Method for producing electrochemical cell

• US 5,435,054 A
• Filed: 11/15/1993
• Issued: 07/25/1995
• Est. Priority Date: 11/15/1993
• Status: Expired due to Fees

• Current Assignee: Valence Technology Incorporated (Lithium Werks B.V.)
• Original Assignee: Valence Technology Incorporated (Lithium Werks B.V.)
• Inventors: Tonder, Pia E., Shackle, Dale R.
• Primary Examiner(s): Maples, John S.
• Application Number:
  US08/152,771
• Time in Patent Office: 617 Days
• Field of Search: 29/623.5, 29/623.1, 429/192
• US Class Current: 29/623.5
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/0565 Polymeric materials, e.g. gel-type or solid-type
• CPC Class Codes: H01M 4/04 Processes of manufacture in general
• CPC Class Codes: H01M 4/0404 by coating on electrode collectors
• CPC Class Codes: H01M 4/0409 by a doctor blade method, slip-casting or roller coating
• CPC Class Codes: H01M 4/0411 by extrusion
• CPC Class Codes: H01M 4/0435 Rolling or calendering
• CPC Class Codes: H01M 6/188 Processes of manufacture
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y10T 29/49108 Electric battery cell making
• CPC Class Codes: Y10T 29/49115 including coating or impregnating

Abstract

In a new process for making a cathode current collector assembly, a cathode composition is positioned on a substrate between the substrate and a releasable layer. Next, force is applied on the releasable layer and directed toward the substrate so as to provide a smooth cathode surface in contact with the releasable layer. The cathode composition having the releasable layer maintained thereon is cooled to reduce the tackiness of the cathode composition and then the releasable layer is removed while the cathode composition remains in its condition of reduced tackiness. In an alternative process, the cathode composition is applied and then force is applied immediatly before or simultaneously with cooling the composition to a state of reduced tackiness. An electrolyte composition is applied to the smooth surface cathode and the cathode and electrolyte compositions are cured together. In a final step, an anode layer is applied onto the electrolyte composition to form a cell assembly and further curing may occur.

Claims

1. A process for making an electrochemical cell comprising the steps of:

a. applying a cathode composition onto a current collector providing an external surface of such composition which is not in contact with the current collector;

b. applying a releasable layer onto the external surface of the cathode composition;

c. applying pressure to the external surface of the cathode composition sufficient to reduce discontinuities and irregularities on the external surface;

d. cooling the cathode composition of step (c) for a time and at a temperature each sufficient to reduce the temperature of the cathode composition to -20°

C. or less to reduce the tackiness thereof;

e. removing the releasable layer while maintaining such cathode composition in a condition of reduced tackiness;

f. applying an ionically conductive electrolyte composition onto the cathode composition of step (e);

g. at least partially curing the cathode and the electrolyte compositions; and

h. applying an anode layer onto the electrolyte composition of step (g) to form a cell assembly.

2. The process according to claim 1 wherein the step of applying pressure comprises rolling with a pressure roller the external surface of the releasable layer which is not in contact with the cathode composition.

3. The process according to claim 1 wherein the releasable layer comprises Mylar (polyethylene terephthalate, PET), Teflon (polytetrafluoroethylene), or silicone coated polyethylene.

4. The process according to claim 1 wherein the cathode composition comprises an active cathode material, an electrically conductive material, and an ionically conductive material.

5. The process according to claim 1 comprising the additional step of applying pressure to the cell assembly sufficient to further adhere the anode layer to the electrolyte composition and the electrolyte composition to the cathode composition.

6. A process for making an electrochemical cell comprising the steps of:

a. applying a cathode composition onto a current collector providing an external surface of such composition which is not in contact with the current collector;

b. applying a releasable layer onto the external surface of the cathode composition;

c. applying pressure to the external surface of the cathode composition sufficient to reduce discontinuities and irregularities on the external surface;

d. cooling the cathode composition of step (c) for a time and at a temperature sufficient to substantially solidify the cathode composition to reduce the tackiness thereof;

e. removing the releasable layer while maintaining such cathode composition in a condition of reduced tackiness;

f. applying an ionically conductive electrolyte composition onto the cathode composition of step (e);

g. at least partially curing the cathode and the electrolyte compositions; and

h. applying an anode layer onto the electrolyte composition of step (g) to form a cell assembly.

7. The process according to claim 6 wherein the step of applying pressure comprises rolling with a pressure roller the external surface of the releasable layer which is not in contact with the cathode composition.

8. The process according to claim 6 wherein the releasable layer comprises Mylar (polyethylene terephthalate, PET), Teflon (polytetrafluoroethylene), or silicone coated polyethylene.

9. The process according to claim 6 wherein the cathode composition comprises an active cathode material, an electrically conductive material, and an ionically conductive material.

10. The process according to claim 9 wherein the ionically conductive material comprises an ionically conductive polymeric matrix and an ionically conductive powder or such matrix and an alkali metal salt complexed with a conductive liquid.

11. The process according to claim 6 comprising the additional step of applying pressure to the cell assembly sufficient to further adhere the anode layer to the electrolyte composition and the electrolyte composition to the cathode composition.

12. A process for making a cathode/current collector comprising the steps of:

a. positioning a cathode composition on a substrate between the substrate and a releasable layer;

b. directing pressure on the releasable layer and toward the substrate;

c. cooling the cathode composition for a time and at a temperature each sufficient to reduce the temperature of the cathode composition to -20°

C. or less to reduce the tackiness thereof; and

d. removing the releasable layer while maintaining the cathode composition in a condition of reduced tackiness.

