Method of cleaning gas cylinders with supercritical fluids

• US 5,440,824 A
• Filed: 09/21/1993
• Issued: 08/15/1995
• Est. Priority Date: 09/21/1993
• Status: Expired due to Fees

• Current Assignee: MG Industries Incorporated
• Original Assignee: MG Industries Incorporated
• Inventors: Boehm, Alfred U., Ramachandran, Sivaramasubramanian
• Primary Examiner(s): ESQUIVEL, DENISE LYNNE
• Application Number:
  US08/124,394
• Time in Patent Office: 693 Days
• Field of Search: 34/443, 34/449, 34/516, 34/521, 134/1, 134/2, 134/10, 134/40, 15/305, 15/363, 15/406, 210/774, 204/157.21, 204/157.42, 204/157.5
• US Class Current: 34/443
• CPC Class Codes: B08B 7/0021 by liquid gases or supercritical fluids
• CPC Class Codes: B08B 9/08 Cleaning containers, e.g. tanks

Abstract

The interior of a gas cylinder is cleaned using a supercritical fluid. A treating material, such as carbon dioxide, is injected into the cylinder, and the pressure in the cylinder is increased until the pressure of the treating material exceeds its critical pressure. Then, the cylinder is heated until the temperature of the treating material exceeds its critical temperature. The treating material therefore becomes a supercritical fluid. The treating material is maintained in its supercritical state while the cylinder is rolled for a period of time, while the supercritical fluid dissolves contaminants on the interior surface of the cylinder, and on objects within the cylinder. Then, the supercritical fluid is vented from the cylinder, preferably while the fluid in the cylinder is maintained in its supercritical state. This process provides exceptionally thorough cleaning of the interior of the cylinder, and makes it possible to provide a cylinder gas having a level of contaminants of the order of parts per billion or better.

Claims

1. Apparatus for cleaning a gas cylinder with a supercritical fluid, the cylinder having an interior region, the apparatus comprising:

a) at least one roller, the roller comprising means for rolling the gas cylinder,

b) means for heating the cylinder, and

c) conduit means for directing a treating material and a topping gas into a manifold, and means for connecting the manifold to the cylinder, wherein the treating material and the topping gas can be directed into the interior region of the cylinder.

2. The apparatus of claim 1, further comprising at least one thermally insulated wall disposed near the cylinder.

3. The apparatus of claim 2, wherein the cylinder has side wall, and wherein there are two thermally insulated walls, the thermally insulated walls being arranged generally parallel to the side wall of the cylinder.

4. The apparatus of claim 1, wherein the cylinder has a dual valve, the dual valve having first and second ports, and wherein the apparatus includes means for directing the treating material into the first port and means for directing the topping gas into the second port.

5. The apparatus of claim 4, wherein there are two manifolds, and wherein the means for directing the treating material includes a first manifold, and wherein the means for directing the topping gas includes the second manifold.