Prehydrolysis of lignocellulose

• US 5,424,417 A
• Filed: 09/24/1993
• Issued: 06/13/1995
• Est. Priority Date: 09/24/1993
• Status: Expired due to Term

• Current Assignee: Nudwest Research Institute
• Original Assignee: Midwest Research Institute
• Inventors: Wyman, Charles E., Kadam, Kiran L., Philippidis, George P., Torget, Robert W., Hsu, Teh-An
• Primary Examiner(s): Lilling, Herbert J.
• Application Number:
  US08/126,792
• Time in Patent Office: 627 Days
• Field of Search: 127/1, 127/37, 127/29, 536/1.11, 536/56, 536/57, 435/101, 162/16, 162/19
• US Class Current: 536/56
• CPC Class Codes: C08H 8/00 Macromolecular compounds derived from lignocellulosic materials pretreatment thereof B27N
• CPC Class Codes: C13K 1/02 obtained by saccharification of cellulosic materials manufacture of fodder A23K10/32
• CPC Class Codes: D21C 1/00 Pretreatment of the finely-divided materials before digesting of waste paper D21C5/02

Abstract

The invention relates to the prehydrolysis of lignocellulose by passing an acidic or alkaline solution through solid lignocellulosic particles with removal of soluble components as they are formed. The technique permits a less severe combination of pH, temperature and time than conventional prehydrolysis. Furthermore, greater extraction of both hemicellulose and lignin occurs simultaneously in the same reactor and under the same conditions.

Claims

1. A process for prehydrolyzing lignocellulosic material so as to separate a greater percentage of hemicellulose and at least 20% lignin to obtain a more purified cellulose comprising:

placing lignocellulosic material in a prehydrolysis flow-through reactor;

prehydrolyzing said lignocellulosic material at a temperature of between about 120°

to about 240°

C., by passing a dilute acidic liquid that produces pH conditions of about 1.0 to about 5.5 into the reactor and through said lignocellulosic material and withdrawing liquid out of said prehydrolysis flow-through reactor to form a prehydrolyzate liquor;

recovering said prehydrolyzate liquor; and

removing solid material inclusive of at least 20% of the lignin present in said lignocellulosic material from said flow-through prehydrolysis reactor at temperatures used during prehydrolyzing.

2. A process according to claim 1, said prehydrolysis occurs at a temperature of about 120°

C. to wherein the prehydrolyzate liquor has a pH of about 1 to about 5.

3. A process according to claim 1, further comprising adding an acidic liquid having a pH of about 1.0 to about 5.5 to said prehydrolysis flow-through reactor.

4. A process according to claim 3, wherein said acidic liquid is continuously added throughout said prehydrolysis.

5. A process according to claim 3, wherein at least one condition of the prehydrolysis is changed during the prehydrolysis.

6. A process according to claim 5, further comprising passing the acidic liquid through said prehydrolysis flow-through reactor before or during a change in at least one condition.

7. A process according to claim 1, wherein said prehydrolyzate liquor comprises a pentose, oligomers of pentose and a significant amount of lignin, said solid material contains cellulose, substantially no hemicellulose and a significantly reduced amount of lignin compared to said lignocellulosic material.

8. A cellulosic material produced by the process of claim 1, wherein the cellulosic material is capable of being completely digested by cellulase.

9. A prehydrolyzate liquor produced by the process of claim 1, wherein the prehydrolyzate liquor contains xylan oligomers or monomers and lignin.