High energy density and high power density ultracapacitors and supercapacitors

• US 5,426,561 A
• Filed: 03/31/1994
• Issued: 06/20/1995
• Est. Priority Date: 09/29/1992
• Status: Expired due to Fees

• Current Assignee: United States Administrator of National Aeronautics and Space Administration
• Original Assignee: United States Administrator of National Aeronautics and Space Administration
• Inventors: Yen, Shiao-Ping S., Lewis, Carol R.
• Primary Examiner(s): Reynolds, Bruce A.
• Assistant Examiner(s): Mills, Gregory L.
• Application Number:
  US08/221,973
• Time in Patent Office: 446 Days
• Field of Search: 361/502, 361/503, 361/504, 361/505, 361/511, 361/512, 361/522, 361/530, 361/541, 29/25.03
• US Class Current: 361/502
• CPC Class Codes: H01G 11/12 Stacked hybrid or EDL capacitors
• CPC Class Codes: H01G 11/28 arranged or disposed on a current collector; Layers or phases between electrodes and current collectors, e.g. adhesives
• CPC Class Codes: H01G 11/32 Carbon-based
• CPC Class Codes: H01G 11/66 Current collectors
• CPC Class Codes: H01G 11/68 characterised by their material
• CPC Class Codes: H01G 11/70 characterised by their structure
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors

Abstract

Ultracapacitor and supercapacitor designs wherein two discrete metal film current collectors of the prior art, one for each of the cathode and anode, are replaced by a single thin polymer film. The polymer film is typically several microns thick and metallized on both sides. The thickness of the metallization is varied from several hundred to several thousand Ångstroms depending upon the particular application. This metallization serves as the positive and negative electrodes (current collectors) which are spatially separated by the polymer dielectric film. The resulting reduction of volume increases the volumetric energy density and the reduction of mass increases the gravimetric energy density. The electrolyte solvent/salt system can be selected to provide useful individual cell voltages as high as 5 volts. The voltage is limited only by the electrolytic stability of the solvent and salt. Ultracapacitors fabricated in accordance with the present invention may have energy densities exceeding 10 watt-hours per kilogram and volumetric energy densities exceeding 15 watt-hours per liter. Values which are yet higher are feasible with supercapacitors fabricated in accordance with the present invention.

Claims

1. A capacitor comprising:

a metalized polymer film having opposing surfaces;

each said opposing surface being coated with a layer of metal forming a current collector;

a pair of electrode layers, each of said electrode layers formed of a mixture of carbon and electrolyte binder, each of said electrode layers coated respectively onto each of said layers of metal; and

an electrolyte in contact with said metal layers and with said carbon and binder mixture layers.

2. The capacitor recited in claim 1 wherein the thickness of said polymer film is less than ten microns and the thickness of said metal layer is less than 10,000 Angstroms.

3. The capacitor recited in claim 1 wherein said electrolyte binder comprises an elastomeric polymer.

4. The capacitor recited in claim 1 wherein said electrolyte comprises a non-aqueous solvent/salt system.

5. The capacitor recited in claim 4 wherein said solvent/salt system comprises acetonitrile tetrabutylammonium tetrafluoroborate.

6. The capacitor recited in claim 1 wherein said electrolyte comprises a solvent taken from the group consisting of propylene carbonate;

propylene carbonate/diethylcarbonate;

1, 3 dioxolane; and

tetrahydrofuran.

7. The capacitor recited in claim 1 wherein said electrolyte comprises a salt taken from the group consisting of tetrabutylammonium tetraphenylborate;

tetraethylphosphonium tetrafluoroborate; and

tetraethylammonium tetrafluoroborate.

8. The capacitor recited in claim 1 further comprising at least one polymeric film cell separator positioned adjacent at least one of said carbon and binder mixture layers.

9. A capacitor comprising:

a metalized polymer film having opposing surfaces;

each said opposing surface being coated with a layer of metal forming a current collector;

a pair of electrode layers, each of said electrode layers formed of material taken from the group consisting of transition metal oxides and hydrous oxides, each of said electrode layers coated respectively onto each of said layers of metal; and

an electrolyte in contact with said metal layers and with said group material layers.

10. The capacitor recited in claim 9 wherein the thickness of said polymer film is less than ten microns and the thickness of said metal layer is less than 10,000 Angstroms.

11. The capacitor recited in claim 9 wherein said electrolyte comprises a non-aqueous solvent/salt system.

12. The capacitor recited in claim 11 wherein said solvent/salt system comprises acetonitrile tetrabutylammonium tetrafluoroborate.

13. The capacitor recited in claim 9 wherein said electrolyte comprises a solvent taken from the group consisting of propylene carbonate;

propylene carbonate/diethylcarbonate;

1, 3 dioxolane; and

tetrahydrofuran.

14. The capacitor recited in claim 9 wherein said electrolyte comprises a salt taken from the group consisting of tetrabutylammonium tetraphenylborate;

tetraethylphosphonium tetrafluoroborate; and

tetraethylammonium tetrafluoroborate.

15. The capacitor recited in claim 9 further comprising at least one polymeric film cell separator positioned adjacent at least one of said carbon and binder mixture layers.

16. A capacitor comprising:

a plurality of cells each such cell having a metalized polymer film having opposed surfaces;

each of said opposed surfaces being coated with a layer of metal forming a current collector;

a pair of electrode layers, each of said electrode layers formed of an electrode material coated onto each of said metal layers;

an electrolyte in contact with said metal layers and with said electrode material layers; and

a polymeric film cell separator positioned between the electrode materials of adjacent cells.

17. The capacitor recited in claim 16 wherein said electrode material comprises a mixture of carbon and electrolyte binder.

18. The capacitor recited in claim 16 wherein said electrode material comprises a material taken from the group consisting of transition metal oxides and hydrous oxides.