, e.g. pigments preparations in powder form A61Q1/12
• CPC Class Codes: A61Q 1/10 for eyes, e.g. eyeliner, mascara
• CPC Class Codes: A61Q 17/04 Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
• CPC Class Codes: C08G 77/46 containing polyether sequences
• CPC Class Codes: C08L 83/12 containing polyether sequences

Abstract

A silicone polymer, a paste-like silicone composition prepared by kneading the silicone polymer and a silicone oil under a shearing force, and a water-in-oil type cosmetic composition comprising the paste-like silicone composition as an oil phase component are disclosed. The silicone polymer is prepared by the addition polymerization of components comprising an organohydrogenpolysiloxane R¹_a R²_b H_c SiO.sub.(4-a-b-c)/2 (1) or R¹_f H_g SiO.sub.(4-f-g)/2 (2) and a polyoxyalkylene C_m H_2m-1 O(C₂ H₄ O)_h (C₃ H₆ O)_i C_m H_2m-l (A) or an organopolysiloxane R¹_j R⁴_k SiO.sub.(4-j-k)/2 (B) the components, including (1) or (A) as an essential component. The silicone polymer can swell in silicone oils and function as a viscosity increasing agent for silicone oils.

Claims

1. A water-in-oil cosmetic composition comprising:

(a) an oil phase component which comprises (i) a pasty silicone composition which can disperse water and (ii) silicic acid anhydride or hydrophobic silica, or both; and

(b) at least one water phase component comprising water and water soluble components;

wherein the pasty like silicone composition is prepared by kneading 100 parts by weight of a silicone polymer and 5 to 1,000 parts by weight of a silicone oil under a sufficient shearing force to produce a smooth and homogeneous outward appearance, and

wherein the silicone polymer is prepared by the addition polymerization of the following components (I) and (II);

(I) an organohydrogenpolysiloxane represented by the following formula (1),

space="preserve" listing-type="equation">R.sup.1.sub.a R.sup.2.sub.b H.sub.c SiO.sub.(4-a-b-c)/2 (

     1)

wherein

R¹ represents a substituted or unsubstituted alkyl, aryl, or aralkyl group having 1 to 18 carbon atoms, or a halogenated hydrocarbon group;

R² represents a group,

space="preserve" listing-type="equation">--C.sub.n H.sub.2n O(C.sub.2 H.sub.4 O).sub.d (C.sub.3 H.sub.6 O).sub.e R.sup.3 (

     3)

wherein

R³ is a hydrogen, a saturated aliphatic hydrocarbon group having 1 to 10 carbon atoms, or a group --(CO)--R⁵, wherein R⁵ is a saturated aliphatic hydrocarbon group having 1 to 5 carbon atoms,

d is an integer of 2 to 200, and

e is an integer of 0 to 200,

provided that d+e is 3 to 200, and n is 2 to 6;

a is a value satisfying inequality 1.0≦

a≦

2.5;

b is a value satisfying inequality 0.001≦

b≦

1.0; and

c is a value satisfying inequality 0.001≦

c≦

1.0;

or an organohydrogenpolysiloxane represented by the following formula (2),

space="preserve" listing-type="equation">R.sup.1.sub.f H.sub.g SiO.sub.(4-f-g)/2 (

     2)

wherein

R¹ is the same as defined in formula (1),

f is a value satisfying inequality 1.0≦

f≦

3.0,

g is a value satisfying inequality 0.001 ≦

g ≦

1.5;

or a mixture of said organohydrogenpolysiloxanes of formulas (1) and (2), and

(II) a polyoxyalkylene represented by the following formula (A),

space="preserve" listing-type="equation">C.sub.m H.sub.2m-1 O(C.sub.2 H.sub.4 O).sub.h (C.sub.3 H.sub.6 O).sub.i C.sub.m H.sub.2m-1 (A)

wherein

h is an integer of 2 to 200,

i is an integer of 0 to 200, provided that h+i is 3 to 200, and

m is 2 to 6,

or an organopolysiloxane represented by the following formula (B),

space="preserve" listing-type="equation">R.sup.1.sub.j R.sup.4.sub.k SiO.sub.(4-j-k)/2 (B)

wherein

R¹ is the same as defined in formula (1),

R₄ is a monovalent hydrocarbon group having an aliphatic unsaturated bond at the terminal thereof and containing 2 to 10 carbon atoms,

j is a value satisfying inequality 1.0≦

j≦

3.0, and

k is a value satisfying inequality 0.001≦

k≦

1.5,

or a mixture of the polyoxyalkylene of formula (A) and the organopolysiloxane of formula (B),

wherein at least one organohydrogenpolysiloxane of formula (1) or at least one polyoxyalkylene of formula (A) is contained as an essential component of the addition polymerization.

