Electrochemical capacitors having dissimilar electrodes

• US 5,429,893 A
• Filed: 02/04/1994
• Issued: 07/04/1995
• Est. Priority Date: 02/04/1994
• Status: Expired due to Fees

• Current Assignee: Motorola, Inc. (Motorola Solutions, Inc.)
• Original Assignee: Motorola, Inc. (Motorola Solutions, Inc.)
• Inventors: Thomas, George
• Primary Examiner(s): Niebling, John
• Assistant Examiner(s): Bell, Bruce F.
• Application Number:
  US08/191,910
• Time in Patent Office: 515 Days
• Field of Search: 429/194, 429/197, 429/218, 429/221, 429/223, 429/224, 429/233, 429/236, 361/502
• US Class Current: 429/333
• CPC Class Codes: H01G 11/02 using combined reduction-oxidation reactions, e.g. redox arrangement or solion
• CPC Class Codes: H01G 11/04 Hybrid capacitors
• CPC Class Codes: H01G 11/34 characterised by carbonisation or activation of carbon
• CPC Class Codes: H01G 11/58 Liquid electrolytes
• CPC Class Codes: H01G 11/62 characterised by the solute, e.g. salts, anions or cations therein
• CPC Class Codes: H01M 14/00 Electrochemical current or voltage generators not provided for in groups H01M6/00 - H01M12/00; Manufacture thereof
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors

Abstract

The invention provides for an improved pseudocapacitive device (10) having dissimilar electrodes (20) and (40). The first electrode (20) stores electrochemical charge via a double layer electrochemical mechanism, while the second electrode stores electrochemical charge via an oxidation/reduction reaction.

Claims

1. A high energy density, electrochemical capacitor device, said capacitor device comprising:

a first electrode fabricated of a carbon-based material, and said electrode stores charge via a double layer electrochemical mechanism;

a second electrode fabricated of an inorganic redox material selected from the group of materials consisting of Ru, Rh, Pd, Os, Ir, Co, Ni, Mn, Fe, Pt, Ru alloys, Rh alloys, Pd alloys, Os alloys, Ir alloys, Co alloys, Ni alloys, Fe alloys, Pt alloys, Ru oxides, Rh oxides, Pd oxides, Os oxides, Ir oxides, Co oxides, Ni oxides, Mn oxides, Fe oxides, Pt oxides, and combinations thereof; and

an electrolyte disposed between said first and second electrodes.

2. A device as defined in claim 1, wherein said electrolyte is a non-aqueous electrolyte.

3. A device as defined in claim 2, where said non-aqueous electrolyte is selected from the group of materials consisting of propylene carbonate/dimethoxyethanol/LiAsF₆, propylene carbonate/dimethoxyethanol/(CH₃)₄, ClO₄ propylene carbonate/dimethoxyethanol/LiClO₄, and combinations thereof.

4. A device as defined in claim 1, where said electrolyte is an aqueous electrolyte.

5. A device as defined in claim 4, wherein said aqueous electrolyte is selected from the group of materials consisting of KOH/H₂ O, LiOH/H₂ O, NaClO₄ /LiOH/H₂ O, NaOH/H₂ O, H₂ SO₄ /H₂ O, HClO₄ /H₂ O, and combinations thereof.

6. A high energy density electrochemical capacitor device comprising:

first and second electrodes formed of dissimilar materials, and characterized by different charge storage mechanisms, wherein said second electrode is fabricated of an inorganic redox material selected from the group of materials consisting of Ru, Rh, Pd, Os, Ir, Co, Ni, Mn, Fe, Pt, Ru alloys. Rh alloys, Pd alloys Os alloys, Ir alloys, Co alloys, Ni alloys, Fe alloys, Pd alloys, Ru oxides, Rh oxides, Pd oxides. Os oxides, Ir oxides, Co oxides, Ni oxide, Mn oxides, Fe oxides, Pt oxides, and combinations thereof; and

an electrolyte material disposed between said electrodes to facilitate charge transfer.

7. A device as defined in claim 6 wherein said first electrode is stores charge via a double layer electrochemical mechanism.

8. A device as in claim 7 wherein said first electrode is fabricated of a carbon based material selected from a group of materials consisting of activated carbon, petroleum coke, vitreous carbon, and combinations thereof.

9. A device as in claim 6 one said electrolyte is a non-aqueous electrolyte.

10. A device as in claim 6 wherein said electrolyte is an aqueous electrolyte.

11. A high energy density electrochemical capacitor device, said capacitor device comprising:

a first electrode fabricated of a carbon base material selected from the group of materials consisting of activated carbon, petroleum coke, vitreous carbon, and combinations thereof, and said electrode stores charge via a double layer electrochemical mechanism;

a second electrode fabricated of an inorganic redox material; and

an electrolyte disposed between said first and second electrodes.

12. A device as defined in claim 11, wherein said inorganic redox electrode is fabricated of materials selected from the group of materials consisting of Ru, Rh, Pd, Os, Ir, Co, Ni, Mn, Fe, Pt, Ru alloys, Rh alloys, Pd alloys, Os alloys, Ir alloys, Co alloys, Ni alloys, Fe alloys, Pt alloys, Ru oxides, Rh oxides, Pd oxides, Os oxides, Ir oxides, Co oxides, Ni oxides, Mn oxides, Fe oxides, Pt oxides, and combinations thereof.

13. A device as defined in claim 11, wherein said electrolyte is a non-aqueous electrolyte.

14. (new) A device as defined in claim 13, wherein said non-aqueous electrolyte is selected from the group of materials consisting of propylene carbonate/dimethoxyethanol/LiAsF₆, propylene carbonate/dimethoxyethanol/(CH₃)₄, ClO₄, propylene carbonate/dimethoxyethanol/LiClO₄, and combinations thereof.

15. A device as defined in claim 11, wherein said electrolyte is an aqueous electrolyte.

16. A device as defined in claim 15 wherein said aqueous electrolyte is selected from the group of materials consisting of KOH/H₂ O, LiOH/H₂ O, NaClO₄ /LiOH/H₂ O, NaOH/H₂ O, H₂ SO₄ /H₂ O, HClO₄ /H₂ O, and combinations thereof.