Nickel alloy electrodes for electrochemical devices

• US 5,429,895 A
• Filed: 10/13/1994
• Issued: 07/04/1995
• Est. Priority Date: 10/13/1994
• Status: Expired due to Fees

• Current Assignee: Motorola, Inc. (Motorola Solutions, Inc.)
• Original Assignee: Motorola, Inc. (Motorola Solutions, Inc.)
• Inventors: Bai, Lijun, Lian, Ke K.
• Primary Examiner(s): Niebling, John
• Assistant Examiner(s): Bell, Bruce F.
• Application Number:
  US08/322,130
• Time in Patent Office: 264 Days
• Field of Search: 429/209, 429/218, 429/221, 429/223, 429/224, 420/900, 361/508, 361/509, 361/516, 361/528, 361/529, 361/532
• US Class Current: 429/223
• CPC Class Codes: H01G 9/0425 specially adapted for cathode
• CPC Class Codes: H01M 14/00 Electrochemical current or voltage generators not provided for in groups H01M6/00 - H01M12/00; Manufacture thereof
• CPC Class Codes: H01M 4/38 of elements or alloys
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors
• CPC Class Codes: Y10S 420/90 Hydrogen storage

Abstract

A nickel alloy material for use as a cathode of an electrochemical charge storage device (10) provides significantly higher charge densities than available in prior art devices. The nickel alloy electrode (30) includes a host matrix material such as nickel, molybdenum, chromium, and combinations thereof, and at least one modifier element selected from the group consisting of cobalt, iron, aluminum, titanium, tungsten, vanadium, zirconium, niobium, and combinations thereof. The rechargeable electrode material may be incorporated into a charge storage device such as an electrochemical capacitor, and including an electrode fabricated of the material (30), an anode (20), and an electrolyte (40) disposed therebetween.

Claims

1. A rechargeable electrode for a rechargeable electrochemical capacitor device, said electrode having an oxidation/reduction charge storage mechanism, and comprising a multi-component material having host having a host matrix selected from the group consisting of nickel, molybdenum,chromium, and combinations thereof, and at least one modifier selected from the group consisting of cobalt, iron, aluminum, titanium, tungsten,vanadium, zirconium, niobium, and combinations thereof.

2. A rechargeable electrode material as in claim 1, wherein said material has the formula

3. A rechargeable electrode material as in claim 1, wherein said material has the formula Ni₅₈.5 Cr₂₁ Mo₁₃.5 W₃ Fe₄.

4. A rechargeable electrode material as in claim 1, wherein said material has the formula Ni₅₅.4 Cr₁₉ Co₁₁ Mo₁₁ Al₁.5 Ti₃.1.

5. A rechargeable electrode material as in claim 1, wherein said material has the formula Ni₇₂ Mo₂₈.

6. A rechargeable electrode material as in claim 1, wherein said material has the formula Ni₅₈.7, Co₁₃.5, Cr₁₉.5, Mo₄.3, Al_l.3, Ti₃.0.

7. A rechargeable electrode material as in claim 1, wherein said material is a crystalline or polycrystalline material.

8. A rechargeable electrode material as in claim 7, wherein said crystalline material has a face-centered cubic crystallographic structure.

9. A rechargeable electrode material as in claim 7, where said material is a multiphase material.

10. A rechargeable electrode material as in claim 1, wherein said material is a single phase amorphous material.

11. A rechargeable electrochemical capacitor charge storage device comprising:

an anode;

an electrolyte; and

a cathode having an oxidation/reduction charge storage mechanism, and comprising a multi-component material having a host matrix selected from the group consisting of nickel, molybdenum, chromium and combinations thereof, and at least one modifier selected from the group consisting of cobalt, iron, aluminum, titanium, tungsten, vanadium, zirconium, niobium and combinations thereof and their oxides.

12. A rechargeable electrochemical capacitor as in claim 11, wherein said cathode is fabricated of a material having the formula:

space="preserve" listing-type="equation">Ni.sub.a Mo.sub.b Cr.sub.c M.sub.d

where M is said modifier, a is between 30 and 90, b is between 10 to 50 and c is between 10 and 50, and d is between 0 and 30.

13. A rechargeable electrochemical capacitor as in claim 11, wherein said material has the formula Ni₅₈.5 Cr₂₁ Mo₁₃.5 W₃ Fe₄.

14. A rechargeable electrochemical capacitor as in claim 11, wherein said material has the formula Ni₅₅.4 Cr₁₉ Co₁₁ Mo₁₁ Al₁.5 Ti₃.1.

15. A rechargeable electrochemical capacitor as in claim 11, wherein said material has the formula Ni₇₂ Mo₂₈.

16. A rechargeable electrochemical capacitor as in claim 11, wherein said material has the formula Ni₅₈.7, Co₁₃.5, Cr₁₉.5, Mo₄.3, Al₁.3, Ti₃.0.

17. A rechargeable electrochemical capacitor as in claim 11, wherein said material is crystalline or polycrystalline.

18. A rechargeable electrochemical capacitor as in claim 17, wherein said crystalline material has a face-centered cubic crystallographic structure.

19. A rechargeable electrochemical capacitor as in claim 17, wherein said material is multiphase.

20. A rechargeable electrochemical capacitor as in claim 17, wherein said material is a single phase amorphous material.