Small glass electrode

• US 5,417,837 A
• Filed: 12/06/1991
• Issued: 05/23/1995
• Est. Priority Date: 12/06/1990
• Status: Expired due to Fees

• Current Assignee: Fujitsu Limited
• Original Assignee: Fujitsu Limited
• Inventors: Suzuki, Hiroaki, Sugama, Akio, Kojima, Naomi
• Primary Examiner(s): Tung, T.
• Application Number:
  US07/803,433
• Time in Patent Office: 1,264 Days
• Field of Search: 204/416-420
• US Class Current: 204/420
• CPC Class Codes: G01N 27/36 Glass electrodes
• CPC Class Codes: G01N 27/4035 Combination of a single ion-sensing electrode and a single reference electrode G01N27/406 and G01N27/413 take precedence

Abstract

A small glass electrode and process for preparation thereof are disclosed. This small glass electrode is characterized in that said glass electrode, which has a bonded structure comprises a reference electrode composed of silver/silver chloride, a glass substrate having a pad embedded therein, said pad being composed of gold or platinum and circuit-connected to the reference electrode, and a silicon substrate having a (100) plane selectively etched by the anisotropic etching technique and comprising a groove for injecting an electrolyte composed of an aqueous solution containing chlorine such as KCl, or HCl, at least one hole for holding the electrolyte and a glass film formed in a portion corresponding to the reference electrode. By this structure, the small glass electrode can be easily manufactured at a low cost.

Claims

1. A small glass electrode having a bonded structure and comprising:

a reference electrode composed of silver/silver chloride, a glass substrate having a pad embedded therein, said pad being composed of gold or platinum and circuit-connected to the reference electrode, and a silicon substrate having a first main surface defined by a (100) plane and which is selectively etched by anisotropic etching to define a reservoir for holding an aqueous electrolyte, the reservoir extending from the first main surface and to a second, opposite main surface and having a sidewall at the second main surface of the silicon substrate, and a groove in communication with the reservoir for injecting the aqueous electrolyte into the reservoir, and a glass film formed on said silicon substrate at the second main surface thereof in a portion of the sidewall of the reservoir at a position corresponding to that of the reference electrode.

2. A small glass electrode as set forth in claim 1, wherein an electrolyte occupies the electrolyte-holding reservoir.

3. A small glass electrode as set forth in claim 1, wherein the glass film is a sensing film and comprises two layers of glass film.

4. A small glass electrode having a bonded structure comprising:

a glass substrate having a first main surface and having embedded therein, from the main surface, a reference electrode, a pad and a lead-in line interconnecting said reference electrode and said pad;

a silicon semiconductor substrate having a first main surface, at least one reservoir extending into the substrate from the first main surface for holding an aqueous electrolyte and a groove forming a fluid passageway in communication with the reservoir for injecting the aqueous electrolyte into the reservoir, said groove and said reservoir being formed by anisotropic etching of the substrate, the reservoir extending from the first main surface and toward a second, opposite main surface of the semiconductor substrate and the reservoir having a sidewall defining an aperture at the second main surface of the silicon substrate to expose the interior of the reservoir, the aperture being disposed at a location corresponding to the position of the reference electrode embedded in the glass substrate; and

a glass sensing film covering and sealing the aperture in the sidewall and thus at a position corresponding to said reference electrode.

5. A small glass electrode as set forth in claim 4, wherein said reference electrode is comprised of silver or silver/silver chloride.

6. A small glass electrode as set forth in claim 4, wherein said pad and said lead-in line are made of gold or platinum.

7. A small glass electrode as set forth in claim 4, wherein said electrolyte is an aqueous electrolyte solution.

8. A small glass electrode as set forth in claim 4, wherein the glass film is a sensing film and comprises two layers of glass film.

9. A small glass electrode as set forth in claim 4, wherein said semiconductor substrate is a (100) oriented silicon substrate.

10. A small glass electrode as set forth in claim 4, wherein said glass film comprises two layers of glass film.

11. A glass electrode structure comprising:

a glass substrate comprising a first, end portion, a second, central portion and a third, end portion, the third end portion being opposite the first end portion and integrally connected thereto by the second central portion, the first, second and third portions having corresponding first, second and third main surface portions lying in a common plane and defining a common main surface of the glass substrate, the glass substrate having opposite end walls respectively associated with the first and second opposite end portions and a pair of spaced, lateral sidewalls respectively interconnecting the end walls, and the main surface including a peripheral main surface portion extending inwardly from each of the lateral sidewalls and the end walls of the glass substrate and defining an interior main surface portion;

a conductor layer embedded in the interior main surface portion and comprising a reference electrode portion formed on the interior of the first main surface portion, an electrical conducting pad on the interior of the third main surface portion and an interconnecting lead formed on the interior of the second main surface portion and extending between and electrically interconnecting the pad and the reference electrode, the pad and the lead comprising a common material selected from the group consisting of gold and platinum material and the reference electrode comprising a layer of silver formed on the interior of the first main surface portion and a layer of silver chloride formed on the layer of silver;

a silicon substrate having a first main surface defined by a (100) plane thereof and an opposite main surface, and further having a pair of spaced, opposite end walls and a pair of spaced, lateral sidewalls respectively extending between and interconnecting the opposite end walls, the silicon substrate further comprising a first, end portion and an integral, second portion having respective first and second main surface portions comprising the first main surface of the substrate and respectively corresponding to the first and second main surface portions of the glass substrate, the silicon substrate further having a peripheral main surface portion extending inwardly from each of the lateral sidewalls and the end walls thereof and defining an interior main surface portion, a recess in the first, end portion and a groove extending from the recess and along the first main surface of the silicon substrate to the second end wall thereof, the recess being bounded by the peripheral main surface portion and extending from the interior main surface portion to the opposite main surface of the substrate and defining an aperture at a position at least adjacent to the opposite main surface, the aperture being closed by a glass film; and

the glass substrate and the silicon substrate being assembled with the respective main surfaces thereof in contiguous and aligned relationship with the first and second main surface portions of the silicon substrate disposed on the first and second main surface portions of the glass substrate and with the peripheral main surface portion of the silicon substrate bonded to the corresponding peripheral and main surface portions of the glass substrate and thereby with the reference electrode in registry with the recess and defining therewith a reservoir, the groove in the silicon substrate defining a fluid passageway, extending from the reservoir and between the glass and silicon substrates to the second end wall of the silicon substrate to and of sufficient depth for the injection of a liquid electrolyte solution therethrough into the reservoir.

12. A small glass electrode as recited in claim 11, further comprising an electrolyte injected through the groove and received in the reservoir.

13. A small glass electrode as recited in claim 12, wherein the glass and silicon substrates are bonded together by anodic bonding.

14. A small glass electrode as recited in claim 11, wherein the aperture is defined at a recessed position within the silicon substrate, displaced inwardly of the second main surface thereof, and the glass film is positioned at the recessed position of the aperture and secured about the peripheral edges thereof to the corresponding edge walls of the aperture.

15. A small glass electrode as recited in claim 14, wherein the glass film is secured to the silicon substrate by anodic bonding.

16. A small glass electrode as recited in claim 11, wherein the glass film comprises a double layer glass film.

17. A small glass electrode as recited in claim 16, wherein the double layer glass film comprises a first layer of a heat resistant glass and a second, sputtered layer of sodium-calcium glass.

18. A small glass electrode as recited in claim 11, wherein each of the recess and the groove is formed by anisotropic etching of the silicon substrate, inwardly from the first main surface thereof.

19. A small glass electrode as set forth in claim 11, wherein the glass film is a sensing film and comprises two layers of glass film.