Totally consumable brazing encapsulate for use in joining aluminum surfaces

• US 5,418,072 A
• Filed: 09/20/1993
• Issued: 05/23/1995
• Est. Priority Date: 09/20/1993
• Status: Expired due to Fees

• Current Assignee: Alcan Incorporated (Alcan)
• Original Assignee: Alcan Incorporated (Alcan)
• Inventors: Baldantoni, Antonio, Timsit, Roland S.
• Primary Examiner(s): Walsh, Donald P.
• Assistant Examiner(s): Greaves, John N.
• Application Number:
  US08/124,159
• Time in Patent Office: 610 Days
• Field of Search: 428/545, 428/548, 428/551, 428/552, 428/553, 428/554, 428/557, 428/558, 428/564, 419/5, 419/8, 419/9, 419/23, 419/25, 419/38, 419/47, 419/46
• US Class Current: 428/558
• CPC Class Codes: B23K 2103/05 Stainless steel
• CPC Class Codes: B23K 2103/08 Non-ferrous metals or alloys
• CPC Class Codes: B23K 2103/10 Aluminium or alloys thereof
• CPC Class Codes: B23K 2103/12 Copper or alloys thereof
• CPC Class Codes: B23K 2103/18 Dissimilar materials
• CPC Class Codes: B23K 2103/20 Ferrous alloys and aluminium or alloys thereof
• CPC Class Codes: B23K 35/0227 Rods, wires B23K35/0244 takes precedence
• CPC Class Codes: B23K 35/0238 layered
• CPC Class Codes: B23K 35/286 Al as the principal constituent
• CPC Class Codes: B23K 35/288 with Sn or Zn
• CPC Class Codes: B23K 35/3605 Fluorides
• CPC Class Codes: B23K 35/368 Selection of non-metallic compositions of core materials either alone or conjoint with selection of soldering or welding materials
• CPC Class Codes: Y10T 428/12007 Component of composite having metal continuous phase interengaged with nonmetal continuous phase
• CPC Class Codes: Y10T 428/12028 Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
• CPC Class Codes: Y10T 428/12049 Nonmetal component
• CPC Class Codes: Y10T 428/12056 Entirely inorganic
• CPC Class Codes: Y10T 428/12063 Nonparticulate metal component
• CPC Class Codes: Y10T 428/12069 Plural nonparticulate metal components
• CPC Class Codes: Y10T 428/1209 Plural particulate metal components
• CPC Class Codes: Y10T 428/12097 Nonparticulate component encloses particles
• CPC Class Codes: Y10T 428/12139 : Nonmetal particles in particulate component

Abstract

A consumable brazing encapsulate is used for joining aluminum to metal surfaces, e.g. aluminum, copper, brass or steel surfaces, by brazing. The encapsulate comprises a mixture of particles of an eutectic forming metal selected from the group consisting of silicon, germanium, copper and zinc and particles of a brazing flux encapsulated in a layer or layers of aluminum or its alloys, said eutectic forming metal and flux being present in the following parts by weight per 100 parts by weight of the total aluminum in the encapsulate: (a) 7 to 15 parts of silicon and 7 to 45 parts of flux; (b) 25 to 120 parts of germanium and 100 to 250 parts of flux; (c) 40 to 70 parts of copper and 20 to 100 parts of flux; (d) 1300 to 2400 parts of zinc and 1000 to 2000 parts of flux; such that when the encapsulate is placed between aluminum surfaces to be joined and is heated, the eutectic forming metal and the encapsulating aluminum are totally converted in situ into an eutectic filler metal for joining the aluminum surfaces. It may also be in the form of a consumable brazing laminate in which the mixture of particles are bonded to an aluminum substrate by means of a binding agent.

Claims

1. A consumable brazing encapsulate for use in joining aluminum to metal surfaces, said encapsulate comprising a mixture of particles of an eutectic forming metal selected from the group consisting of silicon, germanium, copper and zinc and particles of a brazing flux encapsulated in a layer or layers of aluminum or its alloys, said eutectic forming metal and flux being present in the following parts by weight per 100 parts by weight of the total aluminum in the encapsulate:

(a) 7 to 15 parts of silicon and 7 to 45 parts of flux;

(b) 25 to 120 parts of germanium and 100 to 250 parts of flux;

(c) 40 to 70 parts of copper and 20 to 100 parts of flux;

(d) 1300 to 2400 parts of zinc and 70 to 200 parts of flux;

such that when the encapsulate is placed between aluminum surfaces to be joined and is heated, the eutectic forming metal and the encapsulating aluminum are totally converted in situ into an eutectic filler metal for joining the aluminum surfaces.

2. An encapsulate according to claim 1 wherein the encapsulated mixture includes aluminum powder.

3. An encapsulate according to claim 1 wherein the encapsulated mixture comprises a mixture of flux particles and particles of one or more hypereutectic alloys selected from the group consisting of Al-Si, Al-Ge, Al-Cu and Al-Zn.

4. An encapsulate according to claim 3 wherein the encapsulated mixture also includes aluminum powder.

5. An encapsulate according to claim 1 wherein the encapsulated mixture comprises a mixture of particles of one or more aluminum alloys, particles of one ore more of silicon germanium, copper and zinc or particles of one or more hypereutectic alloys selected from Al-Si, Al-Ge, Al-Cu and Al-Zn and particles of flux.

