Reversible sensor for detecting solvent vapors

• US 5,417,100 A
• Filed: 03/10/1993
• Issued: 05/23/1995
• Est. Priority Date: 03/10/1993
• Status: Expired due to Term

• Current Assignee: Hughes Electronics Corporation (AT&T, Inc.)
• Original Assignee: Hughes Aircraft Company (Rtx Corporation)
• Inventors: Yamagishi, Frederick G., Miller, Leroy J., van Ast, Camille I.
• Primary Examiner(s): Thibodeau, Paul J.
• Assistant Examiner(s): Sand, Stephen
• Application Number:
  US08/029,805
• Time in Patent Office: 804 Days
• Field of Search: 73/29.05, 73/31.01, 73/31.02, 73/31.03, 428/421, 428/913, 428/426, 428/461, 428/458, 428/446, 324/439, 324/446, 324/693, 324/722, 324/724, 324/691, 204/424, 204/427, 204/412
• US Class Current: 73/31.02
• CPC Class Codes: G01M 3/16 using electric detection means G01M3/045, G01M3/06, G01M3/12, G01M3/20, G01M3/24, G01M3/26 take precedence
• CPC Class Codes: G01N 27/126 comprising organic polymers
• CPC Class Codes: G01N 33/0047 Organic compounds
• CPC Class Codes: Y10T 428/3154 Of fluorinated addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31681 Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]

Abstract

A novel, inexpensive sensor (10) for detecting volatile hydrocarbons and other solvent vapors detects leaks in the fittings and valves of petroleum refineries and chemical manufacturing and processing plants. The sensor comprises (a) a dielectric substrate (12) having a major surface; (b) a pair of interdigitated, electrically conductive electrodes (14a, 14b) disposed on the major surface of the substrate; and (c) a composite coating (16) covering the interdigitated electrodes and comprising (1) a conductive polymer, and (2) a dielectric polymer with an affinity for the solvent vapors to be detected.

Claims

1. A fugitive emissions sensor for reversibly detecting solvent vapors comprising:

(a) a dielectric substrate having a major surface;

(b) a pair of electrically conductive electrodes disposed on said major surface of said substrate, said electrodes each comprising a plurality of fingers interdigitated with the other electrode; and

(c) a composite coating covering the interdigitated electrodes and comprising (1) a conductive polymer, said polymer having a conductivity in the range of 10^-6 to 1 S/cm, and (2) a dielectric polymer with an affinity for said solvent vapors to be detected, the ratio of said conductive polymer to said dielectric polymer ranging from about 1;

1 to 1;

5.

2. The fugitive emissions sensor of claim 1 wherein said solvent vapors are selected from the group consisting of hydrocarbons and polar solvents.

3. The fugitive emissions sensor of claim 1 wherein said dielectric substrate comprises a material selected from the group consisting of glass, ceramics, and dielectric polymers.

4. The fugitive emissions sensor of claim 3 wherein said dielectric substrate comprises a glass selected from the group consisting of silica, phosphate, and borate glasses and mixtures thereof.

5. The fugitive emissions sensor of claim 3 wherein said dielectric substrate comprises a ceramic selected from the group consisting of alumina, magnesia, calcia and mixtures thereof.

6. The fugitive emissions sensor of claim 3 wherein said dielectric substrate comprises a dielectric polymer selected from the group consisting of polyethylene terephthalate, poly(tetrafluoroethylene), polymethyl methacrylate, and polyimides.

7. The fugitive emissions sensor of claim 1 wherein said electrically conducting electrodes comprise a material selected from the group consisting of gold, platinum, palladium, and carbon.

8. The fugitive emissions sensor of claim 7 wherein said electrically conducting electrodes both consist essentially of gold.

9. The fugitive emissions sensor of claim 8 wherein said gold electrodes are formed on an adhering layer that adheres said gold electrodes to said substrate.

10. The fugitive emissions sensor of claim 1 wherein said conductive polymer is selected from the group consisting of polyaniline, polythiophene, polypyrrole, poly(p-phenylene vinylene), derivatives of these polymers, and mixtures of these materials, with appropriate dopants present in an amount necessary to change said conductive polymer from a neutral state to a charged state to provide the requisite conductivity.

11. The fugitive emissions sensor of claim 10 wherein said conductive polymer is polyaniline and said dopants are selected from the group consisting of salts of p-toluenesulfonic acid, benzenesulfonic acid, p-dodecylsulfonic acid, poly(styrenesulfonic acid), sulfuric acid, and hydrochloric acid.

12. The fugitive emissions sensor of claim 1 wherein said solvent vapors comprise hydrocarbon solvents and said dielectric polymers are selected from the group consisting of poly(isobutylene), polybutadiene, polystyrene, and alkyl-substituted polystyrenes.

13. The fugitive emissions sensor of claim 1 wherein said solvent vapors comprise polar solvents and said dielectric polymers contain polar functional groups selected from the group consisting of hydroxyl, amino, and carboxylate groups.

14. A fugitive emissions sensor for reversibly detecting solvent vapors selected from the group consisting of hydrocarbons and polar solvents, comprising:

(a) a dielectric substrate having a major surface;

(b) a pair of electrically conductive electrodes disposed on said major surface of said substrate, said electrodes each comprising a plurality of fingers interdigitated with the other electrode; and

(c) a composite coating covering the interdigitated electrodes and comprising (1) a conductive polymer selected from the group consisting of polyaniline, polythiophene, polypyrrole, poly(p-phenylene vinylene), derivatives of these polymers, and mixtures of these materials, doped with appropriate dopants to provide a conductivity in the range of about 10^-6 to 1 S/cm, and (2) a dielectric polymer with an affinity for said solvent vapors to be detected, said dielectric polymer selected from the group consisting of poly(isobutylene), polybutadiene, polystyrene, and alkyl-substituted polystyrenes where said solvent vapors to be detected comprise hydrocarbon solvents or said dielectric polymer containing polar functional groups selected from the group consisting of hydroxyl, amino, and carboxylate groups where said solvent vapors to be detected comprise polar solvents, the ratio of said conducting polymer to said dielectric polymer ranging from about 1;

1 to 1;

5.

15. A fugitive emissions sensor for reversibly detecting hydrocarbon solvent vapors comprising:

(a) a dielectric substrate having a major surface;

(b) a pair of electrically conductive electrodes disposed on said major surface of said substrate, said electrodes each comprising a plurality of fingers interdigitated with the other electrode; and

(c) a composite coating covering the interdigitated electrodes and comprising (1) a conductive polymer consisting essentially of polyaniline doped with p-toluenesulfonic acid to provide a sulfonate salt having a conductivity within the range of about 10^-6 to 1 S/cm, and (2) a dielectric polymer consisting essentially of poly(iso-butylene), the ratio of said conducting polymer to said dielectric polymer ranging from about 1;

1 to 1;

5.