Chemical heat source comprising metal nitride, metal oxide and carbon

• US 5,443,560 A
• Filed: 12/14/1992
• Issued: 08/22/1995
• Est. Priority Date: 11/29/1989
• Status: Expired due to Term

• Current Assignee: Philip Morris USA Incorporated (Altria Group, Inc.)
• Original Assignee: Philip Morris USA Incorporated (Altria Group, Inc.)
• Inventors: Losee, Bruce D. Jr., Deevi, Seetharama C.
• Primary Examiner(s): Brown, Theatrice
• Application Number:
  US07/990,126
• Time in Patent Office: 981 Days
• Field of Search: 131/359, 131/369, 252/635, 252/640, 44/605, 44/641
• US Class Current: 131/359
• CPC Class Codes: A24B 15/165 comprising as heat source a carbon fuel or an oxidized or thermally degraded carbonaceous fuel, e.g. carbohydrates, cellulosic material
• CPC Class Codes: C09K 5/16 Materials undergoing chemical reactions when used

Abstract

A chemical heat source comprising metal nitride, metal oxide and carbon, particularly useful in smoking articles, and methods of making the heat source are provided. The metal nitride of the heat source has an ignition temperature substantially lower than conventional carbonaceous heat sources, while at the same time provides sufficient heat to release a flavored aerosol from a flavor bed for inhalation by the smoker. Upon combustion the heat source produces virtually no carbon monoxide. The metal nitride is prepared by pre-forming the starting materials into a desired shape, and converting them to metal nitride in situ, without substantially altering the shape of the starting materials.

Claims

1. A method of making metal nitride, comprising the steps of:

a) mixing a metal species and a carbon source to form a mixture;

b) supplying heat to the mixture, wherein the heat is provided by electromagnetic radiation having a frequency in the range from radio frequency to microwave frequency; and

c) contacting the mixture with a nitriding material to form metal nitride.

3. The method of claim 1 or 2, wherein the metal species is an iron species.

4. The method of claim 3, wherein the iron species is selected from the group consisting of Fe₂ O₃, FeOOH, Fe₃ O₄, FeO, or Fe⁰.

5. The method of claim 1 or 2, wherein the carbon source is selected from the group consisting of colloidal graphite and activated carbon.

6. The method of claim 1 or 2, wherein the heat is supplied by a microwave oven.

7. The method of claim 1 or 2, wherein the nitriding material is a nitrogenous gas.

11. The method of claim 1 or 2, wherein the metal species and carbon source are combined in a polar solvent.

12. The method of claim 1 or 2, wherein the metal species is in particulate form having a particle size of up to about 300 microns.

13. The method of claim 1 or 2, wherein the metal species is in particulate form having a particle size of between about submicron and about 20 microns.

14. The method of claim 1 or 2, wherein the metal species has a surface area of between about 0.2 m² /g and about 300 m² /g.

15. The method of claim 1 or 2, wherein the metal species has a surface area of between about 1 m² /g and about 150 m² /g.

16. The method of claim 1 or 2, wherein the carbon source is in particulate form having a particle size of up to about 300 microns.

17. The method of claim 1 or 2, wherein the carbon source is in particulate form having a particle size of between about submicron and about 40 microns.

18. The method of claim 1 or 2, wherein the carbon source has a surface area of between about 0.5 m² /g and about 2000 m² /g.

19. The method of claim 1 or 2, when in the carbon source has a surface area of between about 100 and about 600 m² /g.

2. A method of making a heat source comprising metal nitride, comprising the steps of:

a) mixing a metal species and a carbon source to form a mixture;

b) combining the mixture from step a) with a binder;

c) forming the mixture from step b) into a shape;

d) supplying heat to the mixture, wherein the heat is provided by electromagnetic radiation having a frequency in the range from radio frequencies to microwave frequencies; and

e) contacting the mixture with a nitriding material to form metal nitride.

8. The method of claim 2, wherein the binder comprises a carbonaceous material.

9. The method of claim 2, wherein the carbonaceous material comprises a mixture comprising flour, sugar, and a vegetable oil.

