Evaporation for solids concentration

• US 5,413,674 A
• Filed: 12/23/1992
• Issued: 05/09/1995
• Est. Priority Date: 12/23/1992
• Status: Expired due to Fees

• Current Assignee: UOP Llc (Honeywell International Inc.)
• Original Assignee: UOP Llc (Honeywell International Inc.)
• Inventors: Ragi, Elias G.
• Primary Examiner(s): Manoharan, Virginia
• Application Number:
  US07/997,252
• Time in Patent Office: 867 Days
• Field of Search: 159/47.3, 159/DIG. 8, 159/17.1, 159/24.2, 159/DIG. 32, 159/16.3, 159/27.1, 165/133, 202/174, 202/235, 162/29, 162/47
• US Class Current: 159/47.3
• CPC Class Codes: B01D 1/26 Multiple-effect evaporating
• CPC Class Codes: Y10S 159/08 Multieffect or multistage
• CPC Class Codes: Y10S 159/32 Indirect heat exchange

Abstract

A black liquor process for paper pulping uses a nucleic boiling surface in a series of multi-effective evaporators. The nucleic boiling surface may be used to retube all effects or a single effect.

Claims

1. A continuous process for evaporating water from a solution containing solids, said solution comprising a black liquor from the manufacture of paper, said process comprising,

(a) passing a first black liquor feed into a first vertical thermosyphon heat exchanger that functions as an evaporator for the evaporation of water from the black liquor feed and indirectly heating said first black liquor feed with a first heating medium comprising a first boiled liquid stream by contacting said first black liquor feed with a first heat exchange surface and contacting said first heat exchange medium with a second heat exchange surface in said first heat exchanger to produce an intermediate black liquor containing at least 15 wt % solids and a second boiled stream comprising water evaporated from said first black liquor feed;

(b) passing said intermediate black liquor to at least one intermediate vertical thermosyphon heat exchanger that functions as an evaporator for the evaporation of water from the intermediate black liquor and indirectly contacting said intermediate black liquor with a second heat exchange medium comprising at least one of a third boiled liquid stream and a live steam stream by contacting said intermediate black liquor with a third heat exchange surface comprising a nucleate boiling surface and said second heat exchange medium with a fourth heat exchange surface to produce a second black liquor feed and at least a portion of said first boiled stream which comprises water evaporated from said intermediate black liquor; and

,

(c) passing said second black liquor feed to a third vertical thermosyphon heat exchanger that functions as an evaporator for the evaporation of water from the second black liquor feed and indirectly contacting said second black liquor feed with live steam by contacting said second black liquor feed with a fifth heat exchange surface and said live steam with a sixth heat exchange surface in said third heat exchanger to produce a black liquor product having an increased concentration of solids relative to said first black liquor feed and at least a portion of said third boiled liquid stream which comprises water evaporated from said second black liquor feed.

2. The process of claim 1 wherein said nucleate boiling surface is a High Flux boiling surface comprising a surface layer of reentrant openings.

3. The process of claim 1 wherein the concentration of solids in said black liquor is increased from less than 20 wt. % to at least 50 wt %.

4. The process of claim 1 wherein said first and said fifth heat exchanger surfaces further include a nucleate boiling surface.

5. The process of claim 1 wherein said live steam has a temperature of at least 220°

F. and a pressure less than 50 psia.

6. The process of claim 1 wherein said black liquor passes through a series of at least six heat exchangers.

7. The process of claim 1 wherein the black liquor product has a concentration of 40 to 65 wt % solids.