Pressure swing absorption with recycle of void space gas

• US 5,429,664 A
• Filed: 02/16/1994
• Issued: 07/04/1995
• Est. Priority Date: 02/22/1993
• Status: Expired due to Fees

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Lee, Sang K.
• Primary Examiner(s): SPITZER, ROBERT H
• Application Number:
  US08/197,091
• Time in Patent Office: 503 Days
• Field of Search: 95/97, 95/103, 95/138, 95/148, 95/903, 95/45, 95/54, 95/96, 95/100-102, 95/105
• US Class Current: 95/54
• CPC Class Codes: B01D 2253/102 Carbon
• CPC Class Codes: B01D 2256/10 Nitrogen
• CPC Class Codes: B01D 2257/104 Oxygen
• CPC Class Codes: B01D 2259/40052 Recycled product or process gas
• CPC Class Codes: B01D 2259/40081 Counter-current
• CPC Class Codes: B01D 2259/402 using two beds
• CPC Class Codes: B01D 53/0446 Means for feeding or distributing gases
• CPC Class Codes: B01D 53/053 with storage or buffer vessel
• CPC Class Codes: B01D 53/229 Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
• CPC Class Codes: C01B 13/0251 by making use of membranes
• CPC Class Codes: C01B 13/0259 by adsorption on solids
• CPC Class Codes: C01B 21/045 by adsorption in solids
• CPC Class Codes: C01B 21/0494 Combined chemical and physical processing
• CPC Class Codes: C01B 2210/001 by making use of membranes
• CPC Class Codes: C01B 2210/0014 by adsorption in solids
• CPC Class Codes: C01B 2210/0045 Oxygen
• CPC Class Codes: Y10S 95/903 Carbon

Abstract

The present invention is a pressure swing adsorption process for separating a more strongly adsorbed gas component from a less strongly adsorbed gas component in a feed gas mixture at higher recoveries and productivity and less capital cost by the use of void space gas recycle, membrane based nitrogen enrichment of feed gas and the elimination of pressure equalization steps. The process is particularly amenable to air separation wherein nitrogen product is recovered and an oxygen byproduct is removed.

Claims

1. A pressure swing adsorption process for separating a feed gas containing at least nitrogen and oxygen into more strongly adsorbed oxygen and less strongly adsorbed nitrogen in at least two parallel zones of adsorbent, each zone proceeding through a series of steps out of phase with the other zone comprising;

(a) said feed gas at elevated pressure is contacted with a zone of a carbon molecular sieve adsorbent selective for oxygen, the oxygen is adsorbed and the nitrogen passes out of said zone as a product;

(b) said zone is initially depressurized countercurrently to remove void space gas and adsorbed gas as depressurization gas, with said depressurization gas recycled to a reservoir at an intermediate pressure and mixed with feed gas;

(c) said feed gas and depressurization gas are compressed to said elevated pressure of step (a);

(d) said zone is further depressurized to a lowest pressure by venting to regenerate said carbon molecular sieve adsorbent; and

,

(e) said zone is repressurized to said elevated pressure of step (a) with feed gas and nitrogen.

2. The process of claim 1 wherein said elevated pressure is in the range of approximately 80 to 135 psig.

3. The process of claim 1 wherein said reservoir is at a pressure in the range of approximately one quarter to one half of said elevated pressure.

4. The process of claim 1 wherein a nitrogen product is produced having a purity of at least 97%.

5. The process of claim 1 wherein said zone is further depressurized until gas depressurized from the zone has an oxygen content of approximately 21% oxygen.

6. The process of claim 1 wherein said zone is further depressurized in step (d) countercurrently to feed gas flow to said zone.

7. The process of claim 1 wherein said zone is further depressurized in step (d) to ambient pressure.

8. The process of claim 1 wherein said zone is further depressurized in step (d) to subambient pressure by application of a vacuum to a feed end of said zone.

9. The process of claim 1 wherein said feed gas initially contacts a membrane selectively permeable to oxygen to increase the nitrogen content of said feed gas as a reject stream and said reject stream is passed to said zone of carbon molecular sieve as the feed gas.

10. The process of claim 9 wherein gas depressurized in step (d) is passed over an oxygen permeate side of said membrane as a sweep gas to enhance permeation of oxygen through said membrane.

11. A pressure swing adsorption process for separating a feed gas containing nitrogen and oxygen into more strongly adsorbed oxygen and less strongly adsorbed nitrogen in at least two parallel zones of adsorbent, each zone proceeding through a series of steps out of phase with the other zone comprising;

(a) said feed gas initially contacts a membrane selectively permeable to oxygen to increase the nitrogen content of said feed gas as a reject stream;

(b) said reject stream at elevated pressure is contacted with a zone of a carbon molecular sieve adsorbent selective for oxygen, the oxygen is adsorbed and the nitrogen passes out of said zone as a product;

(b) said zone is initially depressurized countercurrently to remove void space gas and adsorbed gas as depressurization gas, with said depressurization gas recycled to a reservoir at an intermediate pressure and mixed with feed gas;

(c) said feed gas and depressurization gas are compressed to said elevated pressure of step (b);

(d) said zone is further depressurized to a lowest pressure to regenerate said carbon molecular sieve adsorbent and the resulting gas released during further depressurization is passed over an oxygen permeate side of said membrane as a sweep gas to enhance permeation of oxygen through said membrane; and

,

(e) said zone is repressurized to said elevated pressure of step (b) with feed gas and nitrogen.