Water resistant, removable acrylic emulsion pressure sensitive adhesive

• US 5,420,195 A
• Filed: 01/10/1992
• Issued: 05/30/1995
• Est. Priority Date: 01/10/1992
• Status: Expired due to Term

• Current Assignee: Avery Dennison Corporation
• Original Assignee: Avery Dennison Corporation
• Inventors: Keller, Paul, Mayer, Andre
• Primary Examiner(s): Michl, Paul R.
• Assistant Examiner(s): CAIN, EDWARD J
• Application Number:
  US07/819,114
• Time in Patent Office: 1,236 Days
• Field of Search: 524/556, 524/560, 524/561, 526/370, 526/371
• US Class Current: 524/556
• CPC Class Codes: C08F 220/1804 C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
• CPC Class Codes: C08F 2800/20 as weight or mass percentages
• CPC Class Codes: C08F 2810/20 leading to a crosslinking, either explicitly or inherently
• CPC Class Codes: C08F 8/00 Chemical modification by after-treatment graft polymers, block polymers, crosslinking with unsaturated monomers or with polymers C08F251/00 - C08F299/00; of conjugated diene rubbers C08C
• CPC Class Codes: C08L 2666/54 Inorganic substances
• CPC Class Codes: C09J 133/08 Homopolymers or copolymers of acrylic acid esters
• CPC Class Codes: C09J 2301/302 the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C

Abstract

A water-resistant, removable pressure sensitive adhesive for use with transparent film facestocks comprises an acrylic-based emulsion polymer composition comprising 85 to 97% by weight alkyl acrylate monomers, up to 3% by weight polar monomers, up to 1% by weight internal crosslinking agent and up to 2% by weight external crosslinking agent.

Claims

1. A water-resistant removable acrylic emulsion pressure-sensitive adhesive polymer comprising:

a. from about 85% to about 97% by weight alkyl acrylate monomers having from about 4 to about 8 carbon atoms in the alkyl chain;

b. a positive amount up to about 3% by weight of polar monomers selected from the group consisting of methacrylic acid, acrylic acid, itaconic acid, maleic acid, acrylamide, methacrylamide, 2-hydroxy ethyl acrylate and mixtures thereof; and

crosslinked with

c. a positive amount up to about 2% by weight of an external metal salt cross-linking agent, said pressure-sensitive polymer being formed by emulsion polymerization in the presence of up to about 2% by weight surfactant.

2. A pressure-sensitive adhesive as claimed in claim 1 wherein the alkylacrylate is selected from the group consisting of 2-ethylhexyl acrylate, butyl acrylate, heptyl acrylate, octyl acrylate, isooctyl acrylate, and isobutyl acrylate.

3. A pressure-sensitive adhesive as claimed in claim 1 wherein the external cross-linking agent is selected from the group consisting of zirconium ammonium carbonate, zinc ammonium carbonate, aluminum acetate and zinc acetate.

4. A pressure-sensitive adhesive as claimed in claim 1 wherein up to about 15% of the alkylacrylate is replaced by a hard monomer.

5. A pressure-sensitive adhesive as claimed in claim 4 wherein the hard monomer is selected from the group consisting of vinyl acetate, styrene, methyl methacrylate and vinyl pyrrolidone.

8. A water-resistant, removable pressure-sensitive adhesive as claimed in claim 1 in which the pressure-sensitive adhesive is formed in the presence of a redox emulsion polymerization catalyst.

9. A pressure-sensitive adhesive as claimed in claim 8 in which the redox emulsion polymerization catalyst comprises a peroxide oxidant and a reductant selected from the group consisting of ascorbic acid and sodium formaldehyde sulfoxylate.

10. A pressure-sensitive adhesive as claimed in claim 9 in which the peroxide is selected from the group consisting of hydrogen peroxide and hydroperoxides.

14. A pressure-sensitive adhesive as claimed in claim 1 in which there is present during formation of the polymer a positive amount up to about 1% by weight of the pressure-sensitive adhesive of an internal cross-linking agent.

15. A pressure-sensitive adhesive as claimed in claim 14 wherein the internal crosslinking agent is selected from the group consisting of polyethylene glycol diacrylate, hexanediol diacrylate, ethoxylated trimethylolpropane triacrylate, pentaeythritol triacrylate, propyleneglycol diacrylate, diallyl maleate, diallyl phthalate and trimethylolpropane trimethacrylate.

6. A water-resistant, removable pressure-sensitive adhesive construction comprising:

a film facestock;

a water-resistant, removable pressure-sensitive adhesive applied to the bottom surface of the film facestock, said pressure-sensitive adhesive comprising;

from about 85% to about 97% by weight alkyl acrylate monomers;

having from about 4 to about 8 carbon atoms in the alkyl chain;

a positive amount of up to about 3% by weight of polar monomers selected from the group consisting of methacrylic acid, acrylic acid, itaconic acid, maleic acid, acrylamide, methacrylamide, 2-hydroxy ethyl acrylate and mixtures thereof; and

crosslinked with

a positive amount of up to about 2% by weight of an external metal salt cross-linking agent selected from the group consisting of zirconium ammonium carbonate, zinc ammonium carbonate, aluminum acetate and zinc acetate, said water-resistant removable pressure-sensitive adhesive being formed by emulsion polymerization in the presence of up to about 2% by weight surfactant based on the weight of the monomers said crosslinked pressure-sensitive adhesive having a peel adhesion to stainless steel of about 50 to about 300 N/m.

7. A construction as claimed in claim 6 wherein up to about 15% of the alkyl acrylate monomers are replaced by hard monomers.

11. A construction as claimed in claim 6 in which the adhesive is formed by emulsion polymerization in the presence of a redox emulsion polymerization catalyst.

12. A construction as claimed in claim 11 in which the redox emulsion polymerization catalyst comprises a peroxide oxidant and a reductant selected from the group consisting of ascorbic acid and sodium formaldehyde sulfoxylate.

13. A construction as claimed in claim 12 in which the peroxide is selected from the group consisting of hydrogen peroxide and hydroperoxides.

16. A construction as claimed in claim 6 in which there is present during formation of the polymer a positive amount up to about 1% by weight of the pressure-sensitive adhesive of an internal cross-linking agent.

17. A construction as claimed in claim 16 wherein the internal cross-linking agent is selected from the group consisting of polyethylene glycol diacrylate, hexanediol diacrylate, ethoxylated trimethylolpropane triacrylate, pentaeythritol triacryiate, propyleneglycol diacrylate, diallyl maleate, diallyl phthalate and trimethylolpropane trimethacrylate.