10. The method of claim 2, wherein in step c) the mixture is formed into a cylindrical rod.

20. A method of producing a composite carbon and metal species heat source comprising:

a) mixing a metal oxide and a carbon source;

b) supplying heat to the mixture in an environment which allows the formation of a metal species, wherein the heat is provided by electromagnetic radiation having a frequency in the range from radio frequency to microwave frequency; and

c) cooling.

23. The method of claim 20, 21 or 22, wherein the metal oxide is iron oxide.

24. The method of claim 23 wherein the iron oxide is selected from the group consisting of Fe₂ O₃, Fe₃ O₄, and FeO.

25. The method of claim 20, 21 or 22, wherein the carbon source is selected from the group consisting of colloidal graphite and activated carbon.

26. The method of claim 20, 21 or 22, wherein the heat is supplied by a microwave oven.

21. A method for producing a composite heat source, comprising:

a) mixing a metal oxide and a carbon source;

b) combining the mixture from step a) with a binder;

c) forming the mixture from step b) into a shape;

d) supplying heat to the mixture in an environment which allows for the reduction of the metal species, wherein the heat is provided by electromagnetic radiation having a frequency in the range from radio frequency to microwave frequency; and

e) cooling the shape foraged in step c).

27. The method of claim 21 or 22, wherein the binder comprises carbonaceous materials.

22. A method for producing a composite heat source, comprising:

a) mixing a metal oxide, metal and a carbon source;

b) combining the mixture from step a) with a binder

c) forming the mixture from step b) into a shape;

d) supplying heat to the mixture in an environment which allows for the reduction of the metal species, wherein the heat is provided by electromagnetic radiation having a frequency in the range from radio frequency to microwave frequency; and

e) cooling the shape formed in step c).

28. A process for making a heat source for a smoking article comprising the steps of:

(a) mixing charcoal particles of the desired size with desired additives for a set period of time;

(b) extruding or molding said charcoal and additives into the desired shape; and

(c) heating said extruded material, wherein the heat is provided by electromagnetic radiation having a frequency in the range from radio frequency to microwave frequency.

29. The process of claim 28, wherein the heat is supplied by a microwave oven.

30. A method of producing metal carbide, comprising the steps of:

a. mixing a metal species and a carbon source, wherein the carbon source is selected from the group consisting of colloidal graphite, activated carbon and activated charcoal;

b. supplying heat to the mixture, wherein the heat is provided by electromagnetic radiation having a frequency in the range from radio frequency to microwave frequency; and

c. contacting the mixture with a reducing/carbidizing atmosphere.

32. The method of claims 30 or 31, wherein the metal species is an iron species.

33. The method of claim 32, wherein the iron species is selected from the group consisting of iron oxyhydroxide, Fe₂ O₃, Fe₃ O₄, FeO and mixtures thereof.

34. The method of claim 30 or 31, wherein the carbon source is selected from the group consisting of colloidal graphite and activated carbon.

35. The method of claim 30 or 31, wherein the heat is supplied by a microwave oven.

31. A method of producing a heat source comprising a metal carbide, comprising the steps of:

a. mixing a metal species and a carbon source;

b. combining the mixture from step a) with a binder;

c. forming the mixture from step b) into a shape;

d. supplying heat to the mixture, wherein the heat is provided by electromagnetic radiation having a frequency in the range from radio frequency to microwave frequency; and

e. contacting the mixture with a reducing/carbidizing atmosphere.

36. A method of producing a heat source comprising the steps of:

a. mixing a carbon component, a catalytic precursor, and a binder, wherein the catalytic precursor is a metal species which upon combustion of the heat source forms a catalyst for converting carbon monoxide produced during combustion of the heat source to a benign substance;

b. forming the mixture into a shape; and

d. supplying heat to the mixture, wherein the heat is provided by electromagnetic radiation having a frequency in the range from radio frequency to microwave frequency.

37. The method of claim 36, wherein the metal species is an iron species.

38. The method of claim 36, wherein the metal species is Fe₅ C₂.

39. The method of claim 36, wherein the carbon component is selected from the group consisting of colloidal graphite and activated carbon.

40. The method of claim 36, wherein the heat is supplied by a microwave oven.