2. A water-in-oil cosmetic composition as claimed in claim 1, comprising from 0.01 to 10% of the oil phase components of said silicic acid anhydride or hydrophobic silica.

3. A water-in-oil cosmetic composition as claimed in claim 2 wherein the hydrophobic silica is trimethylsiloxylated silica, dimethylsiloxylated silica, octylsiloxylated silica or silicone oil treated silica.

4. A water-in-oil cosmetic composition comprising:

(a) an oil phase component which comprises (i) a pasty silicone composition which can disperse water; and

(ii) silicic acid anhydride or hydrophobic silica, or both; and

(b) at least one water phase component comprising water and water soluble components;

wherein the pasty silicone composition is prepared by kneading 100 parts by weight of a silicone polymer and 5 to 1,000 parts by weight of a silicone oil under a sufficient shearing force to produce a smooth and homogeneous outward appearance, and wherein the silicone polymer is prepared by the addition polymerization, in the presence of 3 to 200 parts by weight of a low viscosity silicone oil having a viscosity of 100 cS or lower at 25°

C. or a polyhydric alcohol, or both, of 100 parts by weight of components comprising,

(I) an organohydrogenpolysiloxane represented by the following formula (1),

space="preserve" listing-type="equation">R.sup.1.sub.a R.sup.2.sub.b H.sub.c SiO.sub.(4-a-b-c)/2 (

     1)

wherein

R¹ represents a substituted or unsubstituted alkyl, aryl, or aralkyl group having 1 to 18 carbon atoms, or a halogenated hydrocarbon group;

R² represents a group --C_n H_2n O(C₂ H₄ O)_d (C₃ H₆ O)_e R³

wherein

R³ is a hydrogen, a saturated aliphatic hydrocarbon group having 1 to 10 carbon atoms, or a group --(CO)--R⁵, wherein R⁵ is a saturated aliphatic hydrocarbon group having 1 to 5 carbon atoms,

d is an integer of 2 to 200,

e is an integer of 0 to 200,

provided that d+e is 2 to 200, and

n is 2 to 6;

a is a value satisfying inequality 1.0≦

a≦

2.5;

b is a value satisfying inequality 0.001≦

b≦

1.0; and

c is a value satisfying inequality 0.001≦

c≦

1.0;

or an organohydrogenpolysiloxane represented by the following formula (2),

space="preserve" listing-type="equation">R.sup.1.sub.f H.sub.g SiO.sub.(4-f-g)/2 (

     2)

wherein

R¹ is the same as defined in formula (1),

f is a value satisfying inequality 1.0≦

f≦

3.0, and

g is a value satisfying inequality 0.001≦

g≦

1.5;

or a mixture of said organohydrogenpolysiloxanes of formulas (1) and (2); and

(II) a polyoxyalkylene represented by the following formula (A)

space="preserve" listing-type="equation">C.sub.m H.sub.2m-1 O(C.sub.2 H.sub.4 O).sub.h (C.sub.3 H.sub.6 O).sub.i C.sub.m H.sub.2m-1 (A)

wherein

h is an integer of 2 to 200,

i is an integer of 0 to 200,

provided that h+i is 2 to 200, and

m is 2 to 6,

or an organopolysiloxane represented by the following formula (B),

space="preserve" listing-type="equation">R.sup.1.sub.j R.sup.4.sub.k SiO.sub.(4-j-k)/2 (B)

wherein

R¹ is the same as defined in formula (1),

R⁴ is a monovalent hydrocarbon group having an aliphatic unsaturated bond at the terminal thereof and containing 2 to 10 carbon atoms,

j is a value satisfying inequality 1.0≦

j≦

3.0, and

k is a value satisfying inequality 0.001≦

k≦

1.5,

or a mixture of the polyoxyalkylene of formula (A) and the organopolysiloxane of formula (B),

wherein at least one organohydrogenpolysiloxane of formula (1) or at least one polyoxyalkylene of formula (A) are contained as an essential component of the addition polymerization.

5. A water-in-oil cosmetic composition as claimed in claim 4 comprising from 0.01 to 10% in the oil phase components of said silica acid anhydride or hydrophobic silica.

6. A water-in-oil cosmetic composition as claimed in claim 5 wherein the hydrophobic silica is trimethylsiloxylated silica, dimethylsiloxylated silica, octylsiloxylated silica or silicone oil treated silica.

