Window glass with an electroconductive layer, obtained by pyrolysis of powdered components, which can be used as a windshield for an automobile

• US 5,418,025 A
• Filed: 05/09/1994
• Issued: 05/23/1995
• Est. Priority Date: 07/27/1988
• Status: Expired due to Fees

• Current Assignee: Saint Gobain Vitrage (Compagnie De Saint-Gobain S.A.)
• Original Assignee: Saint Gobain Vitrage (Compagnie De Saint-Gobain S.A.)
• Inventors: Harmand, Helene, Trouve, Maurice, Sauvinet, Vincent
• Primary Examiner(s): TURNER, ARCHENE A
• Application Number:
  US08/239,929
• Time in Patent Office: 379 Days
• Field of Search: 428/38, 428/76, 428/195, 428/210, 428/336, 428/423.1, 428/425.6, 428/426, 428/432, 428/437, 428/460, 428/442, 428/216, 428/697, 428/699, 428/701, 428/702, 428/913 , 428/472, 219/203, 219/522, 219/543
• US Class Current: 428/38
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/1011 having predetermined tint or excitation purity
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: B32B 17/10211 Doped dielectric layer, electrically conductive, e.g. SnO2:F
• CPC Class Codes: B32B 17/10293 Edge features, e.g. inserts or holes
• CPC Class Codes: B32B 17/10339 Specific parts of the laminated safety glass or glazing being colored or tinted tinted glass sheet B32B17/1011; tinted interlayer B32B17/10651
• CPC Class Codes: B32B 17/10348 comprising an obscuration band
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 17/1077 containing polyurethane
• CPC Class Codes: B32B 17/10788 containing ethylene vinylacetate
• CPC Class Codes: B32B 17/10935 as a preformed layer, e.g. formed by extrusion
• CPC Class Codes: C03C 17/42 at least one coating of an organic material and at least one non-metal coating
• CPC Class Codes: C03C 3/087 containing calcium oxide, e.g. common sheet or container glass
• CPC Class Codes: C03C 4/02 for coloured glass
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10S 501/904 Infrared transmitting or absorbing
• CPC Class Codes: Y10S 501/905 Ultraviolet transmitting or absorbing
• CPC Class Codes: Y10T 428/24975 No layer or component greater than 5 mils thick
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31601 Quartz or glass
• CPC Class Codes: Y10T 428/3163 : Next to acetal of polymerized unsaturated alcohol [e.g., formal butyral, etc.]
• CPC Class Codes: Y10T 428/31649 : Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31688 : Next to aldehyde or ketone condensation product

Abstract

A window glass comprising at least one sheet of glass coated with an electroconductive ITO layer, pyrolyzed from powdered components, combined with a flexible plastic material of the PVB, PU, PVC type, with an index approaching more the index of the ITO layer than the index of air, with which the said layer is coated, and a sheet of glass dyed in the mass, with the same color as the ITO layer, and with properties of reduced energy transmission also entering advantageously into the composition of the window glass is provided. The invention particularly applies to the production of heated windshields for automobiles.

Claims

1. A curved window glass comprising at least one curved sheet of glass coated with an electroconductive layer of metal oxide comprised of indium tin oxide (ITO), obtained by pyrolysis, followed by reduction treatment, of a powdered mixture of a tin compound and an indium compound, on face 3 of the faces of said curved window glass numbered conventionally 1, 2, 3 and 4 proceeding from the outside to the inside of the space enclosed by the window glass, said (ITO) layer covered by a sheet of flexible plastic material having an optical index between that of the metal oxide layer and that of air and closer to that of the metal oxide layer than to the index of air.

2. The window glass of claim 1, wherein said tin compound comprises dibutyl tin oxide (DBTO).

3. The window glass of claim 1, wherein the plastic sheet is comprised of a material selected from the group consisting of polyvinylbutyral, polyvinylchloride and polyurethane and possesses an optical index between the index 1 of air and the index on the order of 1.8 of the metal oxide layer.

4. The window glass of claim 3, wherein said optical index is about 1.5.

5. A window glass according to claim 1, comprising a single sheet of glass carrying the layer of ITO and wherein the sheet of plastic material is formed, in the order starting from the metal oxide layer, of a layer of thermoplastic polyurethane (PU)

6. A window glass according to claim 1, wherein the flexible plastic material with an index greater than that of air is colored.

7. A window glass according to claim 1, wherein the ITO layer has a thickness which gives it a greenish color.

8. A window glass according to claim 7, wherein the ITO layer has a thickness at least 330 nm.

9. The window glass of claim 8, wherein said ITO layer has a thickness of 350-380 nm.

10. The window glass of claim 7, wherein said ITO layer has a thickness of about 180 nm.

11. A window glass according to claim 1, wherein it comprises a thickness of glass tinted in its body, with a reduced coefficient of energy transmission.

