Solid state displacement elements

• US 5,436,372 A
• Filed: 04/09/1992
• Issued: 07/25/1995
• Est. Priority Date: 04/09/1991
• Status: Expired due to Fees

• Current Assignee: Nippon Soken, Inc.
• Original Assignee: Nippon Soken, Inc.
• Inventors: Yoshida, Hiroyuki, Fukushima, Yoshiaki, Yasuda, Eturo
• Primary Examiner(s): FAN, JANE T
• Application Number:
  US07/865,617
• Time in Patent Office: 1,202 Days
• Field of Search: 564/463, 564/291
• US Class Current: 564/291
• CPC Class Codes: C07C 211/03 Monoamines
• CPC Class Codes: H10N 30/857 Macromolecular compositions

Abstract

The invention is intended to provide novel solid state displacement elements that have an extent of displacement. The solid state displacement element has an intercalation compound in which a polar compound (B) is mixed with an inorganic layered compound (A), and produces a strain when a voltage is applied.

Claims

1. A solid state displacement element comprising:

an intercalation compound comprising inorganic layered compounds opposing each other, and a polar compound placed between said inorganic layered compounds, so that a distance formed between said inorganic compounds is extended when a voltage is applied across said intercalation compound, wherein said solid state displacement element is molded by a press-molding operation; and

said polar compound is at least one compound selected from the group consisting of n-hexylamine and n-hexyl trimethyl ammonium bromide.

2. A solid state displacement element according to claim 1 wherein at least 20% of said polar compound is intercalated into said inorganic layered compounds with respect to a possible amount of said polar compound to be intercalated into said inorganic layered compounds.

3. A solid state displacement element according to claim 1 wherein said inorganic layered compound is at least one compound selected from the group consisting of a mica based mineral, a smectite based mineral, a phyllosilicate of a kaolin based mineral, a layered polysilicate, a transition metal dicalcogenite, and a tungsten bronze based compound.

4. The solid state displacement element according to claim 3, wherein said mica based mineral is selected from the group consisting of muscovite mica and phlogopite mica;

said smectic base mineral is selected from the group consisting of vermiculite, montmorillomite, and saponite; and

phyllosilicate of a kaolin based mineral is selected from the group consisting of kaolinite and zirconium phosphates;

said layered polysilicate is selected from the group consisting of magadeite, and a layered titanate;

said transitional metal dicalcogenite is MoS₂ ; and

said tungsten bronze based compound is selected from the group consisting of KNiAsO₄ and HTaWO₆.

5. The solid state displacement element according to claim 4, wherein said layered titanate is selected from the group consisting of V₂ O₅ and Na₂ Ti₃ O₇.

8. A solid state displacement element comprising an intercalation compound as defined in any one of claims 1-3 or 6-7 such that said compound expands said element upon application of a voltage across element.

6. A solid state displacement element comprising:

an inter-layer compound comprised of a layered inorganic compound and a polar compound as the principal component, such that application of a voltage across said element expands the distance between said layers;

said polar compound being at least one compound selected from the group consisting of n-hexylamine and n-hexyl trimethyl ammonium bromide.

7. A solid state displacement element according to claim 6 wherein said inter-layer compound contains at least 20% of said polar compound.

9. A solid state displacement element comprising an intercalation compound as a main element, said intercalation compound comprising inorganic layered compounds, each being oppositely arranged;

and a polar compound interposed in a space formed between said inorganic layered compounds arranged oppositely to each other, said element being strained when electrical voltage is applied thereto;

said polar compound being at least one compound selected from the group consisting of n-hexylamine and n-hexyl trimethyl ammonium bromide.

10. A solid state displacement element comprising:

an intercalation compound comprising inorganic layered compounds opposing each other, and a polar compound placed between said inorganic layered compounds so that a distance formed between said inorganic compounds is extended when a voltage is applied across said intercalation compound, wherein said inorganic layered compound is selected from inorganic layered compound group which swell in water or other solvents and said polar compound is selected from polar compound group having a dipole moment of at least 0.7 Debye;

said polar compound being at least one compound selected from the group consisting of n-hexylamine and n-hexyl trimethyl ammonium bromide.

11. A solid state displacement element according to claim 10, wherein said solid state displacement element is molded by press-molding operation.

12. A solid state displacement element according to claim 10, wherein said polar compound is selected from polar compound group having a dipole moment of more than 1.0.

13. A solid state displacement element according to claim 10, wherein said inorganic layered compound is selected from mica base minerals having at least one of negative electric charge and positive electric charge on a surface of said layered compound.