Method of recovering ammonia and compounds from offgases contaminated with organic materials, carbon dioxide, and ammonia

• US 5,427,759 A
• Filed: 08/09/1994
• Issued: 06/27/1995
• Est. Priority Date: 05/30/1992
• Status: Expired due to Fees

• Current Assignee: Evonik Degussa GmbH
• Original Assignee: Huels Aktiengesellschaft
• Inventors: Heitmann, Wilhelm
• Primary Examiner(s): LANGEL, WAYNE A
• Application Number:
  US08/288,232
• Time in Patent Office: 322 Days
• Field of Search: 423/238, 423/245.1, 423/234, 423/352, 423/245.2
• US Class Current: 423/352
• CPC Class Codes: B01D 2251/304 of sodium
• CPC Class Codes: B01D 2251/604 Hydroxides
• CPC Class Codes: B01D 53/1418 Recovery of products
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: B01D 53/72 Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
• CPC Class Codes: C01C 1/12 Separation of ammonia from gases and vapours as part of the ammonia synthesis process C01C1/04
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02P 20/151 Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Abstract

A method for recovering ammonia and organic compounds from offgases contaminated with organic materials, carbon dioxide, and ammonia, using a combined absorption and rectification column is disclosed. Carbon dioxide is washed out with aqueous alkali, ammonia is drawn off as an overhead product, and the organic compounds are recovered in pure form from the bottoms product following separation-out of the alkali carbonate.

Claims

1. A method for recovering ammonia and organic compounds from offgases comprising:

contacting offgases contaminated with at organic compound, carbon dioxide, and ammonia with 13.3-20 wt. % aqueous alkali in a combined absorption and rectification column to wash out carbon dioxide and form an aqueous alkali carbonate solution, wherein the combined absorption and rectification column is operated in the sump at the boiling temperature of the mixture of the alkali carbonate solution and the organic compounds, recovering ammonia as an over head product, and recovering the organic compounds from the bottoms product by separating the aqueous alkali carbonate solution.

2. A method according to claim 1, wherein the alkali carbonate solution is separated out by decantation.

3. A method according to claim 1, wherein water in the recovered organic compound is separated therefrom by distillation, and is used for diluting an aqueous alkali solution.

4. A method according to claim 1, wherein the ammonia-containing offgases come from a process for the manufacture of bisurethane employing diamine, urea, and alcohol.

5. A method according to claim 1, wherein the concentration of aqueous alkali is 15-20 wt %.