12. A window glass according to claim 11, wherein the tinted glass is either green or the same color as the ITO layer.

13. A window glass according to claim 12, wherein the tinted glass is "TSA" or "TSA^2+" glass, containing oxide dyes in approximately the following weight proportions:

"TSA" Fe₂ O₃ ;

between 0.55 and 0.62%

FeO;

between 0.11 and 0.16%

CoO;

less than 10 ppm

"TSA^2+" Fe₂ O₃ ;

between 0.75 and 0.90%

FeO;

between 0.15 and 0.22%

CoO;

less than 17 ppm

14. A window glass according to claim 11, wherein the tinted glass is the one which carries the ITO layer.

15. A window glass according to claim 14, comprising a single layer selected from the group consisting of TSA and TSA²⁺ glass with a maximum thickness of 3.5-4 mm, carrying an ITO layer with a thickness of 180 nm, and a sheet of PU coated onto the sheet of glass on the side of the ITO layer.

16. A window glass according to claim 14, comprising a single layer selected from the group consisting of "TSA" or "TSA^2+" glass with a maximum thickness of 3.5-4 mm, carrying an ITO layer with a thickness of 350-380 nm, and a sheet of PU coated onto said single layer of glass on the side of the ITO layer.

17. A window glass according to claim 16, wherein the single sheet of glass carries, at its periphery, a continuous layer of opaque enamel, reduced to a dotted line in the area adjacent the longitudinal center of the window glass, a conductive strip with a silver base being arranged at the edge of the enamel, partly on the dots of enamel and partly on the ITO layer.

18. A wind glass according to claim 17, characterized by the fact that the deposits of enamel arranged on the periphery of the sheets of glass are deposited on faces of said glass sheets directed to the interior of a space enclosed by the window glass.

19. A window glass according to one of claim 16, characterized by the fact that it presents a light transmission (T_L) greater than or equal to 70, a reduced energy transmission (T_E) resulting in a ratio of T_L /T_E on the order of 1.5, and a uniform electrical resistance per square, either less than or equal to 5 ohms.

20. The window glass of claim 19, wherein the electrical resistance per square is about 4.5 ohms.

21. A window glass according to claim 16, having a uniform electrical resistance of about 10 ohm per square.

22. A window glass according to claim 11, wherein the sheet of glass having the ITO layer has two faces, faces 3 and 4 and carrying the ITO layer on its face 3, is clear glass, and a sheet of glass with faces 1 and 2, which is combined with sheet of glass carrying the ITO layer by the intermediary of the sheet of plastic material, is of "TSA" or "TSA^2+" glass.

23. A window glass according to claim 22, comprising an exterior sheet of tinted "TSA" glass with a maximum thickness on the order of 2.2 mm, a sheet arranged towards the interior of a space enclosed by the window glass, of clear glass with a thickness on the order of 2.1 to 2.6 mm, coated with an ITO layer with a thickness on the order of 350 to 380 nm on the face facing towards the sheet of tinted glass, these two sheets of glass being combined into a laminate with the intermediary layer of a sheet of flexible material with an index greater than 1.

24. The window glass of claim 22, wherein said plastic material comprises polyvinylbutyral.

25. A window glass according to claim 22, comprising an exterior curved sheet of tinted "TSA" glass with a maximum thickness on the order of 2.6 mm, a curved sheet arranged towards the interior of a space enclosed by the window glass, of clear glass with a thickness on the order of 2.1 to 2.6 mm, coated with an ITO layer with a thickness on the order of 180 nm on the face facing towards the sheet of tinted glass, these two curved sheets of glass being combined into a laminate with the intermediary layer of a sheet of flexible material with an index greater than 1.

26. The window glass of claim 25, wherein said flexible material is comprised of polyvinylbutyral.

27. A window glass according to claim 1, comprising means of supplying current to provide electricity for the ITO layer.

28. A window glass according to claim 27, wherein the means of supplying current are comprised of two serigraphed strips comprising Ag or an Ag alloy.

29. A window glass according to claim 27, wherein the means of supplying current are two metallic tinsels, comprising copper, which are brought into contact with the ITO layer, these tinsels being arranged between the said layer and the sheet of plastic material with an index greater than that of air, coated against the said layer.

30. A window glass according to claim 29, wherein two electrical connections to which the tinsels are attached are essentially at the same location, in an extension of one power lead strip formed by one of the tinsels, another power lead strip formed by the other tinsel, passing at the side of the sheet of flexible material with an index greater than that of air and not in contact with the ITO layer, through an incision made in this sheet and leading to a common position of exit, and being insulated from the ITO layer by the thickness of the sheet of flexible material.

31. A window glass according to claim 1, it is encapsulated in a plastic about its periphery.

32. The curved window glass of claim 1, wherein the conductive ITO layer has a uniform square resistivity equal to or less than 10 ohms.

33. A curved window glass prepared by coating a flat sheet of glass with an electroconductive layer of metal oxide comprised of indium tin oxide (ITO) obtained by pyrolysis, followed by a reduction treatment, of a powdered mixture of a tin compound and an indium compound, on face 3 of the faces of said curved window glass numbered conventionally 1, 2, 3 and 4 proceeding from the outside to the inside of the space enclosed by the window glass, followed by bending of the glass sheet thereby shaping the glass such that face 3 is convex, and then covering the ITO layer with a sheet of flexible polyvinylbutyral, and finally completing the curved windshield by placing a bent glass sheet over the polyvinylbutyral layer.