Method of assembling a bipolar lead-acid battery and the resulting bipolar battery

• US 5,429,643 A
• Filed: 06/02/1993
• Issued: 07/04/1995
• Est. Priority Date: 06/02/1993
• Status: Expired due to Fees

• Current Assignee: Exice Corporation
• Original Assignee: GNB Battery Technologies, Inc.
• Inventors: Kump, William H., Lund, David L., Groff, Donald W.
• Primary Examiner(s): Kalafut, Stephen
• Assistant Examiner(s): NUZZOLILLO, MARIA
• Application Number:
  US08/071,298
• Time in Patent Office: 762 Days
• Field of Search: 429/210, 429/212, 429/233, 29/623.3
• US Class Current: 29/623.3
• CPC Class Codes: H01M 10/18 with bipolar electrodes
• CPC Class Codes: H01M 50/30 Arrangements for facilitating escape of gases
• CPC Class Codes: H01M 50/317 Re-sealable arrangements
• CPC Class Codes: H01M 50/627 Filling ports
• CPC Class Codes: H01M 8/0273 with sealing or supporting means in the form of a frame
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y10T 29/49112 including laminating of indefinite length material

Abstract

A method of assembling a bipolar lead-acid battery includes assembling the electrochemical components necessary to provide the necessary voltage and capacity, maintaining the electrochemical components under the desired compression and then sealing such electrochemical components as a unit utilizing various assembly components. The resulting bipolar battery in the preferred embodiment includes an electrolyte fill/vent box that seals the top of the electrochemical component unit and a vacuum box that seals the bottom surface.

Claims

1. A method of making a bipolar lead-acid battery, which method comprises:

providing a pair of end frames, each of the end frames having a body portion, said body portion defining an exterior surface, a top surface, a bottom surface, side surfaces, and an interior surface, said interior surface including a peripheral border;

a conductive metal substrate embedded in the body portion of the end frame; and

a layer of positive or negative active material adhered to the conductive metal substrate of the end frame;

providing a plurality of intermediate frames, each of the intermediate frames having a body portion, said body portion defining a top surface, a bottom surface, side surfaces, and interior surfaces, said interior surfaces including peripheral borders;

a conductive metal substrate embedded in the body portion of the intermediate frame; and

a layer of positive or negative active material adhered to each surface of the conductive metal substrate of the intermediate frame;

providing a plurality of separators;

assembling the end frames, intermediate frames, and separators so that the peripheral boarders of adjacent end and intermediate frames abut to form an electrochemical component unit, said electrochemical component unit having a plurality of electrochemical cells, a top surface, a bottom surface, and side surfaces corresponding, respectively, to the top surface, bottom surface, and side surfaces of the end and intermediate frames, and end surfaces corresponding to the exterior surfaces of the end frames;

providing each electrochemical cell with an opening in the top surface of the electrochemical unit and an opening in the bottom surface of the electrochemical unit, one of said cell openings associated with each cell being an electrolyte fill/vent hole and the other said cell hole associated with each cell being a vacuum hole;

sealing the side surfaces of the electrochemical component unit with a panel;

providing a top box including a base, the base defining a plurality of compartments, each said base compartment having a hole therein, said top box base compartment holes being in alignment with the cell openings in the top surface of the electrochemical component unit;

a front panel having an aperture communicating with each top box base compartment; and

an open top;

sealing the base of the top box to the top surface of the electrochemical component unit, thereby providing communication between the cell openings in the top surface of the electrochemical component unit and their associated top box base compartment holes, top box compartments, and top box front panel apertures;

providing a bottom box including a base, the base defining a plurality of compartments, each said base compartment having a hole therein, said bottom box base compartment holes being in alignment with the cell openings in the bottom surface of the electrochemical component unit;

a front panel having an aperture communicating with each bottom box base compartment; and

an open top;

sealing the base of the bottom box to the bottom surface of the electrochemical component unit, thereby providing communication between the cell openings in the bottom surface of the electrochemical component unit and their associated bottom box base compartment holes, bottom box compartments, and bottom box front panel apertures;

providing covers for the open tops of the top box and bottom box;

sealing the top and bottom box covers to the open tops of the top box and bottom box;

filling each cell with electrolyte by introducing electrolyte into the top or bottom box front panel aperture in communication with the electrolyte fill/vent hole of the cell while applying a vacuum to the top or bottom box front panel aperture in communication with the vacuum hole of the cell;

providing covers for the front panels of the top box and bottom box; and

sealing the front panel covers over the front panels of the top box and bottom box.

2. The method of claim 1, wherein the cell openings in the top surface of the electrochemical component unit are electrolyte fill/vent holes and the cell openings in the bottom surface of the electrochemical component unit are vacuum holes;

wherein the front panel cover for the top box is a manifolding cover; and

wherein the front panel cover for the bottom box blocks off the bottom box front panel apertures.

4. The method of claim 1 wherein the bipolar lead-acid battery is a sealed battery, wherein said separators are compressible separators, so as to compress said separators prior to sealing the top, bottom and side surfaces of the electrochemical component unit.

