High reliability electrochemical cell and electrode assembly therefor

• US 5,439,760 A
• Filed: 11/19/1993
• Issued: 08/08/1995
• Est. Priority Date: 11/19/1993
• Status: Expired due to Term

• Current Assignee: Medtronic Incorporated (Medtronic Plc)
• Original Assignee: Medtronic Incorporated (Medtronic Plc)
• Inventors: Berkowitz, Fred J., Howard, William G., Crespi, Ann M., Skarstad, Paul M., Kelm, Roger W., Weiss, Douglas J.
• Primary Examiner(s): Maples, John S.
• Application Number:
  US08/155,410
• Time in Patent Office: 627 Days
• Field of Search: 429/94, 429/194, 429/219, 429/211, 429/217
• US Class Current: 429/94
• CPC Class Codes: H01M 4/02 Electrodes composed of, or comprising, active material
• CPC Class Codes: H01M 4/06 Electrodes for primary cells
• CPC Class Codes: H01M 4/13 Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
• CPC Class Codes: H01M 4/382 Lithium H01M4/405 takes precedence
• CPC Class Codes: H01M 4/405 Alloys based on lithium
• CPC Class Codes: H01M 4/661 Metal or alloys, e.g. alloy coatings H01M4/669 take precedence
• CPC Class Codes: H01M 4/662 Alloys collectors of lead alloys H01M4/685
• CPC Class Codes: H01M 4/74 Meshes or woven material; Expanded metal
• CPC Class Codes: H01M 50/103 prismatic or rectangular H01M50/109, H01M50/11 take precedence
• CPC Class Codes: H01M 50/147 Lids or covers
• CPC Class Codes: H01M 50/531 Electrode connections inside a battery casing
• CPC Class Codes: H01M 50/593 Spacers; Insulating plates
• CPC Class Codes: H01M 6/10 with wound or folded electrodes
• CPC Class Codes: H01M 6/16 with organic electrolyte H01M6/18 takes precedence
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y10T 29/49108 Electric battery cell making

Abstract

An electrochemical cell and electrode assembly in which an alkali metal anode and a cathode assembly are wound together in a unidirectional winding having substantially straight sides such that the winding will fit into a prismatic cell. The anode and cathode are arranged in the winding to provide for even utilization of reactive material during cell discharge by placing cathode and anode material in close proximity throughout the electrode assembly in the proportions in which they are utilized. The winding also contributes to even utilization of reactive material by employing multiple tabs on the cathode assembly to ensure that cathode material is evenly utilized throughout the electrode assembly during cell discharge and also so that connections to the tabs are readily made.

Claims

1. An electrode assembly for an electrochemical cell comprising:

(a) an anode including an elongated strip of alkali metal and a connector tab in electrical contact with the alkali metal on an edge thereof;

(b) a cathode assembly including

(1) a cathode current collector having on an edge thereof a connector tab; and

(2) a cathode material bonded at a uniform density of reactive material to the current collector;

the cathode assembly being shorter than the anode;

the anode and the cathode assembly combined with a separator material therebetween in an elongated, unidirectional winding with two substantially straight sides, the winding having;

(a) at the innermost portion thereof a portion of the anode folded over the end of the cathode assembly such that it is disposed along both sides of the cathode assembly, the folded over portion establishing the length of the straight sides of the winding; and

(b) at the outermost portion thereof, the anode wrapped around the cathode assembly.

2. An electrode assembly according to claim 1 also comprising an anode current collector.

3. An electrode assembly according to claim 2 wherein the anode current collector is bonded on a first side to a length of alkali metal having a uniform thickness and on a second side to a second length of alkali metal having a uniform thickness.

4. An electrode assembly according to claim 2 wherein the anode current collector material is selected from the group consisting of nickel, copper and alloys thereof.

5. An electrode assembly according to claim 1 wherein the cathode current collector material is titanium.

6. An electrode assembly according to claim 1 wherein the cathode material comprises a solid reactive material, a binder material and a conductivity enhancer.

7. An electrode assembly according to claim 6 wherein the solid reactive material is silver vanadium oxide.

8. An electrode assembly according to claim 6 wherein the binder material is PTFE.

9. An electrode assembly according to claim 6 wherein the conductivity enhancer is conductive carbon.

10. An electrode assembly according to claim 1 wherein the separator material covers the anode and is sealed to provide a pouch around the anode, the pouch having an opening through which the connector tab of the anode projects.