7. A water-in-oil cosmetic composition comprising:

(a) an oil phase component which comprises a pasty silicone composition which can disperse water; and

(b) water and a stabilizing effective amount of one or more components selected from the group consisting of saccharides, sugar alcohols, and inorganic salts, as water phase components;

wherein the pasty silicone composition is prepared by kneading 1 00 parts by weight of a silicone polymer and 5 to 1,000 parts by weight of a silicone oil under sufficient shearing force to produce a smooth and homogeneous outward appearance, and

wherein the silicone polymer is prepared by the addition polymerization of the following components (I) and (II);

(I) an organohydrogenpolysiloxane represented by the following formula (1),

space="preserve" listing-type="equation">R.sup.1.sub.a R.sup.2.sub.b H.sub.c SiO.sub.(4-a-b-c)/2 (

     1)

wherein

R¹ represents a substituted or unsubstituted alkyl, aryl, or aralkyl group having 1 to 18 carbon atoms, or a halogenated hydrocarbon group;

R₂ represents a group,

space="preserve" listing-type="equation">--C.sub.n H.sub.2n O(C.sub.2 H.sub.4 O).sub.d (C.sub.3 H.sub.6 O).sub.e R.sup.3 (

     3)

wherein

R³ is a hydrogen, a saturated aliphatic hydrocarbon group having 1 to 10 carbon atoms, or a group --(CO)--R⁵, wherein R⁵ is a saturated aliphatic hydrocarbon group having 1 to 5 carbon atoms,

d is an integer of 2 to 200, and

e is an integer of 0 to 200,

provided that d+e is 3 to 200, and n is 2 to 6;

a is a value satisfying inequality 1.0≦

a≦

2.5;

b is a value satisfying inequality 0.001≦

b≦

1.0; and

c is a value satisfying inequality 0.001≦

c≦

1.0;

or an organohydrogenpolysiloxane represented by the following formula (2),

space="preserve" listing-type="equation">R.sup.1.sub.f H.sub.g SiO.sub.(4-f-g)/2 (

     2)

wherein

R¹ is the same as defined in formula (1),

f is a value satisfying inequality 1.0≦

f≦

3.0,

g is a value satisfying inequality 0.001≦

g≦

1.5;

or a mixture of said organohydrogenpolysiloxanes of formulas (1) and (2), and

(II) a polyoxyalkylene represented by the following formula (A),

space="preserve" listing-type="equation">C.sub.m H.sub.2m-1 O(C.sub.2 H.sub.4 O).sub.h (C.sub.3 H.sub.6 O).sub.i C.sub.m H.sub.2m-1 (A)

wherein

h is an integer of 2 to 200,

i is an integer of 0 to 200, provided that h+i is 3 to 200, and

m is 2 to 6,

or an organopolysiloxane represented by the following formula (B),

space="preserve" listing-type="equation">R.sup.1.sub.j R.sup.4.sub.k SiO.sub.(4-j-k)/2 (B)

wherein

R¹ is the same as defined in formula (1),

R⁴ is a monovalent hydrocarbon group having an aliphatic unsaturated bond at the terminal thereof and containing 2 to 10 carbon atoms,

j is a value satisfying inequality 1.0≦

j≦

3.0, and

k is a value satisfying inequality 0.001≦

k≦

1.5,

or a mixture of the polyoxyalkylene of formula (A) and the organopolysiloxane of formula (B),

wherein at least one organohydrogenpolysiloxane of formula (1) or at least one polyoxyalkylene of formula (A) is contained as an essential component of the addition polymerization.

8. A water-in-oil cosmetic composition as claimed in claim 7 wherein the water phase component is glucose, fructose, galactose, xylose, maltose, sucrose, lactose, starch, dextrin, sorbitol, mannitol, maltitol, an inorganic salt selected from the group consisting of sodium, potassium, calcium, magnesium, and aluminum, or a zinc salt of hydrochloric acid, sulfuric acid, carbonic acid or nitric acid.

9. A water-in-oil cosmetic composition as claimed in claim 8 wherein the stabilizing effective amount is from 0.1 to 20% of the total amount of the oil phase components.