13. The process according to claim 12 and including at least partially curing the cathode composition.

14. The process according to claim 12 and including:

a. applying an electrolyte composition onto the cathode composition of step 12(d);

b. at least partially curing the cathode and the electrolyte compositions; and

c. applying an anode layer onto the electrolyte composition to form a cell assembly.

15. The process according to claim 12 wherein the releasable layer comprises Mylar (polyethylene terephthalate, PET), Teflon (polytetrafluoroethylene), or silicone coated polyethylene.

16. A process for making a cathode/current collector comprising the steps of:

a. positioning a cathode composition on a substrate between the substrate and a releasable layer;

b. directing pressure on the releasable layer and toward the substrate;

c. cooling the cathode composition to substantially solidify the cathode composition to reduce the tackiness thereof; and

removing the releasable layer while maintaining the cathode composition in a condition of reduced tackiness.

17. The process according to claim 16 and including at least partially curing the cathode composition.

18. The process according to claim 16 and including

(a) applying an electrolyte composition onto the cathode composition of step 16(d);

(b) at least partially curing the cathode and the electrode compositions; and

(c) applying an anode layer onto the electrolyte composition to form a cell assembly.

19. The process according to claim 16 wherein the releasable layer comprises Mylar (polyethylene terephthalate, PET), Teflon (polytetrafluoroethylene), or silicone coated polyethylene.

20. A process for making an electrochemical cell comprising the steps of:

a. applying a cathode composition onto a current collector providing an external surface of such composition which is not in contact with the current collector;

applying pressure to the external surface of the cathode composition sufficient to reduce discontinuities on the external surface and essentially simultaneously cooling the cathode composition for a time and at a temperature sufficient to reduce the tackiness thereof by rolling the external surface with a chill roller;

applying an ionically conductive electrolyte composition onto the pressed and chilled cathode composition;

d. at least partially curing one or both of the cathode and the electrolyte compositions; and

e. applying an anode layer onto the electrolyte composition to form a cell assembly.

21. The process according to claim 20 comprising the additional step of applying pressure to the cell assembly sufficient to further adhere the anode layer to the electrolyte and the electrolyte to the cathode.

22. A process for making an electrochemical cell comprising the steps of:

a. applying a cathode composition onto a current collector providing an external surface of such composition which is not in contact with the current collector;

b. applying pressure to the external surface of the cathode composition sufficient to reduce discontinuities on the external surface;

c. cooling the cathode composition for a time and at a temperature sufficient to reduce the temperature of the cathode composition to a substantially solidified condition or to about -20°

C. or less thereby reducing the tackiness thereof;

d. applying an ionically conductive electrolyte composition onto the pressed and chilled cathode composition;

e. at least partially curing one or both of the cathode and the electrolyte compositions; and

f. applying an anode layer onto the electrolyte composition to form a cell assembly.

23. The process according to claim 22 wherein the step of applying pressure comprises rolling with a pressure roller the external surface of the cathode composition.

24. The process according to claim 22 comprising the additional step of applying pressure to the cell assembly sufficient to further adhere the anode layer to the electrolyte and the electrolyte to the cathode.

25. The process according to claim 22 wherein the step of applying pressure and the step of cooling are conducted essentially simultaneously.

26. A process for making a cathode/current collector comprising the steps of:

a. applying a cathode composition onto a substrate providing an external surface of such composition which is not in contact with the substrate;

b. directing pressure on the external surface and toward the substrate; and

c. immediately after step (b) and/or during step (b), cooling the cathode composition to reduce the temperature of the cathode composition to a substantially solidified condition or to about -20°

C. or less thereby reducing the tackiness thereof.

27. The process according to claim 26 and including at least partially curing the cathode composition.

28. The process according to claim 26 and further including after step 26(c);

a. applying an electrolyte composition onto the cathode composition;

b. at least partially curing the cathode and the electrolyte compositions; and

c. applying an anode layer onto the electrolyte composition to form a cell assembly.

29. A process for making a cathode/current collector comprising the steps of:

a. applying a cathode composition onto a substrate providing an external surface of such composition which is not in contact with the substrate; and

b. directing pressure on the external surface and toward the substrate, and cooling the cathode composition to reduce the tackiness thereof by rolling the external surface with a chill roller.

30. The process according to claim 29 and including at least partially curing the cathode composition.

31. The process according to claim 29 and further including after step 29(b):

a. applying an electrolyte composition onto the cathode composition;

b. at least partially curing the cathode and the electrolyte compositions; and

c. applying an anode layer onto the electrolyte composition to form a cell assembly.

32. A process for making a cathode/current collector comprising the steps of:

a. applying a cathode composition onto a substrate providing an external surface of such composition which is not in contact with the substrate;

b. directing pressure on the external surface and toward the substrate;

c. immediately after step (b) and/or during step (b), cooling the cathode composition to reduce the tackiness thereof; and

d. after step (c), at least partially curing the cathode composition.

33. A process for making a cathode/current collector comprising the steps of:

a. applying a cathode composition onto a substrate providing an external surface of such composition which is not in contact with the substrate;

b. directing pressure on the external surface and toward the substrate;

c. immediately after step (b) and/or during step (b), cooling the cathode composition to reduce the tackiness thereof;

d. after step (c), the additional steps of;

i. applying an electrolyte composition onto the cathode composition;

ii. at least partially curing the cathode and the electrolyte compositions; and

iii. applying an anode layer onto the electrolyte composition to form a cell assembly.