11. An electrode assembly according to claim 1 wherein the cathode includes a second connector tab in spaced apart relation from the first connector tab.

12. An electrode assembly according to claim 11 wherein the anode connector tab is spaced apart from the cathode connector tabs in the winding.

13. An electrode assembly according to claim 1 wherein the separator material covers the cathode current collector and cathode material and is sealed to provide a pouch around the cathode assembly;

the pouch having an opening through which the connector tab of the cathode current collector projects.

14. An electrode assembly according to claim 1 wherein the separator material covers the cathode and is sealed to provide a pouch around the cathode and wherein the separator material also covers the anode and is sealed to provide a pouch around the anode;

the separator material of each of the anode and cathode pouches comprising half of the thickness of the separator between the anode and the cathode assembly in the winding.

15. An electrode assembly according to claim 1 wherein the separator material is a microporous polyolefin.

16. An electrode assembly for an electrochemical cell comprising:

(a) an anode including an elongated strip of alkali metal having a first portion with a first uniform thickness of alkali metal and a second portion with a second, lesser uniform thickness of alkali metal, and a connector tab in electrical contact with the alkali metal on an edge thereof;

(b) a cathode assembly including

(1) a cathode current collector having on an edge thereof a first connector tab and a second connector tab, said first and second connector tabs in spaced apart relation; and

(2) a cathode material bonded at a uniform density of reactive material to the current collector;

the cathode assembly being shorter than the anode;

the anode and the cathode assembly combined with a separator material therebetween in an elongated, unidirectional winding with two substantially straight sides, the winding having;

(a) at the innermost portion thereof a portion of the anode including the first portion of the alkali metal strip folded over the end of the cathode assembly such that it is disposed along both sides of the cathode assembly, the folded over portion establishing the length of the straight sides of the winding; and

(b) at the outermost portion thereof, the anode, including the second portion of the alkali metal strip, wrapped around the cathode assembly.

17. An electrode assembly according to claim 16 also comprising an anode current collector.

18. An electrode assembly according to claim 17 wherein the anode current collector is bonded on a first side to a length of alkali metal having a uniform thickness and on a second side to a second, shorter length of alkali metal having a uniform thickness.

19. An electrode assembly according to claim 17 wherein the anode current collector material is selected from the group consisting of nickel, copper and alloys thereof.

20. An electrode assembly according to claim 16 wherein the cathode current collector material is titanium.

21. An electrode assembly according to claim 16 wherein the cathode material comprises a solid reactive material, a binder material and a conductivity enhancer.

22. An electrode assembly according to claim 21 wherein the solid reactive material is silver vanadium oxide.

23. An electrode assembly according to claim 21 wherein the binder material is PTFE.

24. An electrode assembly according to claim 21 wherein the conductivity enhancer is conductive carbon.

25. An electrode assembly according to claim 16 wherein the separator material covers the anode and is sealed to provide a pouch around the anode, the pouch having an opening through which the connector tab of the anode projects.

26. An electrode assembly according to claim 16 wherein the anode includes a second connector tab in spaced apart relation from the first connector tab.

27. An electrode assembly according to claim 26 wherein the anode connector tabs are spaced apart from the cathode connector tabs in the winding.

28. An electrode assembly according to claim 16 wherein the separator material covers the cathode current collector and cathode material and is sealed to provide a pouch around the cathode assembly;

the pouch having a first opening through which the first connector tab of the cathode current collector projects and a second opening through which the second connector tab of the cathode current collector projects.

29. An electrode assembly according to claim 16 wherein the separator material covers the cathode and is sealed to provide a pouch around the cathode and wherein the separator material also covers the anode and is sealed to provide a pouch around the anode;

the separator material of each of the anode and cathode pouches comprising half of the thickness of the separator between the anode and the cathode assembly in the winding.

