Gas releasing electrochemical cell for fluid dispensing applications

• US 5,427,870 A
• Filed: 09/06/1994
• Issued: 06/27/1995
• Est. Priority Date: 09/06/1994
• Status: Expired due to Fees

• Current Assignee: Microlin LLC
• Original Assignee: Ceramatec, Inc.
• Inventors: Joshi, Ashok V., Gordon, John H., Shen, Yousheng
• Primary Examiner(s): Niebling, John
• Assistant Examiner(s): BELL, BRUCE F
• Application Number:
  US08/301,116
• Time in Patent Office: 294 Days
• Field of Search: 204/415, 204/252, 204/265, 204/266, 204/291, 204/292, 204/294, 429/12, 429/27, 429/30, 429/33, 429/40, 429/46, 429/219, 429/220
• US Class Current: 429/219
• CPC Class Codes: A61M 2005/14204 with gas-producing electrochemical cell
• CPC Class Codes: A61M 5/1486 the bags being substantially completely surrounded by fluid
• CPC Class Codes: B01J 19/2475 Membrane reactors
• CPC Class Codes: B01J 2219/00135 Electric resistance heaters
• CPC Class Codes: B01J 2219/00164 controlling the flow
• CPC Class Codes: B67D 7/0255 squeezing collapsible or flexible storage containers for dispensing beverages on draught B67D1/0462
• CPC Class Codes: H01M 6/16 with organic electrolyte H01M6/18 takes precedence
• CPC Class Codes: H01M 6/18 with solid electrolyte

Abstract

A self-contained device which continuously dispenses a packaged fluid is disclosed. The device is particularly suited for applications where several months may lapse before performance is manually initiated, after which a consistent steady flow is required for an extended period until the packaged fluid is exhausted. The device is particularly suited for applications where ease of fabrication is important. The device utilizes an electrochemically-generated gas, such as oxygen or nitrogen, to pressurize the packaged fluid to dispense it. Oxygen can be electrochemically released from a solid anode material of the general form AxOy as A ions migrate across a suitable ion-conducting electrolyte. Alternatively, nitrogen can be the pressurizing gas wherein it is electrochemically released from a solid, anode material of the general form A'"'"'.sub.α N.sub.β where A'"'"' is a cation, as A'"'"' ions migrate across a suitable ion-conducting electrolyte. At the cathode, several possibilities may occur, either the migrated cations are reduced to their elemental state, or a solid material, R₂, where R is a halogen, is reduced to R^-, or solid material, R'"'"', where R'"'"' is a group VIB element other than oxygen is reduced to R'"'"'^-2, or solid material CR_x is reduced to C+XR^-. The released gas, oxygen or nitrogen, pressurizes a chamber resulting in fluid contained in a flexible bladder within the chamber to be forced through an outlet. Depending on the selection of anode and cathode materials, the device will be self driven or else will require a battery to provide a driving force.

Claims

1. A solid-state, electrically self-contained, fluid-dispensing micropump comprising:

a galvanic electrochemical cell having an anode compartment, a cathode compartment,

solid electrolyte separating said anode and cathode compartments;

a solid anode material of the composition A_x O_y or A'"'"'.sub.α

N.sub.β

,

wherein A is a cation of a metal selected from the class consisting of silver and copper,

wherein A'"'"' is a cation of a metal selected from the class consisting of sodium and lithium,

wherein O is oxygen and N is nitrogen and the value for x is 1 to 3 and y is 1 to 4, α

is 1 to 3 and β

is 1 to 3;

an electrolyte consisting essentially of an ion transport material selected from the class of materials which transport A cations or A'"'"' cations;

a cathode material in intimate contact with said electrolyte, said cathode material consisting essentially of a halogen ionizable to a minus one valence state or a compound consisting of carbon and halogen ionizable to a mixture of carbon and halogen with valence of minus one state or a Group VIB substance ionizable to a minus two valence state;

an electrical conductor connectable between said anode and cathode materials, which upon connection results in oxygen or nitrogen being released from the anode material as the cation present, A or A'"'"' migrates through the electrolyte to react with the cathodic material in a reaction which includes the electrons released at the anode;

a fluid containing chamber having a fluid discharge outlet; and

duct means providing gas communication between said anode compartment and said fluid containing chamber.

2. Apparatus as set forth in claim 1, wherein solid anode material includes the compound Ag₂ O.

3. Apparatus as set forth in claim 1, wherein said solid anode material includes a compound selected from the class consisting of Li₃ N and NaN₃.

4. Apparatus as set forth in claim 1, wherein said solid cathode material includes a compound selected from the class consisting of I₂, S and CF_x where x ranges from 0.8-1.2.

5. Apparatus as set forth in claim 1, wherein an electrical circuit is completed through said electrical conductor by a contact clip pressed into place such that said contact clip electrically communicates with both the anode and the cathode.

6. Apparatus as set forth in claim 1, wherein an electrical circuit is completed through said electrical conductor by inverting a contact clip, to make contact between that portion of said electrical conductor communicating with the anode and that portion of the electrical conductor communicating with the cathode.

7. Apparatus as set forth in claim 1, wherein a principal component of the electrolyte is selected from one class consisting of AgI, LiI, NaI, KI, RbI and Ag₄ RbI₃.

8. Apparatus as set forth in claim 1, wherein a component of the electrolyte is Ag.sub.(1+x) Zr₂ Si_x P.sub.(3-x) O₁₂, wherein x is a value of 0 to 3.

9. Apparatus as set forth in claim 1, wherein the anode and cathode are separated by a microporous membrane.

10. Apparatus as set forth in claim 9, wherein an electrolyte dissolved in a non-aqueous solvent is utilized.

11. Apparatus as set forth in claim 10, wherein a component of said electrolyte is LiBF₄.

12. Apparatus as set forth in claim 10, wherein a component of said electrolyte is AgBF₄.

13. Apparatus as set forth in claim 10, wherein a component of said non-aqueous solvent is ethylene glycol dimethyl ether.

14. Apparatus as set forth in claim 10, wherein a component of said non-aqueous solvent is propylene carbonate.

15. Apparatus as set forth in claim 1, wherein the anode and cathode are separated by a solid polymer electrolyte.

16. A solid-state, electrically self-contained electrochemical cell having a substantially uniform rate of gas production comprising:

a galvanic electrochemical cell having an anode compartment, a cathode compartment, solid electrolyte separating said anode and cathode compartments;

a solid anode material of the composition A_x O_y or A'"'"'.sub.α

N.sub.β

wherein A is a cation of a metal selected from the class consisting of silver and copper,

wherein A'"'"' is a cation of a metal selected from the class consisting of sodium and lithium,

wherein O is oxygen and N is nitrogen and the value for x is 1 to 3 and y is 1 to 4, α

is 1 to 3 and β

is 1 to 3,

solid electrolyte consisting essentially of an ion transport material selected from the class of materials which transport A cations or A'"'"' cations;

a cathode material in intimate contact with said electrolyte, said cathode material consisting essentially of a halogen ionizable to a minus one valence state or a compound consisting of carbon and halogen ionizable to a mixture of carbon and halogen with valence of minus one state or a Group VIB substance ionizable to a minus two valence state; and

an electrical conductor connectable between said anode and cathode materials, which upon connection results in oxygen or nitrogen being released from the anode material as the cation present, A or A'"'"' migrates through the electrolyte to react with the cathodic material in a reaction which includes the electrons released at the anode.