Method and apparatus for injection of a liquid waste into a molten bath

• US 5,436,210 A
• Filed: 02/04/1993
• Issued: 07/25/1995
• Est. Priority Date: 02/04/1993
• Status: Expired due to Term

• Current Assignee: Quantum Catalytics LLC
• Original Assignee: Molten Metal Technology Incorporated
• Inventors: Rauenzahn, Rick M., Nagel, Christopher J., Wilkinson, Mark A.
• Primary Examiner(s): Straub, Gary P.
• Application Number:
  US08/013,756
• Time in Patent Office: 901 Days
• Field of Search: 588/201, 588/209, 588/900, 266/267, 266/268, 266/221, 266/222, 423/DIG. 12
• US Class Current: 588/314
• CPC Class Codes: A62D 2203/10 Apparatus specially adapted for treating harmful chemical agents; Details thereof
• CPC Class Codes: B01J 10/005 carried out at high temperatures in the presence of a molten material
• CPC Class Codes: B01J 4/002 Nozzle-type elements nozzle-type reactors B01J19/26
• CPC Class Codes: F27B 3/00 Hearth-type furnaces, e.g. of reverberatory type F27B9/00, F27B11/00, F27B13/00, F27B14/00, F27B15/00, F27B21/00 take precedence; Tank furnaces
• CPC Class Codes: F27B 3/085 Arc furnaces
• CPC Class Codes: F27B 3/10 Details, accessories, or equipment peculiar to hearth-type furnaces
• CPC Class Codes: F27B 3/20 Arrangements of heating devices
• CPC Class Codes: F27B 3/225 Oxygen blowing
• CPC Class Codes: F27D 17/001 Extraction of waste gases, collection of fumes and hoods used therefor in general B08B15/00
• CPC Class Codes: F27D 17/004 Systems for reclaiming waste heat
• CPC Class Codes: F27D 17/008 cleaning gases
• CPC Class Codes: F27D 2003/162 the fluid being an oxidant or a fuel
• CPC Class Codes: F27D 2003/164 Oxygen
• CPC Class Codes: F27D 2003/166 the fluid being a treatment gas
• CPC Class Codes: F27D 2099/0051 Burning waste as a fuel
• CPC Class Codes: F27D 3/1518 Tapholes
• CPC Class Codes: F27D 3/16 Introducing a fluid jet or current into the charge porous elements for gas flushing of molten metals B22D1/005
• CPC Class Codes: F27D 3/18 Charging particulate material using a fluid carrier
• CPC Class Codes: F27M 2001/02 Charges containing ferrous elements
• CPC Class Codes: F27M 2001/05 Waste materials, refuse
• CPC Class Codes: Y10S 423/12 : Molten media
• CPC Class Codes: Y10S 588/90 : Apparatus

Abstract

A method and apparatus are disclosed for injecting liquids into a molten bath. The method includes forming a suitable liquid dispersion of a liquid phase disposed in a gas phase. The liquid phase has a ratio of surface area to volume which is sufficient to cause an accumulated amount of the liquid phase in the molten bath to be significantly less than that which would occur by injection of a continuous stream of the liquid into the molten bath. The liquid dispersion is directed into the molten metal bath, whereby the liquid volatilizes or decomposes. The rate at which the liquid dispersion is injected into the molten bath is sufficient to cause the liquid of the liquid phase to volatilize or decompose at a rate which is sufficient to cause the accumulation of the liquid phase in the bath to be significantly less than that which would occur by injection of a continuous stream of the liquid into the molten bath. The apparatus includes an atomizer which is disposed at a reactor containing the molten bath. The atomizer can be, for example, a tuyere which atomizes a suitable liquid to form a liquid dispersion of the liquid in a gas. The liquid dispersion is directed into the molten bath through the tuyere for volatilization or decomposition of the liquid.

Claims

1. A method for injecting a liquid into a molten metal bath, comprising the steps of:

a) atomizing a liquid in the presence of a gas to form a liquid dispersion having a liquid phase dispersed in a gas phase, and wherein the liquid phase has a ratio of surface area to volume which is sufficient to cause an accumulated amount of the liquid phase in the molten metal bath to be less than that which would occur by injection of a continuous stream of the liquid into the molten metal bath at an equal feed rate; and

thereafter

b) directing the liquid dispersion into a molten metal bath, having a temperature which is significantly greater than the nucleation temperature of the liquid phase at the operating conditions of the molten metal bath, at a rate which is sufficient to cause liquid of the liquid phase to volatilize or decompose at a rate which is sufficient to cause the accumulation of the liquid phase in the bath to be less than that which would occur by injection of a continuous stream of the liquid into the molten metal bath at an equal feed rate.

2. The method of claim 1 wherein the liquid dispersion is directed into the molten metal bath at a plurality of points beneath an upper surface of the molten metal bath.

3. The method of claim 2 wherein the gas component of the liquid dispersion is inert under the operating conditions of the molten metal bath.

4. The method of claim 2 wherein a portion of the gas component of the liquid dispersion reacts with a component of the molten metal bath under the operating conditions of the molten metal bath.

5. The method of claim 4 wherein the liquid of the liquid dispersion is reactive under the operating conditions of the molten metal bath.

6. A method for injecting a liquid into a molten metal bath, comprising the steps of:

a) directing a liquid through a liquid conduit which is disposed within a gas conduit that is in fluid communication with a molten metal bath, the liquid having a nucleation temperature which is significantly lower than that of the molten metal bath, and wherein the liquid conduit has a liquid-discharge end which is recessed within the gas conduit at a distance from a gas-discharge end of the gas conduit at the molten bath which is sufficient to allow a gas which is directed through the gas conduit to substantially atomize the liquid and form a liquid dispersion prior to introduction of the liquid into the molten metal bath; and

thereafter

b) directing a gas through the gas conduit at a velocity, relative to the velocity of liquid discharge from the liquid-discharge end of the liquid conduit to cause the discharged liquid to atomize and form a liquid dispersion prior to introduction of the liquid into the molten metal bath, the liquid dispersion having a liquid phase dispersed in a gas phase.

7. A tuyere for atomizing a volatilizable liquid during submerged injection into a molten metal bath, comprising:

a) a liquid conduit, having a liquid-discharge end; and

b) a gas conduit, within which the liquid conduit is disposed, and having a gas-discharge end, wherein the liquid discharge end is recessed within the gas conduit at a distance from the gas discharge end which is sufficient to enable an atomizing gas, which is directed through the gas conduit, to atomize liquid discharged from the liquid conduit and form a liquid dispersion before the liquid contacts a molten metal bath into which the gas and the liquid are injected, the liquid dispersion having a liquid phase dispersed in a gas phase; and

c) an oxidant tube, within which the gas conduit is disposed, whereby the liquid dispersion can combine with an oxidant gas discharged from the oxidant tube during injection of the liquid dispersion into the molten metal bath.

8. The tuyere of claim 7, wherein the gas conduit further includes a tapered portion proximate to the liquid-discharge end.

9. The tuyere of claim 8 wherein the liquid discharge end of the liquid conduit is disposed within the tapered portion.

10. The tuyere of claim 9 wherein the gas conduit further includes an atomizing portion having substantially constant diameter, which extends between the tapered portion and the gas-discharge end.

11. The tuyere of claim 10, further including a nozzle disposed within the gas conduit and at the liquid-discharge end of the liquid conduit.

12. The tuyere of claim 11, wherein the oxidant tube includes a tapered portion which is disposed about the tapered portion of the gas conduit.

13. The tuyere of claim 12 further including a coolant tube which is disposed about the oxidant tube.