30. An electrode assembly according to claim 16 wherein the separator material is a microporous polyolefin.

31. An electrode assembly for an electrochemical cell comprising:

(a) an anode assembly including

(1) a first elongated lithium metal element;

(2) a second elongated lithium metal element with a length shorter than that of the first lithium metal element;

(3) an elongated anode current collector having the length of the first alkali metal element bonded on a first side to the first alkali metal element and bonded on a second side to the second, shorter alkali metal element such that a first portion of the current collector includes alkali metal on both sides and a second portion of the current collector includes alkali metal on only one side, the anode current collector having on an edge thereof a connector tab;

(4) separator material covering the first and second alkali metal elements and sealed to provide a pouch around the anode current collector, the pouch having an opening through which the connector tab of the anode current collector projects;

(b) a cathode assembly including

(1) an elongated cathode current collector having on an edge thereof a first connector tab and a second connector tab, said first and second connector tabs in spaced apart relation;

(2) a cathode material bonded at a uniform density to the current collector, the cathode material including as an active material silver vanadium oxide

(3) separator material covering the cathode current collector and sealed to provide a pouch around the current collector, the pouch having a first opening through which the first connector tab of the cathode current collector projects and a second opening through which the second connector tab of the cathode current collector projects;

the cathode assembly being shorter than the anode assembly;

the anode assembly and the cathode assembly joined together in an elongated, unidirectional winding with two straight sides, the winding having;

(a) at the innermost portion thereof a portion of the anode assembly including the first portion of the current collector folded over the end of the cathode assembly such that it is disposed along both sides of the cathode assembly, the folded over portion establishing the length of the straight sides of the winding; and

(b) at the outermost portion thereof, the anode assembly, including the second portion of the current collector with the alkali metal element directed inward encompassing the cathode assembly.

32. An electrode assembly according to claim 31 wherein the anode current collector material is selected from the group consisting of nickel, copper and alloys thereof.

33. An electrode assembly according to claim 31 wherein the cathode current collector material is titanium.

34. An electrode assembly according to claim 31 wherein the cathode material also comprises a binder material and a conductivity enhancer.

35. An electrode assembly according to claim 34 wherein the binder material is PTFE.

36. An electrode assembly according to claim 34 wherein the conductivity enhancer is conductive carbon.

37. An electrode assembly according to claim 31 wherein the anode assembly includes a second connector tab on the anode current collector in spaced apart relation from the first connector tab and a second opening in the anode separator pouch through which the second connector tab projects.

38. An electrode assembly according to claim 37 wherein the anode connector tabs are spaced apart from the cathode connector tabs on the winding.

39. An electrochemical cell comprising:

(a) a case having two parallel, substantially straight sides;

(b) an electrode assembly within the case comprising;

(1) an anode including an elongated strip of alkali metal having a first portion with a first uniform thickness of alkali metal and a second portion with a second, lesser uniform thickness of alkali metal, and a connector tab in electrical contact with the alkali metal on an edge thereof;

(2) a cathode assembly including

(i) a cathode current collector having on an edge thereof a first connector tab and a second connector tab, said first and second connector tabs in spaced apart relation; and

(ii) a cathode material bonded at a uniform density of reactive material to the current collector;

the cathode assembly being shorter than the anode;

the anode and the cathode assembly combined with a separator material therebetween in an elongated, unidirectional winding with two substantially straight sides extending in the same direction as the straight sides of the case, the winding having;

(i) at the innermost portion thereof a portion of the anode including the first portion of the alkali metal strip folded over the end of the cathode assembly such that it is disposed along both sides of the cathode assembly, the folded over portion establishing the length of the straight sides of the winding; and

(ii) at the outermost portion thereof, the anode, including the second portion of the alkali metal strip, wrapped around the cathode assembly;

(c) an organic electrolyte in contact with the electrode assembly.

40. An electrochemical cell according to claim 39 wherein the case comprises an exterior metal shell and on the inside of the metal shell a closely-fitting preform of insulative material.

41. An electrochemical cell according to claim 39 wherein the electrode assembly also comprising an anode current collector.

42. An electrochemical cell according to claim 41 wherein the anode current collector of the electrode assembly is bonded on a first side to a length of alkali metal having a uniform thickness and on a second side to a second, shorter length of alkali metal having a uniform thickness.

43. An electrochemical cell according to claim 41 wherein the anode current collector material of the electrode assembly is selected from the group consisting of nickel, copper and alloys thereof.

44. An electrochemical cell according to claim 39 wherein the cathode current collector material of the electrode assembly is titanium.

45. An electrochemical cell according to claim 39 wherein the cathode material of the electrode assembly comprises a solid reactive material, a binder material and a conductivity enhancer.

46. An electrochemical cell to claim 45 wherein the solid reactive material is silver vanadium oxide.

47. An electrochemical cell according to claim 45 wherein the binder material is PTFE.

48. An electrochemical cell according to claim 45 wherein the conductivity enhancer is conductive carbon.

49. An electrochemical cell according to claim 39 wherein the separator material of the electrode assembly covers the anode and is sealed to provide a pouch around the anode, the pouch having an opening through which the connector tab of the anode projects.

