Fiber optics gas sensor

• US 5,436,167 A
• Filed: 04/13/1993
• Issued: 07/25/1995
• Est. Priority Date: 04/13/1993
• Status: Expired due to Fees

• Current Assignee: Board of Regents of the University of Texas System (University of Texas System)
• Original Assignee: Board of Regents of the University of Texas System (University of Texas System)
• Inventors: Robillard, Jean J.
• Primary Examiner(s): Warden, Robert J.
• Assistant Examiner(s): Thornton, Krisanne M.
• Application Number:
  US08/046,977
• Time in Patent Office: 833 Days
• Field of Search: 422/82.01, 422/82.05, 422/82.06, 422/82.08, 422/82.09, 422/82.11, 422/83, 422/88, 422/91, 422/94, 422/98, 436/165, 436/172, 436/167, 385/128, 385/141, 385/145, 385/12
• US Class Current: 436/165
• CPC Class Codes: G01N 21/7703 using reagent-clad optical fibres or optical waveguides using measurement of total internal reflection or attenuated total reflection G01N21/552; optical fibres or waveguides per se G02B

Abstract

The adsorption of gas on a solid surface can produce considerable variation in the optical properties of the solid surface and eventually lead to the identification of the gas adsorbed. An optical waveguide having at least a portion of its length circumferentially coated with a transparent semiconductor material may function as a gas sensor. The sensor functions by exchanging electrons with a detectable gas brought in proximity with the coating material at reactive sites on the material'"'"'s surface by the process of adsorption, thereby varying the refractive index of the transparent semiconductor material and altering the ellipticity of a light transmission through the optical waveguide. Substantially monochromatic polarized light is transmitted through the optical waveguide and then quantified by a light detector. A meter or other device connected to the light detector is adjusted to register a variation in the signal received by the light detector, indicating the presence of a detectable gas.

Claims

1. An apparatus for detecting the presence of a gas for use with a source of elliptically polarized light, comprising:

an optical waveguide having a circumference; and

a transparent variable index means deposited in a layer over at least a portion of the circumference of said optical waveguide for exchanging electrons with a gas to be detected at reactive sites on the surface of said variable index means by the process of adsorption, thereby varying the refractive index of said variable index means and altering the ellipticity of a light transmitted through the optical waveguide as a function of the presence of said gas.

2. The apparatus of claim 1, wherein said optical waveguide comprises a fiber optic cable with an optical core coated circumferentially with cladding material over a portion of the length of said cable, and coated with said variable index means in a layer over another portion of the length of said cable.

3. The apparatus of claim 1, wherein said variable index means comprises an organic semiconductor.

4. The apparatus of claim 1, further comprising a light emitting means for emitting substantially monochromatic polarized light through a first end of said optical waveguide, said polarized light being elliptically polarized.

5. The apparatus of claim 4, further comprising an optical-to-electronic detector, which comprises:

polarizing means optically coupled to a second end of said optical waveguide for converting the components of light transmitted through said optical waveguide into plane polarized light;

analyzing means for receiving plane polarized light from said polarizing means and selectively allowing the passage of said light according to the ellipticity of said received light;

light detecting means for detecting light selectively passed through said analyzing means; and

a meter electrically connected to said light detecting means.

6. A system for detecting the presence of a gas, comprising:

an optical light source;

an optical waveguide having an input end and an output end, said input end elliptically coupled to said light source, said optical waveguide having a circumference;

transparent variable index means deposited along at least a portion of the circumference of said waveguide for exchanging electrons with a gas to be detected at reactive sites on the surface of said variable index means by the process of adsorption, thereby varying the refractive index of said variable index means and altering the ellipticity of a light transmitted through the optical waveguide; and

optical-to-electronic detector means optically coupled to the output end of the waveguide for detecting and quantifying the presence of a gas to be detected by detecting a change in the ellipticity of a light transmitted through said optical waveguide.

7. The system of claim 6, wherein said variable index means comprises an organic semiconductor material.

8. An apparatus for detecting the presence of a gas, comprising:

a pair of optical waveguides comprising a first optical waveguide optically coupled to a second optical waveguide at a contact area, each said optical waveguide having a circumference;

transparent variable index means deposited in a layer over at least a portion of the circumference of each of said optical waveguides proximal said contact area for exchanging electrons with a gas to be detected at reactive sites on the surface of said variable index means by the process of adsorption, thereby varying the refractive index of said semiconductor material and altering the ratio of a light transmission through said optical waveguides; and

optical-to-electronic detector means located at a first end of said pair of optical waveguides for detecting and quantifying the presence of a gas to be detected by detecting a change in said ratio of light transmitted through said optical waveguides.

9. The apparatus of claim 8, wherein said variable index means comprises an organic semiconductor.

10. The apparatus of claim 8, further comprising a light emitting means for emitting substantially monochromatic, polarized light through a second end of said first optical waveguide.

11. The apparatus of claim 8, wherein said first and second optical waveguides are fiber optic cables, each further comprising a fiber optic core circumferentially surrounded by cladding material over a portion of the length of each of said cables and coated with said variable index means in a layer over another portion of the length of each of said cables proximal said contact area.

12. The apparatus of claim 11, said optical-to-electronic light detector means further comprising:

light detector means optically coupled to an output end of each of said pair of optical waveguides for measuring an intensity of light transmitted through each of said first and second optical waveguides, respectively;

differential amplifier means electronically coupled to each of said light detector means for measuring a difference in the ratio of light intensity received by said light detector means; and

a meter electronically coupled to said differential amplifier means.

