Polymeric sheet having oriented multilayer interference thin film flakes therein, product using the same and method

• US 5,424,119 A
• Filed: 02/04/1994
• Issued: 06/13/1995
• Est. Priority Date: 02/04/1994
• Status: Expired due to Term

• Current Assignee: Viavi Solutions, Inc. (Lumentum Holdings Inc.)
• Original Assignee: Flex Products Incorporated (Sicpa Holding SA)
• Inventors: Phillips, Roger W., Coombs, Paul G., Markantes, Charles T., Higgins, Patrick K.
• Primary Examiner(s): SLUBY, PATRICIA
• Application Number:
  US08/191,992
• Time in Patent Office: 494 Days
• Field of Search: 428/403, 428/328, 428/329, 428/330, 428/331, 428/404, 428/412, 428/480, 428/913, 428/483, 428/916, 264/176.1, 264/144, 264/132, 264/177.2, 264/108, 264/112
• US Class Current: 428/328
• CPC Class Codes: B29C 41/24 for making articles of indefinite length
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/18 the components being layers
• CPC Class Codes: B29C 48/19 the layers being joined at their edges
• CPC Class Codes: B29C 55/12 biaxial
• CPC Class Codes: B29C 70/62 the filler being oriented during moulding for short fibres B29C70/14
• CPC Class Codes: B29D 7/01 Films or sheets
• CPC Class Codes: B29K 2105/0032 Pigments, colouring agents or opacifiyng agents
• CPC Class Codes: B29K 2105/18 oriented
• CPC Class Codes: B29K 2995/002 Coloured
• CPC Class Codes: B29K 2995/003 Reflective
• CPC Class Codes: B29K 2995/0053 bi-axially
• CPC Class Codes: B32B 2307/518 bi-axially
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 37/153 at least one layer is extruded and immediately laminated while in semi-molten state
• CPC Class Codes: B41M 3/14 Security printing securities B42D25/29
• CPC Class Codes: B42D 25/355 Security threads
• CPC Class Codes: Y10S 428/916 Fraud or tamper detecting
• CPC Class Codes: Y10T 428/24124 Fibers
• CPC Class Codes: Y10T 428/256 Heavy metal or aluminum or compound thereof
• CPC Class Codes: Y10T 428/257 : Iron oxide or aluminum oxide
• CPC Class Codes: Y10T 428/258 : Alkali metal or alkaline earth metal or compound thereof
• CPC Class Codes: Y10T 428/259 : Silicic material
• CPC Class Codes: Y10T 428/2991 : Coated
• CPC Class Codes: Y10T 428/2993 : Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
• CPC Class Codes: Y10T 428/31507 : Of polycarbonate
• CPC Class Codes: Y10T 428/31786 : Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/31797 : Next to addition polymer from unsaturated monomers

Abstract

A polymeric sheet comprising a layer of polymeric material having a first and second parallel surfaces. A plurality of oriented multilayer interference thin film flakes are disposed in the layer of polymeric material. The flakes have first and second parallel surfaces and a width and a thickness and have an aspect ratio of at least 2:1 for the width with respect to the thickness.

Claims

1. A polymeric sheet comprising a first layer of polymeric material having first and second parallel surfaces, a plurality of multilayer interference thin film flakes disposed in the first layer of polymeric material, said flakes having first and second parallel surfaces and a width and a thickness and having an aspect ratio of at least 2:

1 for the width with respect to the thickness, said flakes being oriented so that the flakes lie in planes with the first and second parallel surfaces of the flakes being substantially parallel to the first and second parallel surfaces of the first layer of polymeric material.

2. A sheet as in claim 1 together with a second layer of polymeric material adhered to said first layer, said second layer of polymeric material serving as a primary layer and said first layer of polymeric material serving as a secondary layer.

3. A sheet as in claim 2 wherein said flakes are optically variable.

4. A sheet as in claim 2 wherein said second layer is colored.

5. A sheet as in claim 2 wherein said first layer is amorphous.

6. A sheet as in claim 5 wherein said second layer is substantially crystalline.

7. A sheet as in claim 6 wherein said second layer of polymeric material has first and second parallel surfaces and wherein said first layer of polymeric material is disposed on the first surface of the second layer together with a third layer of polymeric material adhered to the second surface of the second layer, said third layer of polymeric material having a plurality of multilayer interference thin film flakes disposed therein, said flakes in the third layer being oriented so that the flakes lie in planes with the first and second parallel surfaces of the flakes being parallel to the first and second parallel surfaces of the third layer.

8. A sheet as in claim 1 which is extruded.

9. A sheet as in claim 1 which is cast.

10. A sheet as in claim 1 wherein said flakes are biaxially oriented.

18. A polymeric sheet as in claim 1 wherein at least one of said second and third layers is colored.

11. A polymeric sheet comprising a polymeric substrate having first and second surfaces and forming a primary layer, a secondary layer of a polymeric material disposed on each of said first and second surfaces, said secondary layer having a plurality of oriented multilayer interference thin film flakes disposed in the second layer, said flakes having first and second parallel surfaces and a width and a thickness to provide an aspect ratio of at least 2:

1 for the width with respect to the thickness, said oriented flakes lying in planes in the secondary layer with the first and second surfaces of the flakes being substantially parallel to the first and second surfaces of the secondary layer.