10. A water-in-oil cosmetic composition comprising:

(a) an oil phase component which comprises a pasty silicone composition which can disperse water; and

(b) water and one or more components selected from the group consisting of saccharides, sugar alcohols, and inorganic salts, as water phase components;

wherein the pasty silicone composition is prepared by kneading 100 parts by weight of a silicone polymer and 5 to 1,000 parts by weight of a silicone oil under sufficient shearing force to produce a smooth and homogeneous outward appearance, and

wherein the silicone polymer is prepared by the addition polymerization, in the presence of 3 to 200 parts by weight of a low viscosity silicone oil having a viscosity of 100 cS or lower at 25°

C. or a polyhydric alcohol, or both, of 100 parts by weight of components comprising,

(I) an organohydrogenpolysiloxane represented by the following formula (1),

space="preserve" listing-type="equation">R.sup.1.sub.a R.sup.2.sub.b H.sub.c SiO.sub.(4-a-b-c)/2 (

     1)

wherein

R¹ represents a substituted or unsubstituted alkyl, aryl, or aralkyl group having 1 to 18 carbon atoms, or a halogenated hydrocarbon group;

R² represents a group --C_n H_2n O(C₂ H₄ O)_d (C₃ H₆ O)_e R³

wherein

R³ is a hydrogen, a saturated aliphatic hydrocarbon group having 1 to 10 carbon atoms, or a group --(CO)--R⁵, wherein R⁵ is a saturated aliphatic hydrocarbon group having 1 to 5 carbon atoms,

d is an integer of 2 to 200,

e is an integer of 0 to 200,

provided that d+e is 2 to 200, and

n is 2 to 6;

a is a value satisfying inequality 1.0≦

a≦

2.5;

b is a value satisfying inequality 0.001≦

b≦

1.0; and

c is a value satisfying inequality 0.001≦

c≦

1.0;

or an organohydrogenpolysiloxane represented by the following formula (2),

space="preserve" listing-type="equation">R.sup.1.sub.f H.sub.g SiO.sub.(4-f-g)/2 (

     2)

wherein

R¹ is the same as defined in formula (1),

f is a value satisfying inequality 1.0≦

f≦

3.0, and

g is a value satisfying inequality 0.001≦

g≦

1.5;

or a mixture of said organohydrogenpolysiloxanes of formulas (1) and (2),

and

(II) a polyoxyalkylene represented by the following formula (A)

space="preserve" listing-type="equation">C.sub.m H.sub.2m-1 O(C.sub.2 H.sub.4 O).sub.h (C.sub.3 H.sub.6 O).sub.i C.sub.m H.sub.2m-1 (A)

wherein

h is an integer of 2 to 200,

i is an integer of 0 to 200,

provided that h+i is 2 to 200, and

m is 2 to 6,

or an organopolysiloxane represented by the following formula (B),

space="preserve" listing-type="equation">R.sup.1.sub.j R.sup.4.sub.k SiO.sub.(4-j-k)/2 (B)

wherein

R¹ is the same as defined in formula (1),

R⁴ is a monovalent hydrocarbon group having an aliphatic unsaturated bond at the terminal thereof and containing 2 to 10 carbon atoms,

j is a value satisfying inequality 1.0≦

j≦

3.0, and

k is a value satisfying inequality 0.001≦

k≦

1.5,

or a mixture of the polyoxyalkylene of formula (A) and the organopolysiloxane of formula (B),

wherein at least one organohydrogenpolysiloxane of formula (1) or at least one polyoxyalkylene of formula (A) are contained as an essential component of the addition polymerization.

11. A water-in-oil cosmetic composition as claimed in claim 10 wherein the water phase component is glucose, fructose, galactose, xylose, maltose, sucrose, lactose, starch, dextrin, sorbitol, mannitol, maltitol, an inorganic salt selected from the group consisting of sodium, potassium, calcium, magnesium, and aluminum, or a zinc salt of hydrochloric acid, sulfuric acid, carbonic acid or nitric acid.

12. A water-in-oil cosmetic composition as claimed in claim 11 wherein the stabilizing effective amount is from 0.1 to 20% of the total amount of the oil phase components.

13. A water-in-oil cosmetic composition comprising:

(a) an oil phase component which comprises a pasty silicone composition which can disperse water;

(b) at least one water phase component comprising water and water soluble components; and

a polyoxyalkylene-modified organopolysiloxane surface active agent

wherein the pasty silicone composition is prepared by kneading 100 parts by weight of a silicone polymer and 5 to 1,000 parts by weight of a silicone oil under sufficient shearing force to produce a smooth and homogenous outward appearance, and

wherein the silicone polymer is prepared by the addition polymerization of the following components (I) and (II);

(I) an organohydrogenpolysiloxane represented by the following formula (1),

space="preserve" listing-type="equation">R.sup.1.sub.a R.sup.2.sub.b H.sub.c SiO.sub.(4-a-b-c)/2 (1)

wherein

R¹ represents a substituted or unsubstituted alkyl, aryl, or aralkyl group having 1 to 18 carbon atoms, or a halogenated hydrocarbon group;

