Quasi-bipolar battery requiring no casing

• US 5,441,824 A
• Filed: 12/23/1994
• Issued: 08/15/1995
• Est. Priority Date: 12/23/1994
• Status: Expired due to Term

• Current Assignee: Aerovironment
• Original Assignee: Aerovironment
• Inventors: Rippel, Wally E.
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US08/363,242
• Time in Patent Office: 235 Days
• Field of Search: 429/53-55, 429/149, 429/152, 429/120, 429/174, 429/185, 429/186, 429/210, 429/245, 429/136, 429/139, 429/140
• US Class Current: 429/53
• CPC Class Codes: H01M 10/0413 Large-sized flat cells or batteries for motive or stationary systems with plate-like electrodes
• CPC Class Codes: H01M 10/0468 Compression means for stacks of electrodes and separators
• CPC Class Codes: H01M 10/18 with bipolar electrodes
• CPC Class Codes: H01M 4/74 Meshes or woven material; Expanded metal
• CPC Class Codes: H01M 4/75 Wires, rods or strips
• CPC Class Codes: H01M 50/30 Arrangements for facilitating escape of gases
• CPC Class Codes: H01M 8/0273 with sealing or supporting means in the form of a frame
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y02T 10/70 Energy storage systems for electromobility, e.g. batteries

Abstract

A quasi-bipolar battery is disclosed which has no casing, making it especially suitable for high-voltage, high-current applications where battery weight and cost are considerations. The quasi-bipolar battery is constructed of alternating bipolar plates and separator sheets, each of which has a frame of hard rubber which has been injection-molded thereon. This frame forms a gas-tight seal when these sheets and plates are stacked and compressed together to form the battery. Each biplate is formed with a tube of woven lead yarn which is slipped over a non-conductive biplate during the manufacturing process and prior to the injection-molding of the rubber frame. The injection-molded rubber frames bond beyond to the edges of the biplate and the lead yarn, and thereby prevent electrolyte leakage between cells by migration along the strands of lead yarn. When the battery cell stack is assembled and compressed axially, the compliant rubber frames interface with one another to form the seal and to permit lateral heat transfer. A thermal insulator at each axial and longitudinal end of the battery cell stack prevents axial heat transfer, thereby maintaining all the battery cells at a single, preferred operating temperature that provides maximum efficiency. Venting passages are also formed within the rubber frames to discharge gas buildup, which might occur under certain conditions.

Claims

1. A battery, comprising:

two stack end plates;

a battery cell stack between the two stack end plates, the battery cell stack having a repeating pattern of cell layers stacked along an axis and a terminal associated with each end of the battery cell stack, including

a conductive separator sheet,

a first active material,

a biplate having first and second sides,

a compliant sealing material on the first side of the biplate, and a compliant sealing material on the second side of the biplate, and

a second active material;

wherein each compliant sealing material forms a framed, middle region on the biplate, and each compliant sealing material also forms an engagement between the biplate and at least one of a separator sheet and a stack end plate, each compliant sealing material effective upon compression of the battery cell stack along the axis to form a gas-tight seal and retain gasses and active materials within boundaries associated with the engagement; and

a compression mechanism that axially compresses the battery cell stack to thereby create the gas-tight seals and isolate each cell of the battery cell stack, and thereby retain the active materials of the battery cell stack in a gas-tight, sealed relationship within the battery cell stack.

2. A battery according to claim 1, wherein the battery cell stack includes at least one bipolar battery cell, at least one biplate being electrically conductive and ionically insulative.

3. A battery according to claim 1, wherein the battery cell smack includes at least one quasi-bipolar battery cell, at least one biplate being electrically and ionically insulative.

7. A battery according to claim 1, wherein the layer of compliant sealing material includes injection-molded rubber shaped as a frame, and wherein the battery cell stack includes a plurality of such frames, such that each biplate and each separator sheet is sandwiched between two frames.

8. A battery according to claim 1, wherein the first active material is a lead dioxide material and the second active material is a lead material.

9. A battery according to claim 1, wherein:

the battery cell stack includes a layer of thermal insulation at each axial end; and

the sealing material conducts heat;

whereby cooling of the battery cell stack occurs substantially in a lateral direction, perpendicular to the axis, and substantially does not occur in directions other than the lateral direction.

10. A battery according to claim 1, wherein the compression mechanism includes:

at least two tie-rods extending generally parallel to the axis;

aperture means in a receiving plate at each end of the battery cell stack, for receiving the at least two tie-rods at each end of the battery cell stack;

a tightening device that is selectively actuated to compress the receiving plates at each end of the battery cell stack toward each other, thereby compressing the battery cell stack to create the gas-tight seals and isolate each cell of the battery cell stack, whereby the active materials of the battery cell stack and gasses are retained in a gas-tight, sealed relationship within the battery cell stack.

11. A battery according to claim 1, wherein the repeating pattern of cell layers also includes an electrolyte added to at least one of the first and second active materials.

12. A battery according to claim 1, further comprising a gas pressure relief discharge system having:

a groove in each cell that permits the discharge of gas notwithstanding the gas-tight seal when pressure within the repeating pattern of layers exceeds a predetermined amount;

a venting passage through each biplate layer and separator sheet; and

a pressure relief valve permitting discharge of gas from the battery cell stack when pressure within the repeating pattern of layers exceeds a predetermined amount.

13. A battery according to claim 1, further comprising stack means for discharging gas from the battery cell stack.

4. A battery according to claim 4, wherein:

the battery cell stack is composed of a plurality of quasi-bipolar cells;

the biplate of each layer is electronically and ionically insulative, and further, has edges defining a width and a length of the biplate; and

the repeating pattern of cell layers includes an electrically-conductive material that is placed in contact with each of the first and second sides of the biplate and is folded about at least one of the edges of the substrate sheet, the first active material being placed in contact the electrically-conductive material on the first side of the biplate and the second active material being placed in contact with the electrically-conductive material on the second side of the biplate.

5. A battery according to claim 4, wherein the electrically-conductive material includes a woven sheet of conductive strands folded about at least one of the edges.

6. A battery according to claim 4, wherein the electrically-conductive material includes a plurality of concentric two-layered strands wrapped around at least one of the edges, the strands having a first, core layer composed of a silica material and a second, conductive layer composed of a conductive material.