Stable conditioning shampoo having a high foam level containing a silicone conditioner, a cationic quaternary acrylate copolymer, an anionic surfactant and polyethyleneimine

• US 5,417,965 A
• Filed: 05/17/1993
• Issued: 05/23/1995
• Est. Priority Date: 06/24/1991
• Status: Expired due to Term

• Current Assignee: Helene Curtis Inc. (Unilever PLC)
• Original Assignee: Helene Curtis Inc. (Unilever PLC)
• Inventors: Brown, William, Janchitraponvej, Ben
• Primary Examiner(s): Page, Thurman K.
• Assistant Examiner(s): HARRISON, ROBERT H
• Application Number:
  US08/062,606
• Time in Patent Office: 736 Days
• Field of Search: 424/70, 424/71, 252/544, 252/547, 252/DIG. 13, 252/174.23
• US Class Current: 510/122
• CPC Class Codes: A61K 2800/5426 cationic
• CPC Class Codes: A61K 2800/594 Mixtures of polymers
• CPC Class Codes: A61K 8/39 Derivatives containing from 2 to 10 oxyalkylene groups
• CPC Class Codes: A61K 8/44 Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
• CPC Class Codes: A61K 8/463 containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
• CPC Class Codes: A61K 8/8158 Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
• CPC Class Codes: A61K 8/8176 Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
• CPC Class Codes: A61K 8/84 obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
• CPC Class Codes: A61K 8/898 containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
• CPC Class Codes: A61Q 5/02 Preparations for cleaning the hair
• CPC Class Codes: A61Q 5/12 Preparations containing hair conditioners

Abstract

A conditioning shampoo containing an anionic cleansing surfactant, in an amount of about 5% to about 65% by weight, preferably about 5% to about 25% by weight, e.g., (C₁₂ -C₂₂) alkyl sulfate, and/or a long chain (C₁₂ -C₂₂) partially or fully ethoxylated alkyl sulfate, and/or a long chain (C₁₂ -C₂₂) alkyl sulfonate, and a combination of cationic polymers comprising (1) a cationic (protonated) polyethyleneimine in an amount of about 0.1% to about 4% by weight, preferably about 0.1% to about 1% by weight, and (2) a cationic oil-soluble, water-dispersible, cross-linked quaternary acrylate/acrylamide copolymer (Polyquaternium 32), in an amount of about 0.1% to about 20% by weight of the composition, provides excellent foaming, conditioning and stability, without settling of water-insoluble materials due to anionic-cationic complexing. The composition preferably also includes one or more silicone conditioning agents, and has extended product stability, excellent overall conditioning to human hair, particularly superior wet and dry combing properties, and unexpectedly maintains very high levels of foam.

Claims

1. A conditioning shampoo for cleansing and conditioning hair while maintaining foam comprising water, an anionic cleansing surfactant in an amount of about 5% to about 65% by weight;

a cationic polyethyleneimine in an amount of about 0.01% to about 4% by weight; and

a cationic oil-soluble, water-dispersible, cross-linked acrylate/acrylamide copolymer conditioning agent in an amount of about 0.1% to about 20% by weight.

2. The composition of claim 1, wherein the anionic surfactant is a carboxylate surfactant.

3. The composition of claim 1 further including a long chain (C₁₂ -C₂₂) amine oxide emulsion stabilizer in an amount of about 0.1% to about 5% based on the weight of the composition.

4. The composition of claim 1 having a pH of about 4.5 to about 7.5.

5. The composition of claim 1, wherein the composition includes a viscosity increasing agent in an amount of about 0.1% to about 10% by weight for raising the viscosity of the composition to at least about 3,000 centipoises.

6. The composition of claim 1 further including a zwitterionic detergent in an amount of about 5% to about 15% by weight of the composition.

7. The composition of claim 1, wherein the composition includes a betaine surfactant in an amount of about 5% to about 25% by weight of the composition.

8. The composition of claim 7, wherein the betaine surfactant is cocamidopropyl hydroxysultaine.

9. The composition of claim 1, further including a silicone conditioning agent in an amount of about 0.1% to about 10% by weight of the composition.

10. The composition of claim 1, wherein the composition includes less than about 9% by weight of an anionic surfactant selected from the group consisting of a long chain (C₁₂ -C₂₂) alkyl sulfate, a long chain (C₁₂ -C₂₂) alkyl ether sulfate;

a long chain (C₁₂ -C₂₂) alkyl sulfonate; and

a long chain (C₁₂ -C₂₂) alkyl ether sulfonate.

11. The composition of claim 1, wherein the polyethyleneimine has a cationic polymer charge density of at least about 10 milliequivalents per gram.

12. The composition of claim 11, wherein the polyethyleneimine has a cationic polymer charge density in the range of about 15 to about 20 milliequivalents per gram.

13. The composition of claim 1, wherein the polyethyleneimine has a weight average molecular weight in the range of about 700 to about 70,000.

14. A method of cleansing and conditioning hair, simultaneously while maintaining foam and excellent cleansing in a shampoo composition comprising contacting the hair with a conditioning shampoo comprising water, an anionic cleansing surfactant in an amount of about 5% to about 65% by weight, a protonated polyethyleneimine in an amount of about 0.01% to about 4% by weight and a cationic oil-soluble, water-dispersible, cross-linked acrylate/acrylamide copolymer conditioning agent in an amount of about 0.1% to about 20% by weight.

15. The method of claim 14, wherein the conditioning shampoo includes an anionic carboxylate surfactant.

16. The method of claim 14, wherein the conditioning shampoo further includes a long chain (C₁₂ -C₂₂) amine oxide emulsion stabilizer in an amount of about 0.1% to about 5% based on the weight of the composition.

17. The method of claim 14, wherein the conditioning shampoo further includes a viscosity increasing agent in an amount of about 0.1% to about 10% by weight for raising the viscosity of the composition to at least about 3,000 centipoises.

18. The method of claim 15, wherein the conditioning shampoo includes a zwitterionic detergent in an amount of about 5% to about 15% by weight of the composition.

19. The method of claim 14, wherein the conditioning shampoo includes a betaine surfactant in an amount of about 5% to about 25% by weight of the composition.

20. The method of claim 19, wherein the betaine surfactant is cocamidopropyl hydroxysultaine.

21. The method of claim 19, wherein the conditioning shampoo further includes a silicone conditioning agent in an amount of about 0.1% to about 10% by weight of the conditioning shampoo.