R² represents a group,

space="preserve" listing-type="equation">--C.sub.n H.sub.2n O(C.sub.2 H.sub.4 O).sub.d (C.sub.3 H.sub.6 O).sub.e R.sup.3 (

     3)

wherein

R³ is a hydrogen, a saturated aliphatic hydrocarbon group having 1 to 10 carbon atoms, or a group --(CO)--R⁵, wherein R⁵ is a saturated aliphatic hydrocarbon group having 1 to 5 carbon atoms,

d is an integer of 2 to 200, and

e is an integer of 0 to 200,

provided that d+e is 3 to 200, and n is 2 to 6;

a is a value satisfying inequality 1.0≦

a≦

2.5;

b is a value satisfying inequality 0.001≦

b≦

1.0; and

c is a value satisfying inequality 0.001≦

c≦

1.0;

or an organohydrogenpolysiloxane represented by the following formula (2),

space="preserve" listing-type="equation">R.sup.1.sub.f H.sub.g SiO.sub.(4-f-g)/2 (

     2)

wherein

R¹ is the same as defined in formula (1),

f is a value satisfying inequality 1.0≦

f≦

3.0,

g is a value satisfying inequality 0.001≦

g≦

1.5;

or a mixture of said organohydrogenpolysiloxanes of formulas (1) and (2), and

(II) a polyoxyalkylene represented by the following formula (A),

space="preserve" listing-type="equation">C.sub.m H.sub.2m-1 O(C.sub.2 H.sub.4 O).sub.h (C.sub.3 H.sub.6 O).sub.i C.sub.m H.sub.2m-1 (A)

wherein

h is an integer of 2 to 200,

i is an integer of 0 to 200, provided that h+i is 3 to 200, and

m is 2 to 6,

or an organopolysiloxane represented by the following formula (B),

space="preserve" listing-type="equation">R.sup.1.sub.j R.sup.4.sub.k SiO.sub.(4-j-k)/2 (B)

wherein

R¹ is the same as defined in formula (1),

R⁴ is a monovalent hydrocarbon group having an aliphatic unsaturated bond at the terminal thereof and containing 2 to 10 carbon atoms,

j is a value satisfying inequality 1.0≦

j≦

3.0, and

k is a value satisfying inequality 0.001≦

k≦

1.5,

or a mixture of the polyoxyalkylene of formula (A) and the organopolysiloxane of formula (B),

wherein at least one organohydrogenpolysiloxane of formula (1) or at least one polyoxyalkylene of formula (A) is contained as an essential component of the addition polymerization.

14. A water-in-oil cosmetic composition as claimed in claim 13, wherein the polyoxyalkylene-modified organopolysiloxane surfactant is:

a compound of formula (4);

##STR17## wherein;

R⁶ represents an alkyl group having 1-5 carbon atoms or a phenyl group;

R⁷ is a group --(CH₂)_r --O--(C₂ H₄ O)_s --(C3H₆ O)_t R¹⁰

wherein R¹⁰ is hydrogen or an alkyl group having from 1 to 5 carbon atoms;

r is a number from 1 to 5;

s is a number from 1-50; and

t is a number from 0-30;

R⁸ and R⁹ are the same as either R⁶ or R⁷ ;

is a number from 5 to 300; and

q is a number from 0 to 50, provided that when q is 0, at least one of R⁸ and R⁹ is the same as R⁷ and provided further that not all R⁶ s can be phenyl groups;

a compound of formula (5);

##STR18## wherein;

R⁶, R⁷, p and q are the same as defined above;

R¹¹ is an alkyl group having 2-20 carbon atoms;

R¹² and R¹³ are the same as at least one of R⁶, R⁷ and R¹¹ ; and

u is a number from 1 to 30, provided that when q is 0, at least one of R¹² and R¹³ is the same as R⁷, and further that not all R⁶ s can be phenyl groups;

or

a compound of formula (6);

##STR19## wherein;

R¹⁴ represents an alkyl group having from 1 to 4 carbon atoms;

R¹⁵ is a group --Q¹ --O--(C₂ H₄ O).sub. --(C₃ H₆ O)_y --R¹⁹

wherein Q¹ is a hydrocarbon group having 1 to 4 carbon atoms;

R¹⁹ is a hydrogen, an alkyl group having 1 to 4 carbon atoms, or an acetyl group;

x is an integer of 1 or more; and

y is an integer of 0 or more;

R¹⁶ is a group --Q₂ --O--R²⁰

wherein Q² is a hydrocarbon group having 1 to 4 carbon atoms; and

R²⁰ is a hydrocarbon group having 8 to 30 carbon atoms;

R¹⁷ and R¹⁸ are the same as at least one of R¹⁴, R¹⁵ or R ¹⁶ ;

α

is an integer of 0 or more; and

β and

γ

are integers of 1 or more.