13. A method of detecting gas, comprising the steps of:

providing an optical waveguide upon which transparent semiconductor material has been deposited in a sensor layer over at least a portion of a circumference of said optical waveguide;

placing said semiconductor-coated optical waveguide in a chamber;

propagating polarized light through said optical waveguide;

detecting and quantifying light transmitted from said optical waveguide;

allowing a gas to be detected to enter said chamber;

reacting said gas with said semiconductor sensor layer whereby said semiconductor material exchanges electrons in said gas at reactive sites on the surface of said semiconductor material by the process of adsorption, thereby varying the refractive index of said semiconductor material and alters the ellipticity of said light propagated through the optical waveguide; and

detecting a change in said ellipticity of said light transmitted from said optical waveguide in the presence of said gas.

14. The method of claim 13, wherein said transparent semiconductor material is organic.

15. The method of claim 13, said propagating step further comprising:

providing a light emitter means for emitting substantially monochromatic polarized light.

16. The method of claim 13, said detecting and quantifying step further comprising the steps of:

converting the components of light transmitted from said optical waveguide into plane polarized light;

modulating the transmission of said light transmitted from said optical waveguide; and

selectively detecting the presence of said light according to the ellipticity of said light.

17. The method of claim 16, wherein said change-detecting step further comprises positioning an analyzer means optically coupled to an output end of said optical waveguide to allow light to be detected only when a gas to be detected has become adsorbed on the surface of said semiconductor sensor layer.

18. A method of detecting gas, comprising the steps of:

providing a pair of optical waveguides comprising a first optical waveguide optically coupled to a second optical waveguide at a contact area, said first and second optical waveguides each having a transparent semiconductor material deposited in a layer over at least a portion of its circumference proximal said contact area;

placing said optical waveguide pair in a chamber;

transmitting polarized light through said first optical waveguide;

detecting and quantifying light transmitted through said optical waveguide pair;

allowing a gas to be detected to enter said chamber;

reacting said gas with said transparent semiconductor layer whereby said semiconductor material exchanges electrons with said gas at reactive sites on the surface of said semiconductor material by the process of adsorption, thereby varying the refractive index of said semiconductor material and altering the ratio of said light transmission through said optical waveguides; and

detecting a change in said ratio of said light transmitted from said optical waveguides in the presence of said gas.

19. The method of claim 18, said transmitting step further comprising:

providing a light emitting means for emitting substantially monochromatic polarized light.

20. The method of claim 18, wherein said transparent semiconductor material is organic.

21. The method of claim 18, said detecting and quantifying step further comprising the steps of:

providing a pair of photodiodes comprising a first photodiode optically coupled to said first optical waveguide and a second photodiode optically coupled to said second optical waveguide;

quantifying a ratio of light intensity received by said photodiode pair; and

receiving a reference ratio value in the absence of a detectable gas; and

indicating when said ratio of light intensity received by said photodiode pair differs from said reference ratio value.

22. An apparatus for detecting the presence of a gas for use with a source of light, comprising:

an optical waveguide having a circumference, a light-input end and a light-emitting end; and

a variable index means deposited in a layer over at least a portion of the circumference of said optical waveguide for altering the ellipticity of a light transmission through the optical waveguide as a function of the presence of said gas.

23. The apparatus of claim 22, wherein said variable index means comprises an organic, transparent semiconductor material.

24. The apparatus of claim 23, wherein said semiconductor material is selected from the group consisting of Cu (II) Phtalocyanine, Polypyrrole, Polyaminoquinone, and Co (III) dithiooxamide.

25. The apparatus of claim 22, further comprising an optical-to-electronic detector, which comprises:

polarizing means optically coupled to said light-emitting end of said optical waveguide for converting the components of light transmitted into said light-input end and through said optical waveguide into plane polarized light;

analyzing means for receiving plane polarized light from said polarizing means and selectively allowing the passage of said light according to the ellipticity of said received light;

light detecting means for detecting light selectively passed through said analyzing means; and

a meter electrically connected to said light detecting means.

26. An apparatus for detecting the presence of a gas for use with a source of light, comprising:

an optical waveguide having a circumference; and

a transparent, organic semiconductor material deposited in a layer over at least a portion of the circumference of said optical waveguide.

27. The apparatus of claim 26, wherein said semiconductor material is selected from the group consisting of Cu (II) Phtalocyanine, Polypyrrole, Polyaminoquinone, and Co (III) dithiooxamide.

28. An apparatus for detecting the presence of a gas, comprising:

a pair of optical waveguides comprising a first optical waveguide optically coupled to a second optical waveguide at a contact area, each said optical waveguide having a circumference;

variable index means deposited in a layer over at least a portion of the circumference of each of said optical waveguides proximal said contact area for altering the relative proportion of a light transmission through each of said optical waveguides in response to adsorption of a gas by said variable index means; and

optical-to-electronic detector means located at a first end of each of said pair of optical waveguides for detecting and quantifying the presence of a gas to be detected by detecting a change in a ratio of light transmitted through each of said optical waveguides, respectively.

29. The apparatus of claim 28, wherein said variable index means comprises a transparent, organic semiconductor.

30. The apparatus of claim 28, said optical-to-electronic light detector means further comprising:

light detector means optically coupled to an output end of each of said pair of optical waveguides for measuring an intensity of light transmitted through each of said first and second optical waveguides, respectively;

differential amplifier means electronically coupled to each of said light detector means for measuring a difference in a ratio of light intensity received by said light detector means; and

a meter electronically coupled to said differential amplifier means.