Electrophotographic photosensitive member, and electrophotographic apparatus and device unit employing the same

• US 5,418,099 A
• Filed: 05/18/1993
• Issued: 05/23/1995
• Est. Priority Date: 05/19/1992
• Status: Expired due to Term

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Aoki, Katsumi, Fujimura, Naoto, Sakai, Kiyoshi, Yoshihara, Toshiyuki, Anayama, Hideki, Ainoya, Hideyuki, Hanami, Nobuyuki, Kishi, Junichi, Mayama, Shinya
• Primary Examiner(s): GOODROW, JOHN L
• Application Number:
  US08/062,224
• Time in Patent Office: 735 Days
• Field of Search: 430/58, 430/59, 430/96, 430/66, 355/211
• US Class Current: 430/59.6
• CPC Class Codes: C08G 64/085 containing silicon
• CPC Class Codes: C08G 77/448 containing polycarbonate sequences
• CPC Class Codes: G03G 5/14756 Polycarbonates
• CPC Class Codes: G03G 5/14773 Polycondensates comprising silicon atoms in the main chain

Abstract

The present invention relates to an electrophotographic photosensitive member comprising an electroconductive support and a photosensitive layer formed thereon: the surface layer of the electrophotographic photosensitive member containing a first copolymer of a first construction unit represented by Formula (1) and a second construction unit represented by Formula (2), and a second copolymer of a third construction unit represented by Formula (3) and a fourth construction unit represented by Formula (4): ##STR1##

Claims

1. An electrophotographic photosensitive member comprising an electroconductive support and a photosensitive layer formed thereon:

the surface layer of the electrophotographic photosensitive member containing a first copolymer having a first construction unit represented by Formula (1) and a second construction unit represented by Formula (2), and a second copolymer having a third construction unit represented by Formula (3) and a fourth construction unit represented by Formula (4);

##STR45## wherein A is a group of alkylidene, arylene, arylenedialkylidene, --O--, --S--, --CO--, --SO--, or --SO₂ --, and R_1-1 to R_1-8 are independently a hydrogen atom, an alkyl group, an aryl group, or a halogen atom;

##STR46## wherein R_2-1 is an alkylene group or an alkylidene group, and R_2-2 to R_2-5 are independently a hydrogen atom, an alkyl group, or an aryl group, and n is an integer of 1 to 200;

##STR47## wherein R_3-1 to R_3-8 are independently a hydrogen atom, an alkyl group, an aryl group, or a halogen atom;

##STR48## wherein B is an alkylidene group, an arylene group, and an arylenedialkylidene group, and R_4-1 to R_4-8 are independently a hydrogen atom, an alkyl group, an aryl group, or a halogen atom.

2. An electrophotographic photosensitive member according to claim 1, wherein the surface layer further contains a polycarbonate having a construction unit represented by Formula (9) below:

##STR49## wherein D is a group of alkylidene, arylene, or arylenedialkylidene; and

R_9-1 to R_9-8 are independently a hydrogen atom, an alkyl group, an aryl group or a halogen atom.

3. An electrophotographic photosensitive member according to claim 1, wherein the surface layer is a photosensitive layer.

4. An electrophotographic photosensitive member according to claim 3, wherein the photosensitive layer comprises a charge-generating layer and a charge-transporting layer, and the charge-transporting layer is the surface layer.

5. An electrophotographic photosensitive member according to claim 1, wherein the electrophotographic photosensitive member has a protection layer on the photosensitive layer, and the protection layer is the surface layer.

6. An electrophotographic photosensitive member according to claim 1, wherein the electrophotographic photosensitive member has a subbing layer between the electroconductive support and the photosensitive layer.

7. An electrophotographic photosensitive member according to claim 2, wherein the surface layer is a photosensitive layer.

8. An electrophotographic photosensitive member according to claim 7, wherein the photosensitive layer comprises a charge-generating layer and a charge-transporting layer, and the charge-transporting layer is the surface layer.

9. An electrophotographic photosensitive member according to claim 2, wherein the electrophotographic photosensitive member has a protection layer on the photosensitive layer, and the protection layer is the surface layer.

10. An electrophotographic photosensitive member according to claim 2, wherein the electrophotographic photosensitive member has a subbing layer between the electroconductive support and the photosensitive layer.

11. An electrophotographic apparatus, comprising an electrophotographic photosensitive member, an image-forming means for forming an electrostatic latent image, a developing means for developing the formed latent image, and a transferring means for transferring the developed image to an image-receiving material;

said electrophotographic photosensitive member comprising an electroconductive support and a photosensitive layer formed thereon;

the surface layer of the electrophotographic photosensitive member containing a first copolymer having a first construction unit represented by Formula (1) and a second construction unit represented by Formula (2), and a second copolymer having a third construction unit represented by Formula (3) and a fourth construction unit represented by Formula (4);

##STR50## wherein A is a group of alkylidene, arylene, arylenedialkylidene, --O--, --S--, --CO--, --SO--, or --SO₂ --, and R_1-1 to R_1-8 are independently a hydrogen atom, an alkyl group, an aryl group, or a halogen atom;

##STR51## wherein R_2-1 is an alkylene group or an alkylidene group, and R_2-2 to R_2-5 are independently a hydrogen atom, an alkyl group, or an aryl group, and n is an integer of 1 to 200;

##STR52## wherein R_3-1 to R_3-8 are independently a hydrogen atom, an alkyl group, an aryl group, or a halogen atom;

##STR53## wherein B is an alkylidene group, an arylene group, and an arylenedialkylidene group, and R_4-1 to R_4-8 are independently a hydrogen atom, an alkyl group, an aryl group, or a halogen atom.

12. A device unit, comprising an electrophotographic photosensitive member, and at least one means selected from the group consisting of a charging means, a developing means, and a cleaning means;

said electrophotographic photosensitive member comprising an electroconductive support and a photosensitive layer formed thereon;

the surface layer of the electrophotographic photosensitive member containing a first copolymer having a first construction unit represented by Formula (1) and a second construction unit represented by Formula (2), and a second copolymer having a third construction unit represented by Formula (3) and a fourth construction unit represented by Formula (4);

##STR54## wherein A is a group of alkylidene, arylene, arylenedialkylidene, --O--, --S--, --CO--, --SO--, or --SO₂ --, and R_1-1 to R_1-8 are independently a hydrogen atom, an alkyl group, an aryl group, or a halogen atom;

##STR55## wherein R_2-1 is an alkylene group or an alkylidiene group, and R_2-2 to R_2-5 are independently a hydrogen atom, an alkyl group, or an aryl group, and n is an integer of 1 to 200;

##STR56## wherein R_3-1 to R_3-8 are independently a hydrogen atom, an alkyl group, an aryl group or a halogen atom;

##STR57## wherein B is an alkylidene group, an arylene group, and an arylenedialkylidene group, and R_4-1 to R_4-8 are independently a hydrogen atom, an alkyl group, an aryl group, or a halogen atom; and

said unit supporting integrally the electrophotographic photosensitive member and said at least one of the charging means, the developing means, and the cleaning means, and being removable from the main body of an electrophotographic apparatus.