15. A water-in-oil composition as claimed in claim 14 wherein the amount of surfactant is from 0.01 to 10%.

16. A water-in-oil cosmetic composition comprising:

(a) an oil phase component which comprises a pasty silicone composition which can disperse water; and

(b) at least one water phase component comprising water and water soluble compounds; and

a polyoxyalkylene-modified organopolysiloxane surface active;

wherein the pasty silicone composition is prepared by kneading 100 parts by weight of a silicone polymer and 5 to 1,000 parts by weight of a silicone oil under sufficient shearing force to a smooth and homogeneous outward appearance, and

wherein the silicone polymer is prepared by the addition polymerization, in the presence of 3 to 200 parts by weight of a low viscosity silicone oil having a viscosity of 100 cS or lower at 25°

C. or a polyhydric alcohol, or both, of 100 parts by weight of components comprising,

(I) an organohydrogenpolysiloxane represented by the following formula (1),

space="preserve" listing-type="equation">R.sup.1.sub.a R.sup.2.sub.b H.sub.c SiO.sub.(4-b-c)/2 (

     1)

wherein

R¹ represents a substituted or unsubstituted alkyl, aryl, or aralkyl group having 1 to 18 carbon atoms, or a halogenated hydrocarbon group;

R² represents a group --C_n H_2n O(C₂ H₄ O)_d (C₃ H₆ O)_e R³

wherein

R³ is a hydrogen, a saturated aliphatic hydrocarbon group having 1 to 10 carbon atoms, or a group --(CO)--R⁵, wherein R⁵ is a saturated aliphatic hydrocarbon group having 1 to 5 carbon atoms,

d is an integer of 2 to 200,

e is an integer of 0 to 200,

provided that d+e is 2 to 200, and

n is 2 to 6;

a is a value satisfying inequality 1.0≦

a≦

2.5;

b is a value satisfying inequality 0.001≦

b≦

1.0; and

c is a value satisfying inequality 0.001≦

c≦

1.0;

or an organohydrogenpolysiloxane represented by the following formula (2),

space="preserve" listing-type="equation">R.sup.1.sub.f H.sub.g SiO.sub.(4-f-g)/2 (

     2)

wherein

R¹ is the same as defined in formula (1),

f is a value satisfying inequality 1.0≦

f≦

3.0, and

g is a value satisfying inequality 0.001≦

g≦

1.5;

or a mixture of said organohydrogenpolysiloxanes of formulas (1) and (2); and

(II) a polyoxyalkylene represented by the following formula (A)

space="preserve" listing-type="equation">C.sub.m H.sub.2m-1 O(C.sub.2 H.sub.4 O).sub.h (C.sub.3 H.sub.6 O).sub.i C.sub.m H.sub.2m-1 (A)

wherein

h is an integer of 2 to 200,

i is an integer of 0 to 200,

provided that h+i is 2 to 200, and

m is 2 to 6,

or an organopolysiloxane represented by the following formula (B),

space="preserve" listing-type="equation">R.sup.1.sub.j R.sup.4.sub.k SiO.sub.(4-j-k)/2 (B)

wherein

R¹ is the same as defined in formula (1),

R⁴ is a monovalent hydrocarbon group having an aliphatic unsaturated bond at the terminal thereof and containing 2 to 10 carbon atoms,

j is a value satisfying inequality 1.0≦

j≦

3.0, and

k is a value satisfying inequality 0.001≦

k≦

1.5,

or a mixture of the polyoxyalkylene of formula (A) and the organopolysiloxane of formula (B),

wherein at least one organohydrogenpolysiloxane of formula (1) or at least one polyoxyalkylene of formula (A) are contained as an essential component of the addition polymerization.

