Acrylate coating material

• US 5,440,446 A
• Filed: 10/04/1993
• Issued: 08/08/1995
• Est. Priority Date: 10/04/1993
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: Catalina Coatings Incorporated
• Inventors: Langlois, Marc, Shaw, David G., Dawson, Eric, Cline, Daniel
• Primary Examiner(s): Evans, Geoffrey S.
• Assistant Examiner(s): Mills, Gregory L.
• Application Number:
  US08/131,328
• Time in Patent Office: 673 Days
• Field of Search: 361/272, 361/273, 361/275.1, 361/301.5, 361/303, 361/304, 361/305, 361/308.1, 361/309, 361/311, 361/313, 361/314, 361/321.6, 361/323, 361/327, 428/458, 428/480, 428/483
• US Class Current: 361/301.5
• CPC Class Codes: B05D 1/60 Deposition of organic layers from vapour phase vapour phase deposition in general C23C14/00, C23C16/00
• CPC Class Codes: B05D 3/144 of polymeric substrates
• CPC Class Codes: B65D 1/0215 multilayered B65D81/3837 takes precedence
• CPC Class Codes: H01G 4/20 using combinations of dielectrics from more than one of groups H01G4/02 - H01G4/06 H01G4/12 takes precedence
• CPC Class Codes: H01G 4/206 inorganic and synthetic material
• CPC Class Codes: Y10T 428/31681 Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers

Abstract

Material for winding high voltage capacitors is prepared by evaporating polyfunctional acrylate monomer having a molecular rate in the range of from 150 to 600 and condensing the acrylate as a monomer film on a dielectric substrate. The acrylate is polymerized by irradiation by ultraviolet or electrons. Sometimes both faces of the dielectric are coated to protect the thermoplastic dielectric from swelling when exposed to dielectric liquid. The metallized layer provides an electrode of the capacitor. A polymerized acrylate layer may be applied over the metal layer. Electrical contact can be made to the metal layer by Schooping even though the metallized layer is covered by a layer of acrylate. Low oxygen permeability polypropylene, polyester or nylon sheet has a layer of crosslinked acrylate and an oxygen barrier layer formed of silicon oxide, aluminum oxide or metal. Adhesion is enhanced by plasma or corona treatment of a surface immediately before deposition. Condensation efficiency is also enhanced by chilling the substrate on which the acrylate is condensed.

Claims

1. A wound capacitor comprising:

at least one thermoplastic dielectric sheet wound into a cylinder;

a metallized conductive layer deposited on at least one face of the dielectric sheet;

a layer crosslinked acrylate in direct contact with the metallized layer; and

an electrical contact made to the conductive layer at an end of the cylinder by Schooping.

2. A capacitor as recited in claim 1 wherein the acrylate layer overlies the entire metallized layer.

3. A capacitor as recited in claim 1 comprising a dielectric fluid impregnating the cylinder.

4. A capacitor as recited in claim 1 wherein the first layer of crosslinked acrylate underlies the conductive layer and further comprising a second layer of crosslinked acrylate deposited over the conductive layer.

5. A capacitor as recited in claim 1 further comprising a second layer of crosslinked acrylate deposited on the face of the dielectric sheet opposite to the face having the conductive layer.

6. A wound capacitor comprising;

a polypropylene or polyester dielectric sheet wound into a cylinder;

a layer of crosslinked acrylate deposited on a face of the dielectric sheet, the acrylate layer being formed from acrylate monomer having a molecular weight in the range of from about 150 to 600 and including at least a portion of polyfunctional acrylate molecules for crosslinking;

a metallized conductive layer deposited over the acrylate layer;

a second layer of crosslinked acrylate deposited over the conductive layer; and

a dielectric liquid filling the capacitor.

7. A capacitor as recited in claim 6 wherein an acrylate layer overlies the entire conductive layer.

8. A capacitor as recited in claim 6 wherein the acrylate is formed from acrylate monomer having a molecular weight in the range of from about 200 to 400 and including at least a major portion of polyfunctional acrylate molecules for crosslinking.

9. A capacitor as recited in claim 6 further comprising a third layer of crosslinked acrylate deposited on the face of the dielectric sheet opposite to the face having the conductive layer.

10. Metallized capacitor sheet for forming a wound capacitor comprising:

a thermoplastic polypropylene or polyester dielectric sheet;

a metallized conductive layer deposited on at least one face of the dielectric sheet;

a first layer of polymerized acrylate deposited on the same face of the dielectric sheet as the conductive layer; and

a second layer of polymerized acrylate deposited on the face of the dielectric sheet opposite from the face having a conductive layer for isolating the dielectric sheet, the acrylate layers being formed from acrylate monomer having a molecular weight in the range of from about 150 to 600 and including at least a portion of polyfunctional acrylate molecules for crosslinking.

11. A barrier sheet with low oxygen permeability comprising:

a polypropylene, polyester or nylon sheet substrate;

a first crosslinked evaporated acrylate layer covering one entire face of the substrate, the acrylate layer being a polymerization product of acrylate monomer having a molecular weight in the range of from 150 to 600; and

a layer of oxygen barrier material selected from the group consisting of silicon oxide, aluminum oxide and metal, vapor deposited over the first acrylate layer and covering the entire face of the sheet; and

a second crosslinked evaporated acrylate layer deposited over the oxygen barrier layer, the second acrylate layer also covering the entire face of the sheet and being a polymerization product of acrylate monomer having a molecular weight in the range of from 150 to 600.

12. A sheet as recited in claim 11 wherein the crosslinked acrylate is a polymerization product of acrylate monomer having a molecular weight in the range of from 200 to 400.