Metal pretreated with an aqueous solution containing a dissolved inorganic silicate or aluminate, an organofuctional silane and a non-functional silane for enhanced corrosion resistance

• US 5,433,976 A
• Filed: 03/07/1994
• Issued: 07/18/1995
• Est. Priority Date: 03/07/1994
• Status: Expired due to Term

• Current Assignee: University of Cincinnati
• Original Assignee: Armco Inc. (Cleveland-Cliffs Steel Holding Corp.)
• Inventors: van Ooij, Wim J., Sabata, Ashok
• Primary Examiner(s): Silverberg, Sam
• Application Number:
  US08/207,565
• Time in Patent Office: 498 Days
• Field of Search: 427/327, 427/337, 427/388.4, 427/387
• US Class Current: 427/327
• CPC Class Codes: B05D 7/16 using synthetic lacquers or varnishes
• CPC Class Codes: B05D 7/54 No clear coat specified
• CPC Class Codes: C23C 22/60 using alkaline aqueous solutions with pH greater than 8
• CPC Class Codes: C23C 22/83 Chemical after-treatment
• CPC Class Codes: C23C 2222/20 Use of solutions containing silanes

Abstract

Painted metal sheet pretreated with an insoluble, composite layer containing siloxane. The composite layer is formed by rinsing the sheet with an alkaline solution containing at least 0.005M of a dissolved silicate or a dissolved aluminate, at least 0.1 vol.-% of an organofunctional silane and at least 0.02 vol.-% of a crosslinking-agent having two or more trialkoxysilyl groups. After the sheet is dried, the composite layer has a thickness of at least 10 Å. After being painted, the siloxane forms a tenacious covalent bond between the paint and the metal substrate.

Claims

1. A method of pretreating metal to improve corrosion resistance, comprising the steps of:

providing an alkaline solution containing at least one of a dissolved inorganic silicate and a dissolved inorganic aluminate, an organofunctional silane and a crosslinking agent including two or more trialkoxysilyl groups,

the alkaline solution containing at least 0.005M of at least one of the silicate or the silicate or the aluminate,

rinsing a metal sheet with the alkaline solution, and

drying the sheet to form a relatively insoluble composite layer containing siloxane.

2. The method of claim 1 including the additional step of painting the composite layer.

3. The method of claim 1 wherein the alkaline solution includes at least 0.1 vol.-% of the crosslinking agent.

4. The method of claim 1 wherein the alkaline solution includes at least 0.1 vol.-% of the organofunctional silane.

5. The method of claim 4 wherein the alkaline solution includes 0.2-5.0 vol.-% of the organofunctional silane.

6. The method of claim 1 wherein the ratio of the organofunctional silane to the crosslinker in the alkaline solution is in the range of 2:

1 to 10;

1.

7. The method of claim 1 wherein the metal sheet is a cold rolled steel coated with a layer of zinc phosphate or iron phosphate prior to being rinsed with the alkaline solution.

8. The method of claim 1 wherein the alkaline solution has a pH≧

12 and the organofunctional silane is APS.

9. The method of claim 3 wherein the alkaline solution includes at least 0.005M of a metal salt.

10. The method of claim 1 wherein the crosslinking agent is TMSE.

11. The method of claim 1 wherein the metal sheet is aluminum or an aluminum alloy and the alkaline solution contains at least 0.005M of the aluminate.

12. The method of claim 1 wherein the metal sheet is steel coated with an aluminum or an aluminum alloy metallic coating and the alkaline solution contains at least 0.005M of the aluminate.

13. A method of pretreating steel to improve corrosion resistance and paint adhesion, comprising the steps of:

providing an alkaline solution containing at least at least 0.005M of one of a dissolved inorganic silicate and a dissolved inorganic aluminate, 0.1-5.0 vol.-% of an organofunctional silane, at least 0.1 vol.-% of a crosslinking agent including two or more trialkoxysilyl groups, rinsing a steel sheet with the alkaline solution,

drying the sheet to form a relatively insoluble composite layer containing siloxane, and

painting the composite layer whereby the siloxane forms an adherent covalent bond between the paint and the steel substrate.