17. A water-in-oil cosmetic composition as claimed in claim 16, wherein the polyoxyalkylene-modified organopolysiloxane surfactant is:

a compound of formula (4);

##STR20## wherein;

R⁶ represents an alkyl group having 1-5 carbon atoms or a phenyl group;

R⁷ is a group --(CH₂)_r --O--(C₂ H₄ O)_s --(C₃ H₆ O)_t --R¹⁰

wherein R¹⁰ is hydrogen or an alkyl group having from 1-5 carbon atoms;

r is a number from 1 to 5;

s is a number from 1-50; and

t is a number from 0-30;

R⁸ and R⁹ are the same as either R⁶ or R⁷ ;

p is a number from 5 to 300; and

q is a number from 0 to 50, provided that when q is 0, at least one of R⁸ and R⁹ is the same as R⁷ and provided further that not all R⁶ s can be phenyl groups;

a compound of formula (5);

##STR21## wherein;

R⁶, R⁷, p and q are the same as defined above;

R¹¹ is an alkyl group having 2-20 carbon atoms;

R¹² and R¹³ are the same as at least one of R⁶, R⁷ and R¹¹ ; and

u is a number from 1 to 30, provided that when q is 0, at least one of R¹² and R¹³ is the same as R⁷, and further that not all R⁶ s can be phenyl groups;

or

a compound of formula (6);

##STR22## wherein;

R¹⁴ represents an alkyl group having from 1 to 4 carbon atoms;

R¹⁵ is a group --Q¹ --O--(C₂ H₄ O)_x --(C₃ H₆ O)_y --R¹⁹

wherein Q¹ is a hydrocarbon group having 1 to 4 carbon atoms;

R¹⁹ is a hydrogen, an alkyl group having 1 to 4 carbon atoms, or an acetyl group;

x is an integer of 1 or more; and

y is an integer of 0 or more;

R¹⁶ is a group --Q² --O--R²⁰

wherein Q² is a hydrocarbon group having 1 to 4 carbon atoms; and

R²⁰ is a hydrocarbon group having 8 to 30 carbon atoms;

R¹⁷ and R¹⁸ are the same as at least one of R¹⁴, R¹⁵ or R¹⁶ ;

α

is an integer of 0 or more; and

β and

γ

are integers of 1 or more.

18. A water-in-oil composition as claimed in claim 17 wherein the amount of surfactant is from 0.01 to 10%.

19. A water-in-oil type make-up cosmetic composition comprising:

(a) a semisolid oil or a liquid oil, or both,

(b) a solid oil or an oil gelling agent, or both,

(c) A water-in-oil type cosmetic composition comprising;

(a) an oil phase component which comprises a pasty silicone composition which can disperse water; and

(b) at least one water phase component;

wherein the pasty silicone composition is prepared by kneading 100 parts by weight of a silicone polymer and 5 to 1,000 parts by weight of a silicone oil under a sufficient shearing force to produce a smooth and homogenous outward appearance, and

wherein the silicone polymer is prepared by the addition polymerization of the following components (I) and (II);

(I) an organohydrogenpolysiloxane represented by the following formula (1),

space="preserve" listing-type="equation">R.sup.1.sub.a R.sup.2.sub.b H.sub.c SiO.sub.(4-a-b-c)/2 (

     1)

wherein

R¹ represents a substituted or unsubstituted alkyl, aryl, or aralkyl group having 1 to 18 carbon atoms, or a halogenated hydrocarbon group;

R² represents a group,

space="preserve" listing-type="equation">--C.sub.n H.sub.2n O (C.sub.2 H.sub.4 O).sub.d (C.sub.3 H.sub.6 O).sub.e R.sup.3 (

     3)

wherein

R³ is a hydrogen, a saturated aliphatic hydrocarbon group having 1 to 10 carbon atoms, or a group --(CO)--R⁵, wherein R⁵ is a saturated aliphatic hydrocarbon group having 1 to 5 carbon atoms,

d is an integer of 2 to 200, and

e is an integer of 0 to 200,

provided that d+e is 3 to 200, and n is 2 to 6;

a is a value satisfying inequality 1.0≦

a≦

2.5;

b is a value satisfying inequality 0.001≦

b≦

1.0; and

c is a value satisfying inequality 0.001≦

c1.0;

or an organohydrogenpolysiloxane represented by the following formula (2),

space="preserve" listing-type="equation">R.sup.1.sub.f H.sub.g SiO.sub.(4-f-g)/2 (

     2)

wherein

R¹ is the same as defined in formula (1),

f is a value satisfying inequality 1.0≦

f≦

3.0,

g is a value satisfying inequality 0.001≦

g ≦

1.5;

or a mixture of said organohydrogenpolysiloxanes of formulas (1) and (2), and

(II) a polyoxyalkylene represented by the following formula (A),

space="preserve" listing-type="equation">C.sub.m H.sub.2m-1 O(C.sub.2 H.sub.4 O).sub.h (C.sub.3 H.sub.6 O).sub.i C.sub.m H.sub.2m-1 (A)

wherein

h is an integer of 2 to 200,

i is an integer of 0 to 200, provided that h+i is 3 to 200, and

m is 2 to 6,

or an organopolysiloxane represented by the following formula (B),

space="preserve" listing-type="equation">R.sup.1.sub.j R.sup.4.sub.k SiO.sub.(4-j-k)/2 (B)

