Galvanic seawater cell

• US 5,427,871 A
• Filed: 12/03/1993
• Issued: 06/27/1995
• Est. Priority Date: 02/07/1991
• Status: Expired due to Term

• Current Assignee: University of Tokyo
• Original Assignee: University of Tokyo
• Inventors: Garshol, Tor, Hasvold, Oistein
• Primary Examiner(s): Kalafut, Stephen
• Assistant Examiner(s): NUZZOLILLO, MARIA
• Application Number:
  US08/098,302
• Time in Patent Office: 571 Days
• Field of Search: 429/119, 429/188, 429/238
• US Class Current: 429/119
• CPC Class Codes: H01M 4/8626 characterised by the form
• CPC Class Codes: H01M 6/34 Immersion cells, e.g. sea-water cells
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

This invention relates to galvanic seawater cells and batteries and in particular to cathodes which are suitable for use in galvanic cells that use an oxidant dissolved in the electrolyte as depolarizer. An example of such cells are seawater cells which use the oxygen dissolved in the seawater as oxidant. The cell has an inert electrode which consists of a number of conducting fibers (1,3,14) connected to a conducting body (2,4,15). The fibers (1,3,14) have different orientations relatively to each other and to the body (2,4,15). In a preferred embodiment the electrode body (2,4) consists of two or more wires which are twisted together to constitute an electrode stem while clamping the fibers (1,3) in a fixed position between the wires, as in a laboratory bottle brush.

Claims

1. Galvanic seawater cell for use with seawater as an electrolyte and with oxygen, hydrogenperoxide or chlorine dissolved in the seawater as an oxidant, said cell comprising:

at least one anode element; and

at least one cathode element, each said cathode element further comprising

a plurality of electrochemically active conductive fibers,

a current collecting conductive body extending along a main axis, and

means for physically and electrically connecting said fibers to said current collecting conductive body such that a substantial portion of each of said fibers extends outwardly from a respective adjacent surface portion of said current collecting body, and said fibers are substantially uniformly distributed about said main axis.

2. Cell according to claim 1, wherein in each said cathode element, each said substantial portion of the same length and is oriented substantially radially about said main axis.

3. Cell according to claim 1, wherein in each said cathode element, each of the fibers is oriented within plus/minus 45 degrees of the normal vector to a plane defined on an adjacent surface of the current collecting body.

4. Cell according to claim 3, wherein in each said cathode element, each of the fibers is oriented approximately normal to an adjacent surface portion of the body.

5. Cell according to claim 1, wherein not all of the fibers have a same length.

6. Cell according to claim 1, wherein said electrochemically active fibers are formed from materials selected from the group consisting of carbon, inert metals, and mixtures thereof.

7. Cell according to claim 1, wherein the current collecting body of each cathode element is formed from an inert metal.

8. Cell according to claim 1, wherein the current collecting body of each cathode element is in the form of an electrode stem consisting of two or more wires which are twisted together about said main axis to clamp each of the fibers in a respective fixed position between the wires.

9. Cell according to claim 8, wherein one part of the stem is twisted in a first direction and another part of the stem is twisted in a second direction opposite said first direction.

10. Cell according to claim 1, comprising a plurality of said anode elements which collectively constitute an anode of said cell and a plurality of said cathode elements which collectively constitute a cathode of said cell.

11. Cell according to claim 10, wherein the cell is open to the seawater and said plurality of anode elements are interleaved with said plurality of cathode elements.

12. Cell according to claim 10, wherein said anode elements are arranged in one or more parallel anode rows and said cathode elements are arranged in one or more parallel cathode rows.

13. Cell according to claim 10, wherein said anode elements and said cathode elements are confined within a common compartment through which said seawater electrolyte flows along a predetermined path.

14. Cell according to claim 13, wherein the seawater electrolyte flows first through the cathode elements and then through the anode elements.

15. Cell according to claim 14, further comprising means for causing the seawater to flow past the cathode elements at substantially right angles to the axis of the respective current collecting conductive bodies.

16. Cell according to claim 1, wherein the current collecting conductive body consists of a current collecting matrix provided with a plurality of apertures into which the electrochemically active conductive fibers are inserted.

17. Cell according to claim 1, wherein the outwardly extending portions of the fibers are deflected as the seawater flows through the cell.

18. Cell according to claim 6 wherein the fibers are formed from carbon.

19. Cell according to claim 6 wherein the fibers are formed from an inert metal selected from the group consisting of stainless steel, copper, copper alloys, silver, titanium, and combinations thereof.

20. Cell according to claim 7 wherein the inert metal is selected from the group consisting of stainless steel, copper, copper alloys, silver, titanium, and combinations thereof.