IR-based nitric oxide sensor having water vapor compensation

• US 5,418,366 A
• Filed: 05/05/1994
• Issued: 05/23/1995
• Est. Priority Date: 05/05/1994
• Status: Expired due to Term

• Current Assignee: Envirotest Corp. (Opus Group AB)
• Original Assignee: Santa Barbara Research Center
• Inventors: Jack, Michael D., Rubin, Lane H.
• Primary Examiner(s): Hannaher, Constantine
• Assistant Examiner(s): Glick, Edward J.
• Application Number:
  US08/239,151
• Time in Patent Office: 383 Days
• Field of Search: 250/338.5, 250/339.09, 250/339.13, 250/343, 250/252.1 A, 250/252.1 R, 356/438, 356/439, 356/246
• US Class Current: 250/338.5
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis
• CPC Class Codes: G01N 33/0037 for NOx
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Abstract

A system (10) for detecting nitric oxide (NO) within an exhaust plume (14) includes a source (18) for generating an optical beam (20) and for directing (22, 24) the optical beam through the exhaust plume, the optical beam having wavelengths within a predetermined band of wavelengths within the infrared (IR) radiation spectrum. The system includes a sensor (32)/filter (30) assembly having a first channel for determining a measured NO transmission value for a first predetermined band of wavelengths; a second channel for determining a measured water transmission value for a second predetermined band of wavelengths; a third channel for determining a measured reference transmission value for a third predetermined band of wavelengths selected so as not to be significantly absorbed by the exhaust plume; and a fourth channel for determining a measured combustion by-product transmission value for a fourth predetermined band of wavelengths. A data processor (38) is responsive to the outputs of the channels for determining an effective NO transmission value from the measured NO transmission value that is scaled by (a) the measured water transmission value, (b) a predetermined factor that compensates for absorption by water within the first predetermined band of wavelengths, and (c) the reference transmission value. The data processor is further operable for converting the effective NO transmission value to a relative NO concentration value using a predetermined calibration factor and for converting the relative NO concentration value to an actual NO concentration value utilizing the measured combustion by-product transmission value.

Claims

1. A system for determining a concentration of NO in an exhaust plume, comprising:

a source of electromagnetic radiation for directing radiation having a plurality of wavelengths along an optical path that passes through the plume;

first sensor means having an output for indicating an amount of absorption of the radiation, within a band of first wavelengths, that is due to the presence of NO in the plume;

second sensor means having an output for indicating an amount of absorption of the radiation, within a band of second wavelengths, that is due to the presence of water along the optical path; and

means, having inputs coupled to the outputs of said first sensor means and said second sensor means, for compensating the indicated absorption within the first band of wavelengths in accordance with the indicated absorption within the second band of wavelengths and in accordance with a predetermined NO absorption modifying factor.

2. A system as set forth in claim 1 wherein the predetermined NO absorption modifying factor is stored within a lookup table means.

3. A system as set forth in claim 1 and further comprising:

third sensor means having an output for indicating an amount of absorption of the radiation, within a band of third wavelengths, that is due to the presence of a predetermined combustion product in the plume; and

wherein

said determining means includes means for determining a concentration of NO in the plume from the compensated indicated absorption within the first band of wavelengths and in accordance with the indication from said output of said third sensor means.

4. A system as set forth in claim 3 wherein the predetermined combustion product is CO₂.

5. A system as set forth in claim 3 and further comprising a calibration cell that is interposed between said first, second and third sensor means and the plume such that the radiation passes through said calibration cell, said calibration cell comprising a compartment having a volume that contains NO, water, and at least one combustion product in a predetermined concentration, said calibration cell further including means for controllably varying the volume of said compartment.

6. A system as set forth in claim 1 and further comprising:

fourth sensor means having an output for indicating a variation in the intensity of the radiation within a band of fourth wavelengths that are selected so as not to be significantly absorbed within the plume; and

wherein

said determining means is responsive to said output of said fourth sensor means for compensating the indicated absorption within the first band of wavelengths and also the indicated absorption within the second band of wavelengths in accordance with the indication output by said fourth sensor means.

7. A system as set forth in claim 1 wherein said source of electromagnetic radiation outputs radiation within a band of wavelengths that includes a band from approximately 3 microns to approximately 6 microns, wherein said first band of wavelengths includes a wavelength of approximately 5.26 microns, and wherein said second band of wavelengths includes a wavelength of approximately 5.02 microns.

8. A system as set forth in claim 1 wherein said first sensor means includes a first photodetector and a first filter interposed between the first photodetector and the plume, wherein the first filter has a wavelength passband of predetermined width that includes a wavelength of 5.26 microns;

and wherein said second sensor means includes a second photodetector and a second filter interposed between the second photodetector and the plume, wherein the second filter has a wavelength passband of predetermined width that includes a wavelength of 5.02 microns.

9. A system as set forth in claim 8 and further comprising means for homogenizing the radiation after the radiation passes through the plume, said homogenizing means being interposed between each of said first and second filters and said plume.

10. A method for determining a concentration of NO in an exhaust plume, comprising the steps of:

passing an optical beam through an exhaust plume, the optical beam having wavelengths within a predetermined band of wavelengths within the infrared radiation spectrum;

determining a measured NO transmission value for a first predetermined band of wavelengths;

determining a measured water transmission value for a second predetermined band of wavelengths;

determining a measured reference transmission value for a third predetermined band of wavelengths selected so as not to be significantly absorbed by the exhaust plume;

determining a measured combustion by-product transmission value for a fourth predetermined band of wavelengths;

determining an effective NO transmission value from the measured NO transmission value that is scaled by (a) the measured water transmission value, (b) a predetermined factor that compensates for absorption by water within the first predetermined band of wavelengths, and (c) the reference transmission value;

converting the effective NO transmission value to a relative NO concentration value using a predetermined calibration factor; and

converting the relative NO concentration value to an actual NO concentration value utilizing the measured combustion by-product transmission value.