5. The method of claim 4 wherein said intermediate frames comprise a plurality of active bipolar frames, each of said active bipolar frames having a layer of positive active material and a layer of negative active material, and a central bi-plate frame, the central bi-plate frame having layers of active material opposite in polarity to the active material of the end frames, the active bipolar frames and the central bi-plate frame being positioned in the electrochemical component unit to provide two batteries in parallel.

6. The method of claim 5 wherein the peripheral border of each end and intermediate frame is configured to provide compression upon assembly of the electrochemical component unit.

7. The method of claim 5 wherein the peripheral border of each end and intermediate frame includes a shoulder aligned to accept one of the separators in the assembly of the electrochemical component unit.

8. The method of claim 7 wherein the conductive metal substrate of the end and bipolar frames includes an active material location restraint for retaining the active material.

9. The method of claim 1 wherein the cell holes are provided by indentations molded in the frames.

10. The method of claim 5 wherein the conductive metal substrate of said central bi-plate frame extends through one of the side surfaces of the electrochemical component unit so as to provide either a positive or negative terminal, wherein the conductive metal substrates of said end frames extend through said side surface of the electrochemical component unit so as to provide terminals of a polarity opposite to the polarity of the central bi-plate frame terminal, and wherein one of the panels to be sealed to the side surfaces of the electrochemical component unit has openings dimensioned and aligned so as to allow said panel to be sealed to said side surface of the electrochemical component unit with the terminals extending therethrough.

11. The method of claim 1 wherein the sealing steps simultaneously seal at least a portion of the abutting peripheral borders of adjacent frames.

12. The method of claim 2 wherein the top box base defines a chamber without an aperture, wherein the front panel cover for the top box includes an explosion-proof vent, and wherein the sealed front panel cover for the top box is positioned such that the explosion-proof vent is juxtaposed adjacent said chamber.

13. The method of claim 1 wherein the end frames have strengthening ribs dimensioned and positioned to minimize bulging of the battery during service.

14. The method of claim 13 wherein each end frame is a unitary component.

15. The method of claim 13 wherein the body portion of each end frame comprises two components, one component comprising the interior surface including the peripheral border and having the conductive metal substrate embedded therein and the other component comprising the exterior surface and having the strengthening ribs therein.

16. The method of claim 13 wherein a plastic stabilizing member is attached to the end frame.

17. The method of claim 13 wherein the top and bottom boxes have strengthening ribs aligning with the ribs on the end frames in the assembled battery.

18. The method of claim 1 wherein the base of the top and bottom boxes are dimensioned and configured so as to provide a ridge which fits over, respectively, the top and bottom surfaces of the electrochemical component unit.

3. A method of making a bipolar lead-acid battery, which method comprises:

providing a pair of end frames, each of the end frames having a body portion, said body portion defining an exterior surface, a top surface, a bottom surface, side surfaces, and an interior surface, a bottom surface, side surfaces, and an interior surface, said interior surface including a peripheral border;

a conductive metal substrate embedded in the body portion of the end frame; and

a layer of positive or negative active material adhered to the conductive metal substrate of the end frame;

providing a plurality of intermediate frames, each of the intermediate frames having a body portion, said body portion defining a top surface, a bottom surface, side surfaces, and interior surfaces, said interior surfaces including peripheral borders;

a conductive metal substrate embedded in the body portion of the intermediate frame; and

a layer of positive or negative active material adhered to each surface of the conductive metal substrate of the intermediate frame;

providing a plurality of separators;

assembling the end frames, intermediate frames, and separators so that the peripheral boarders of adjacent end and intermediate frames abut to form an electrochemical component unit, the separators being compressed thereby, said electrochemical component unit having a plurality of electrochemical cells, a top surface, a bottom surface, and side surfaces corresponding, respectively, to the top surface, bottom surface, and side surfaces of the end and intermediate frames, and end surfaces corresponding to the exterior surfaces of the end frames;

providing each electrochemical cell with an electrolyte fill/vent opening in the top surface of the electrochemical unit;

sealing the side surfaces of the electrochemical component unit with a panel;

providing an electrolyte fill/vent box including a base, the base defining a plurality of compartments, each said base compartment having a hole therein, said base compartment holes being in alignment with the electrolyte fill/vent holes in the top surface of the electrochemical component unit;

a front panel having an aperture communicating with each base compartment; and

an open top;

sealing the base of the electrolyte fill/vent box to the top surface of the electrochemical component unit, thereby providing communication between the electrolyte fill/vent holes in the top surface of the electrochemical component unit and their associated top box base compartment holes, top box compartments, and top box front panel apertures;

providing a cover for the open top of the electrolyte fill/vent box;

sealing the electrolyte fill/vent box cover to the open top of the electrolyte fill/vent box;

sealing the bottom surface of the electrochemical component unit with a panel;

adding electrolyte to each cell by introducing electrolyte into the electrolyte fill/vent box front panel apertures;

inserting valves in the electrolyte fill/vent box front panel apertures adapted to maintain the internal pressure within the battery;

providing a manifolding cover for the front panel of the electrolyte fill/vent box; and

sealing the front panel cover over the front panel of the electrolyte fill/vent box.