12. A polymeric sheet as in claim 11 wherein said primary layer and said secondary layer are coextruded.

13. A polymeric sheet as in claim 11 wherein said primary layer is crystalline and said secondary layer is amorphous.

14. A polymeric sheet as in claim 13 wherein both the primary and secondary layers are biaxially oriented.

15. A polymeric sheet as in claim 11 wherein the flakes are optically variable.

16. A polymeric sheet as in claim 11 wherein said primary layer is colored.

24. A product as in claim 15 wherein said flakes are optically variable.

17. A polymeric sheet comprising a layer of polymeric material having first and second parallel surfaces, a plurality of oriented multilayer interference thin film flakes disposed in said layer of polymeric material, said flakes having first and second parallel surfaces and a width and a thickness to provide an aspect ratio of at least 2:

1 for the width with respect to the thickness, said layer of polymeric material being biaxially oriented with the flakes lying in planes in the directions of the biaxial orientation with the first and second surfaces of the flakes being substantially parallel to the first and second surfaces of the layer, and an additional layer of polymeric material being disposed on each of the surfaces of the first named layer of polymeric material.

19. A polymeric sheet as in claim wherein said first layer of polymeric material and said second and third layers of polymeric material are coextruded.

20. A security product, a sheet of material having first and second surfaces, an optical article carried by the sheet of material, said optical article comprising a layer of polymeric material having first and second parallel surfaces, a plurality of oriented multilayer interference thin film flakes disposed in the layer of polymeric material, said flakes having first and second parallel surfaces and a width and a thickness and having an aspect ratio of at least 2:

1 for the width with respect to the thickness, the first and second parallel surfaces of the flakes lying parallel to the first and second surfaces of the layer of polymeric material.

21. A product as in claim 20 wherein said layer of polymeric material is biaxially oriented with the flakes lying in planes in the directions of the biaxial orientation with the first and second surfaces of the flakes being substantially parallel to the first and second surfaces of the layer.

22. A product as in claim 20 together with an additional layer of polymeric material adhered to the first named layer of polymeric material.

23. A product as in claim 22 wherein said additional layer of polymeric material is colored.

25. A product as in claim 20 wherein said article is in the form of an elongate strip and wherein said strip is at least partially embedded in the sheet of material.

26. A product as in claim 25 wherein said strip has portions and wherein said portions are visually exposed through at least one surface of the security document.

27. A product as in claim 26 wherein said strip has additional portions and wherein said additional portions are visually exposed on the other surface of the sheet of material.

28. A product as in claim 20 together with a sheet carrying an image disposed on the first surface underlying the optical article and wherein the optical article is semi-transparent to permit viewing of the image through the optical article.

29. A product as in claim 20 together with at least one filler agent in the form of a dye or pigment incorporated in the polymeric material.

30. A product as in claim 29 wherein said dye or pigment is selected to block out an undesired color at various angles.

31. A product as in claim 26 wherein said polymeric material is in the form of either a biaxially oriented polymeric layer or a cast layer.

32. A product as in claim 31 together with a dye or pigment being disposed in the polymeric material.

33. A product as in claim 32 wherein said dye or pigment is selected to block out an undesired color at various angles.

34. A method for forming an optical product utilizing multilayer interference thin film flakes having first and second parallel surfaces and a width and a thickness and having an aspect ratio of at least 2:

1 for the width with respect to thickness comprising melting a polymeric material, introducing the flakes into the polymeric material, forming the melted polymeric material into a molten mass with the flakes therein to cause the flakes to orient themselves in the molten mass as it is being formed into a sheet having first and second parallel surfaces so that the first and second surfaces of the flakes lie in planes parallel to the first and second parallel surfaces of the sheet and cooling the sheet to cause the same to solidify to form a sheet.

35. A method as in claim 34 including heating the cooled sheet and stretching the sheet in first and second directions to cause biaxial orientation of the molecular chains in the sheet and at the same time to cause orientation of the flakes so that they lie in planes in the directions of biaxial orientation and further cooling the sheet.

36. A method as in claim 34 together with coextruding the sheet with an additional layer of polymeric material so that the additional layer is adherent to the first surface of the sheet.

37. A method as in claim 36 together with the step of introducing a color into the additional layer of coextruded material.

38. A method as in claim 36 together with the step of coextruding another layer of polymeric material so that the other layer is adherent to the second surface of the sheet.

39. A method for forming an optical product utilizing multilayer interference thin film flakes having first and second parallel surfaces and a width and thickness and having an aspect ratio of at least 2:

1 for the width with respect to the thickness comprising dissolving a polymer into a solvent, introducing the multilayer interference thin film flakes to the dissolved polymer, forming a polymeric sheet having first and second parallel surfaces by casting the dissolved polymer with the multilayer interference thin film flakes therein into a solidified polymer onto a releasable substrate, drawing the polymeric sheet so as to orient the flakes in the solidified polymer, removing the coated sheet from the releasable substrate, the first and second surfaces of the flakes lying in planes parallel to the first and second surfaces of the sheet.