50. An electrochemical cell according to claim 39 wherein the anode of the electrode assembly includes a second connector tab in spaced apart relation from the first connector tab.

51. An electrochemical cell according to claim 50 wherein the anode connector tabs are spaced apart from the cathode connector tabs on the winding.

52. An electrochemical cell according to claim 40 also including a feedthrough attached to the case by an insulative seal and connected to the electrode assembly.

53. An electrochemical cell according to claim 52 wherein the case is metal and the feedthrough is electrically connected with the anode connector tab of the electrode assembly and the two cathode connector tabs are electrically connected with the metal of the case.

54. An electrochemical cell according to claim 39 wherein the case is metal and the feedthrough is electrically connected with both of the cathode connector tabs of the electrode assembly and the anode connector tab is connected with the metal of the case.

55. An electrochemical cell according to claim 39 wherein the separator material covers the cathode current collector and cathode material and is sealed to provide a pouch around the cathode assembly;

the pouch having a first opening through which the first connector tab of the cathode current collector projects and a second opening through which the second connector tab of the cathode current collector projects.

56. An electrochemical cell according to claim 39 wherein the separator material covers the cathode and is sealed to provide a pouch around the cathode and wherein the separator material also covers the anode and is sealed to provide a pouch around the anode;

the separator material of each of the anode and cathode pouches comprising half of the thickness of the separator between the anode and the cathode assembly in the winding.

57. An electrochemical cell according to claim 39 wherein the separator material is a microporous polyolefin.

58. An electrode assembly for an electrochemical cell comprising:

(a) an anode including an elongated strip of alkali metal having a uniform thickness and a connector tab in electrical contact with the alkali metal on an edge thereof;

(b) a cathode assembly including

(1) a cathode current collector having on an edge thereof a first connector tab and a second connector tab, said first and second connector tabs in spaced apart relation; and

(2) a cathode material bonded at a first uniform density of reactive material to a first portion of the cathode current collector and at a second, lesser, uniform density of reactive material to a second portion of the cathode current collector;

the cathode assembly being longer than the anode;

the anode and the cathode assembly combined with a separator material therebetween in an elongated, unidirectional winding with two substantially straight sides, the winding having;

(a) at the innermost portion thereof a portion of the cathode including the first portion of the current collector folded over the end of the anode assembly such that it is disposed along both sides of the anode assembly, the folded over portion establishing the length of the straight sides of the winding; and

(b) at the outermost portion thereof, the cathode, including the second portion of the cathode current collector, is wrapped around the anode assembly.

59. An electrode assembly according to claim 58 also comprising an anode current collector.

60. An electrode assembly according to claim 59 wherein the anode current collector material is selected from the group consisting of nickel, copper and alloys thereof.

61. An electrode assembly according to claim 58 wherein the cathode current collector material is titanium.

62. An electrode assembly according to claim 58 wherein the cathode material comprises a solid reactive material, a binder material and a conductivity enhancer.

63. An electrode assembly according to claim 62 wherein the solid reactive material is silver vanadium oxide.

64. An electrode assembly according to claim 62 wherein the binder material is PTFE.

65. An electrode assembly according to claim 62 wherein the conductivity enhancer is conductive carbon.

66. An electrode assembly according to claim 58 wherein the separator material covers the anode and is sealed to provide a pouch around the anode, the pouch having an opening through which the connector tab of the anode projects.

67. An electrode assembly according to claim 58 wherein the anode includes a second connector tab in spaced apart relation from the first connector tab.

68. An electrode assembly according to claim 67 wherein the anode connector tabs are spaced apart from the cathode connector tabs on the winding.

69. An electrode assembly according to claim 58 wherein the separator material covers the cathode current collector and cathode material and is sealed to provide a pouch around the cathode assembly;

the pouch having a first opening through which the first connector tab of the cathode current collector projects and a second opening through which the second connector tab of the cathode current collector projects.

70. An electrode assembly according to claim 58 wherein the separator material covers the cathode and is sealed to provide a pouch around the cathode and wherein the separator material also covers the anode and is sealed to provide a pouch around the anode;

the separator material of each of the anode and cathode pouches comprising half of the total separator thickness.

71. An electrode assembly according to claim 58 wherein the separator material is microporous polypropylene.