6. An encapsulate according to claim 5 wherein the aluminum alloy particles are alloys containing alloying amounts of one or more of Cu, Mn, Zn, Fe and Si.

7. An encapsulate according to claim 1 wherein the flux is a potassium fluoroaluminate brazing flux which melts below 600°

C. and which in molten state is adapted to remove oxide film from aluminum surfaces.

8. An encapsulate according to claim 1 wherein the flux is present in an amount sufficient to remove oxide film from the encapsulating aluminum surface adjacent the eutectic forming metal and to remove oxide film from aluminum surfaces being joined by the brazing encapsulate.

9. An encapsulate according to claim 8 wherein the mixture of particles also includes a binder capable of volatilizing at a temperature below the melting point of the flux and the eutectic alloy.

10. An encapsulate according to claim 8 wherein the brazing flux has an elemental composition by weight of:

20 to 45% K;

10 to 25% Al and 45 to 60% F.

11. An encapsulate according to claim 8 wherein the brazing flux has a composition, expressed in terms of the weight of the equivalent simplest compounds of 40 to 70% AlF₃ and 30 to 60% KF.

12. An encapsulate according to claim 8 wherein the mixture of particles additionally contains at least one other particulate material for modifying the nature of the brazing joint, said at least one other particulate material being at least one metal selected from the group consisting of Be, Cu, Fe, Mn, Ni, Zn, Bi, Sr, Cr, Sb and V.

13. An encapsulate according to claim 8 in the form of a hollow aluminum wire with said mixture of particles forming a central core therein.

14. An encapsulate according to claim 8 comprising a sandwich structure with said mixture of particles held between aluminum cover sheets.

15. An encapsulate according to claim 8 comprising a hollow extrusion with aluminum surrounding said mixture of particles.

16. An encapsulate according to claim 8 wherein the particles of eutectic forming metal have sizes in the range of 4 to 150 μ

m.

17. An encapsulate according to claim 16 wherein the particles of eutectic forming metal have sizes in the range of 4 to 100 μ

m.

18. An encapsulate according to claim 16 wherein the particles of eutectic forming metal have sizes in the range of 50 to 100 μ

m.

19. An encapsulate according to claim 16 wherein the aluminum forming the layer or layers comprises commercially pure aluminum or a ductile aluminum alloy.

20. A consumable brazing laminate for use in joining aluminum to metal surfaces, said laminate comprising an aluminum or aluminum alloy substrate having bonded thereto a mixture of particles of an eutectic forming metal selected from the group consisting of silicon, germanium, copper and zinc and particles of a brazing flux, said eutectic forming metal and flux being present in the following parts by weight per 100 parts by weight of the total aluminum in the laminate:

(a) 7 to 15 parts of silicon and 7 to 45 parts of flux;

(b) 25 to 120 parts of germanium and 100 to 250 parts of flux;

(c) 40 to 70 parts of copper and 20 to 100 parts of flux;

(d) 1300 to 2400 parts of zinc and 70 to 200 parts of flux;

such that when the laminate is placed between aluminum surfaces to be joined and is heated, the eutectic forming metal and the aluminum substrate are totally converted in situ into an eutectic filler metal for joining the aluminum surfaces.

21. A laminate according to claim 20 wherein the particles are bonded by a binder capable of volatilizing at a temperature below the melting point of the flux and the eutectic alloy.

22. A laminate according to claim 21 wherein the particle mixture includes aluminum powder.

23. A laminate according to claim 21 wherein the particle mixture comprises a mixture of flux particles and particles of one or more hypereutectic alloys selected from the group consisting of Al-Si, Al-Ge, Al-Cu and Al-Zn.

24. A laminate according to claim 23 wherein the particle mixture also includes aluminum powder.

25. A laminate according to claim 21 wherein the particle mixture comprises a mixture of particles of one or more aluminum alloys, particles of one ore more of silicon germanium, copper and zinc or particles of one or more hypereutectic alloys selected from Al-Si, Al-Ge, Al-Cu and Al-Zn and particles of flux.

26. A laminate according to claim 25 wherein the aluminum alloy particles are alloys containing alloying amounts of one or more of Cu, Mn, Zn, Fe and Si.

27. A laminate according to claim 21 wherein the flux is a potassium fluoroaluminate brazing flux which melts below 600°

C. and which in molten state is adapted to remove oxide film from aluminum surfaces.

28. A laminate according to claim 21 wherein the flux is present in an amount sufficient to remove oxide film from the encapsulating aluminum surface adjacent the eutectic forming metal and to remove oxide film from aluminum surfaces being joined by the brazing encapsulate.

29. A laminate according to claim 28 wherein the brazing flux has an elemental composition by weight of:

20 to 45% K;

10 to 25% Al and 45 to 60% F.

30. A laminate according to claim 28 wherein the brazing flux has a composition, expressed in terms of the weight of the equivalent simplest compounds of 40 to 70% AlF₃ and 30 to 60% KF.

31. A laminate according to claim 28 wherein the mixture of particles additionally contains at least one other particulate material for modifying the nature of the brazing joint, said at least one other particulate material being at least one metal selected from the group consisting of Be, Cu, Fe, Mn, Ni, Zn, Bi, Sr, Cr, Sb and V.