wherein

R¹ is the same as defined in formula (1),

R⁴ is a monovalent hydrocarbon group having an aliphatic unsaturated bond at the terminal thereof and containing 2 to 10 carbon atoms,

j is a value satisfying inequality 1.0≦

j≦

3.0, and

k is a value satisfying inequality 0.001≦

k≦

1.5,

or a mixture of the polyoxyalkylene of formula (A) and the organopolysiloxane of formula (B),

wherein at least one organohydrogenpolysiloxane of formula (1) or at least one polyoxyalkylene of formula (A) is contained as an essential component of the addition polymerization

(d) at least one water phase component comprising water and water soluble components; and

(e) a cosmetic powder.

20. A water-in-oil make-up cosmetic composition comprising:

(a) a semisolid oil or a liquid oil, or both,

(b) a solid oil or an oil gelling agent, or both,

(c) a water-in-oil cosmetic composition comprising;

(a) an oil phase component which comprises a pasty silicone composition which can disperse water; and

(b) at least one water phase component comprising water and water soluble components;

wherein the pasty silicone composition is prepared by kneading 100 parts by weight of a silicone polymer and 5 to 1,000 parts by weight of a silicone oil under a sufficient shearing force to produce a smooth and homogenous outward appearance, and

wherein the silicone polymer is prepared by the addition polymerization, in the presence of 3 to 200 parts by weight of a low viscosity silicone oil having a viscosity of 100 cS or lower at 25°

C. or a polyhydric alcohol, or both, of 100 parts by weight of components comprising,

(I) an organohydrogenpolysiloxane represented by the following formula (1),

space="preserve" listing-type="equation">R.sup.1.sub.a R.sup.2.sub.b H.sub.c SiO.sub.(4-a-b-c)/2 (

     1)

wherein

R¹ represents a substituted or unsubstituted alkyl, aryl, or aralkyl group having 1 to 18 carbon atoms, or a halogenated hydrocarbon group;

R² represents a group --C_n H_2n O(C₂ H₄ O)_d (C₃ H₆ O)_e R³

wherein

R³ is a hydrogen, a saturated aliphatic hydrocarbon group having 1 to 10 carbon atoms, or a group --(CO)--R⁵, wherein R⁵ is a saturated aliphatic hydrocarbon group having 1 to 5 carbon atoms,

d is an integer of 2 to 200,

e is an integer of 0 to 200,

provided that d+e is 2 to 200, and

n is 2 to 6;

a is a value satisfying inequality 1.0≦

a≦

2.5;

b is a value satisfying inequality 0.001≦

b≦

1.0; and

c is a value satisfying inequality 0.001≦

c≦

1.0;

or an organohydrogenpolysiloxane represented by the following formula (2),

space="preserve" listing-type="equation">R.sup.1.sub.f H.sub.g SiO.sub.(4-f-g)/2 (

     2)

wherein

R¹ is the same as defined in formula (1),

f is a value satisfying inequality 1.0≦

f≦

3.0, and

g is a value satisfying inequality 0.001≦

g≦

1.5;

or a mixture of said organohydrogenpolysiloxanes of formulas (1) and (2); and

(II) a polyoxyalkylene represented by the following formula (A)

space="preserve" listing-type="equation">C.sub.m H.sub.2m-1 O(C.sub.2 H.sub.4 O).sub.h (C.sub.3 H.sub.6 O).sub.i C.sub.m H.sub.2m-1 (A)

wherein

h is an integer of 2 to 200,

i is an integer of 0 to 200,

provided that h+i is 2 to 200, and

m is 2 to 6,

or an organopolysiloxane represented by the following formula (B),

space="preserve" listing-type="equation">R.sup.1.sub.j R.sup.4.sub.k SiO.sub.(4-j-k)/2 (B)

wherein

R¹ is the same as defined in formula (1),

R⁴ is a monovalent hydrocarbon group having an aliphatic unsaturated bond at the terminal thereof and containing 2 to 10 carbon atoms,

j is a value satisfying inequality 1.0≦

j≦

3.0, and

k is a value satisfying inequality 0.001≦

k≦

1.5,

or a mixture of the polyoxyalkylene of formula (A) and the organopolysiloxane of formula (B),

wherein at least one organohydrogenpolysiloxane of formula (1) or at least one polyoxyalkylene of formula (A) are contained as an essential component of the addition polymerization,

(d) at least one water phase component, and

(e) a cosmetic powder.