11. A method as set forth in claim 10 wherein the predetermined combustion by-product is CO₂.

12. A method as set forth in claim 10 wherein the exhaust plume is generated by a motor vehicle, and further comprising the steps of:

comparing the actual NO concentration value to a predetermined value; and

, if the actual NO concentration value exceeds the predetermined value,

recording an identifying characteristic of the motor vehicle in association with the actual NO concentration value.

13. A method as set forth in claim 10 wherein the step of determining an effective NO transmission value (T(NO)_eff) is accomplished in accordance with:

space="preserve" listing-type="equation">T(NO).sub.eff =T(NO)/(T(H.sub.2 O)×

{Lookup(H.sub.2 O band to NO band)}×

T(REF)),

where, T(NO) is the measured NO transmission value, T(H₂ O) is the measured water transmission value, Lookup(H₂ O band to NO band) is a predetermined water/NO absorption correction, and T(REF) is the measured reference transmission value for the third predetermined band of wavelengths.

14. A system for detecting at least one predetermined pollutant within an exhaust plume, comprising:

means for generating an optical beam and for directing the optical beam through an exhaust plume, the optical beam having wavelengths within a predetermined band of wavelengths within the infrared radiation spectrum;

first means for determining a measured NO transmission value for a first predetermined band of wavelengths;

second means for determining a measured water transmission value for a second predetermined band of wavelengths;

third means for determining a measured reference transmission value for a third predetermined band of wavelengths selected so as not to be significantly absorbed by the exhaust plume;

fourth means for determining a measured combustion by-product transmission value for a fourth predetermined band of wavelengths; and

a data processor having inputs coupled to an output of each of said first, second, third and fourth determining means, said data processor being responsive to said outputs for determining an effective NO transmission value from the measured NO transmission value that is scaled by (a) the measured water transmission value, (b) a predetermined factor that compensates for absorption by water within the first predetermined band of wavelengths, and (c) the reference transmission value;

said data processor including means for converting the effecting NO transmission value to a relative NO concentration value using a predetermined calibration factor; and

means for converting the relative NO concentration value to an actual NO concentration value utilizing the measured combustion by-product transmission value.

15. A system as set forth in claim 14 wherein the predetermined combustion by-product is CO₂.

16. A system as set forth in claim 14 wherein the exhaust plume is generated by a motor vehicle, and wherein said data processor is operable for comparing the actual NO concentration value to a predetermined value;

and, if the actual NO concentration value exceeds the predetermined value, for recording an identifying characteristic of the motor vehicle in association with the actual NO concentration value.

17. A system as set forth in claim 14 wherein said first determining means includes a first photodetector and a first filter interposed between the first photodetector and the plume, wherein the first filter has a wavelength passband of predetermined width that includes a wavelength that is strongly absorbed by NO.

18. A system as set forth in claim 14 wherein said first determining means includes a first photodetector and a first filter interposed between the first photodetector and the plume, wherein the first filter has a wavelength passband of predetermined width that includes a wavelength of 5.265 microns;

and wherein said second determining means includes a second photodetector and a second filter interposed between the second photodetector and the plume, wherein the second filter has a wavelength passband of predetermined width that includes a wavelength of 5.02 microns.

19. A system as set forth in claim 18 and further comprising means for homogenizing the radiation after the radiation passes through the plume, said homogenizing means being interposed between each of said first and second filters and said plume.

20. A system as set forth in claim 14 and further comprising a calibration cell that is interposed between said first, second, third and fourth sensor means and the plume such that the radiation passes through said calibration cell, said calibration cell comprising a compartment having a volume that contains NO, water, and at least one combustion product in a predetermined concentration, said calibration cell further including means for controllably varying the volume of said compartment.

21. A calibration cell for use in calibrating a pollution monitoring system, comprising:

a sealed housing having a plurality of compartments including a first compartment and a second compartment, said first and second compartments being separated by a movable partition;

means for causing a movement of said partition, the movement causing a volume of said first compartment to increase while simultaneously causing a volume of said second compartment to decrease;

a sealed reservoir coupled to said second compartment whereby a gas mixture is enabled to flow between said reservoir and said second compartment, said gas mixture including a plurality of by-products of combustion of a fuel;

wherein

at least a portion of said housing and said partition are substantially transparent to a beam of electromagnetic radiation having wavelengths within a band of wavelengths employed by a pollution monitoring system such that the beam is enabled to pass through said first compartment, said second compartment, the gas mixture contained within said second compartment, and through said partition.

22. A calibration cell as set forth in claim 21 wherein said partition is comprised of a first piston and a second piston, said first and second pistons each comprising a magnetic portion arranged so that a movement of said first piston causes a corresponding movement of said second piston due to a repelling force exerted by said magnetic portions.

23. A calibration cell as set forth in claim 21 wherein said gas mixture is comprised of predetermined percentages of at least NO, H₂ O, and CO₂.

24. A calibration cell as set forth in claim 21 wherein said means for causing a movement of said partition includes means for varying a gas pressure within said calibration cell, the variation in the gas pressure causing a motion of said partition.