Gas phase fluidized bed polyolefin polymerization process using gas or gas-solids tangential flow

• US 5,428,118 A
• Filed: 07/15/1994
• Issued: 06/27/1995
• Est. Priority Date: 07/15/1994
• Status: Expired due to Fees

• Current Assignee: Union Carbide Chemicals & Plastics Technology Corporation (Dow, Inc.)
• Original Assignee: Union Carbide Chemicals & Plastics Technology Corporation (Dow, Inc.)
• Inventors: Painter, Roger B., Song, Gyung-Ho, Garner, Billy J.
• Primary Examiner(s): Schofer, Joseph L.
• Assistant Examiner(s): WEBER, THOMAS
• Application Number:
  US08/276,086
• Time in Patent Office: 347 Days
• Field of Search: 526/74, 526/88, 526/901, 526/65
• US Class Current: 526/74
• CPC Class Codes: B01J 8/0055 using cyclones
• CPC Class Codes: B01J 8/24 according to "fluidised-bed" technique B01J8/20 takes precedence
• CPC Class Codes: C08F 110/02 Ethene
• CPC Class Codes: C08F 110/06 Propene
• CPC Class Codes: C08F 2/34 Polymerisation in gaseous state
• CPC Class Codes: C08F 210/06 Propene
• CPC Class Codes: C08F 210/14 Monomers containing five or more carbon atoms
• CPC Class Codes: C08F 210/16 Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
• CPC Class Codes: C08F 210/18 with non-conjugated dienes, e.g. EPT rubbers
• CPC Class Codes: C08F 236/20 unconjugated
• CPC Class Codes: C08F 2500/25 Cycloolefine
• CPC Class Codes: Y10S 526/901 Monomer polymerized in vapor state in presence of transition metal containing catalyst

Abstract

An improved method for polymerizing one or more polyolefins in the presence of a transition metal catalyst in at least one gas phase reactor having an expanded section, the improvement comprising generating a tangential flow of gas or gas-solids in the expanded section of the gas phase reactor to reduce fines entrainment into the gas cycle system and to reduce or remove solid particle build-up on one or more interior surfaces of the expanded section of the reactor.

Claims

1. An improved method for polymerizing one or more polyolefins in the presence of a transition metal catalyst in at least one gas phase reactor having a straight section and an expanded section, the improvement comprises generating a flow of gas or gas-solids tangentially to one or more interior surfaces in the expanded section of the reactor to reduce particle build-up.

2. The method of claim 1 wherein a tangential gas or gas-solids flow is accomplished by means of one or more tangential nozzles capable of providing a gas velocity of about 10 to 100 feet/second.

3. The method according to claim 2 wherein the tangential flow is accomplished by 1 to 20 tangential nozzles.

4. The method of claim 3 wherein the nozzles are positioned in the gas phase reactor at an elevation between an upper bed level of polymer and the top of the reactor.

5. The method of claim 4 wherein a primary flow of a cycle gas is supplied to a distributor plate and a secondary flow of cycle gas is supplied to the reactor above the top of the bed level.

6. The method of claim 5 wherein the secondary flow of cycle fluidizing gas is 2% to 60% by volume of the primary flow of the cycle gas.

7. The method of claim 6 wherein the tangential flow of gas-solids is accomplished by feeding solid polymer particles from the straight section of the reactor by means of a solids feeding device into the secondary flow of cycle gas.

8. The method of claim 7 wherein the nozzles have a tangential nozzle direction ranging from about 90 degrees below horizontal to about 90 degrees above horizontal.

9. The method of claim 1 wherein the polyolefin is a linear homopolymer of ethylene or a linear copolymer comprised of a major mole percent of ethylene or propylene and a minor mole percent of one or more C₃ to C₈ alpha olefins.

10. The method of claim 1 wherein the polyolefin is selected from the group consisting of

(i) ethylene/propylene rubbers;

(ii) ethylene/propylene/diene rubbers;

(iii) polybutadiene rubbers;

(iv) high ethylene content propylene/ethylene block copolymers;

(v) ethylene/propylene/hexadiene terpolymers;

(vi) ethylene/propylene/ethylidene norbornene; and

(vii) poly(1-butene).

11. The method of claim 1 wherein the polyolefin is produced in a staged reaction process comprising two or more reactors.