Process for improving the adhesiveness of electrolessly deposited metal films

• US 5,436,034 A
• Filed: 12/19/1994
• Issued: 07/25/1995
• Est. Priority Date: 03/25/1992
• Status: Expired due to Fees

• Current Assignee: I & T Innovation Technology Entwicklungs-Und Holding AG
• Original Assignee: Bayer AG
• Inventors: Giesecke, Henning, Haese, Wilfried, Wolf, Gerhard-Dieter
• Primary Examiner(s): PIANALTO, BERNARD D
• Application Number:
  US08/358,660
• Time in Patent Office: 218 Days
• Field of Search: 427/493, 427/508, 427/510, 427/558, 427/559, 427/96, 427/123, 427/126.1, 427/264, 427/265, 427/270, 427/272, 427/282, 427/272.2, 427/385.5, 427/407.1 , 427/419.1, 427/443.1
• US Class Current: 427/508
• CPC Class Codes: C23C 18/30 Activating or accelerating or sensitising with palladium or other noble metal
• CPC Class Codes: H05K 3/181 by electroless plating adhesives therefor H05K3/387
• CPC Class Codes: H05K 3/387 for electroless plating H05K3/4661 takes precedence

Abstract

Electrolessly deposited metal films having improved adhesion can be obtained by coating the surface of the substrates to be metallized with a formulation consisting of UV-curable varnishes which contain noble metal compounds as activators and, in addition, either fillers or solvents or a combination of fillers and solvents, curing these varnishes by means of UV radiation, followed by electroless metallization of the substrates thus treated.

Claims

1. A process for the electroless deposition of strongly adhering metal films on the surfaces of nonconducting substrates, which consists essentially of the steps of

a) coating the surfaces with UV-curable formulations, comprising

i) a binder selected from the group consisting of unsaturated polyesters, polyester acrylates, epoxy acrylates and urethane acrylates,

ii) a reactive diluent selected from the group consisting of styrene, vinyl acetate, N-vinylpyrrolidone, 2-ethylhexyl acrylate, 2-ethoxyethyl acrylate, 1,6-hexanediol diacrylate, trimethylolpropane acrylates, tripropylene glycol diacrylate, trimethylolpropylformal monoacrylate and pentaerythritol tetraacrylate, and

iii) a photoinitiator selected from the group consisting of diketals, benzoin ethers, acetophenones, benzophenones and thioxanthones,

b) curing the coated surfaces with UV radiation and

c) electroless metallisation of the UV-cured films,

wherein the formulations contain, apart from the customary components of UV-curable varnishes, 0.5 to 5% by weight of noble metal compounds from subgroup I or VIII of the periodic table (Mendeleev) as metallisation activators and, in addition, 2 to 20% by weight of fillers and 1-25% by weight of solvents, the weights given being based on the entire amount of the formulation.

2. The process of claim 1, wherein the noble metal compounds used acre organic noble metal compounds.

3. The process of claim 1, wherein the noble metal compounds used are organic palladium compounds.

4. The process of claim 1, wherein the amounts of noble metal compounds are 0.8 to 4% by weight.

5. The process of claim 4, wherein the amounts of noble metal compounds are 1 to 3% by weight.

6. The process of claim 1, wherein the amounts of fillers are 3 to 15% by weight.

7. The process of claim 6, wherein the amounts of fillers are 5 to 15% by weight.

8. The process of claim 1, wherein the amounts of solvents are 5 to 20% by weight.

9. The process of claim 8, wherein the amounts of solvents are 10 to 20% by weight.

10. The process of claim 1, wherein metal films for printed circuits, key pads, switch mats, sensors and electromagnetic screens are deposited.

11. A process for the electroless deposition of strongly adhering metal films on the surfaces of non-conducting substrates, which consists essentially of the steps of

a) coating the surfaces with UV-curable formulations, comprising

i) a binder selected from the group consisting of unsaturated polyesters, polyester acrylates, epoxy acrylates and urethane acrylates,

ii) a reactive diluent selected from the group consisting of styrene, vinyl acetate, N-vinylpyrrolidone, 2-ethylhexyl acrylate, 2-ethoxyethyl acrylate, 1,6-hexanediol diacrylate, trimethylolpropane acrylates, tripropylene glycol diacrylate, trimethylolpropylformal monoacrylate and pentaerythritol tetraacrylate, and

iii) a photoinitiator selected from the group consisting of diketals, benzoin ethers, acetophenones, benzophenones and thioxanthones,

b) exposing the coated surface to light through a mask which allows exposure of only part of the coating.

c) removing the nonexposed portion of the coating from the coated surface,

d) electroless metallisation of the cured coating which remains on the surface of the substrate,

wherein the formulations contain, apart from the customary components of UV-curable varnishes, 0.5 to 5% by weight of noble metal compounds from subgroup I or VIII of the periodic table (Mendeleev) as metallisation activators and, in addition, 2 to 20% by weight of fillers and 1-25% by weight of solvents, the weights given being based on the entire amount of the formulation.