Apparatus and method for submerged injection of a feed composition into a molten metal bath

• US 5,443,572 A
• Filed: 12/03/1993
• Issued: 08/22/1995
• Est. Priority Date: 12/03/1993
• Status: Expired due to Fees

• Current Assignee: Quantum Catalytics LLC
• Original Assignee: Molten Metal Technology Incorporated
• Inventors: Nagel, Christopher J., Wilkinson, Mark A.
• Primary Examiner(s): ANDREWS, MELVYN J
• Application Number:
  US08/162,347
• Time in Patent Office: 627 Days
• Field of Search: 266/46, 266/189, 266/225, 588/201, 422/129, 422/184, 422/159, 110/235, 110/237, 110/238
• US Class Current: 266/46
• CPC Class Codes: C21C 5/35 Blowing from above and through the bath
• CPC Class Codes: C21C 5/4613 Refractory coated lances; Immersion lances
• CPC Class Codes: F23G 5/085 High-temperature heating means, e.g. plasma, for partly melting the waste
• CPC Class Codes: F27D 2009/001 the cooling medium being a fluid other than a gas
• CPC Class Codes: F27D 3/18 Charging particulate material using a fluid carrier
• CPC Class Codes: F27D 9/00 Cooling of furnaces or of charges therein F27D1/00, F27D3/00 take precedence

Abstract

A lance for submerged injection of a feed composition, such as a waste, into a molten metal bath includes a perforate refractory tube which extends substantially coaxially about an injection tube. The perforate refractory tube shields the injection tube from the molten metal bath during partial submersion of the lance into the molten metal bath. A perforate support liner extends between the injection tube and the perforate refractory tube and supports the perforate refractory tube. The perforate support liner and the injection tube define an annulus. The method includes conducting a coolant from a coolant source through the annulus to perforations defined by the perforate support liner and the perforate refractory tube, whereby coolant can be directed through the perforations and into the molten metal bath to cause a protective coating of metal to form on the lance. The lance is thereby protected, preserving its structural and chemical integrity during submerged injection of the feed composition through the injection tube into the molten metal bath.

Claims

1. A lance for submerged injection of a feed composition into a molten metal bath, comprising:

a) an injection tube for conducting the feed composition through the lance and into the molten metal bath;

b) a perforate refractory tube, wherein said refractory tube defines the perforations and extends substantially coaxially about the injection tube for shielding the injection tube from the molten metal bath during partial submersion of the lance into the molten metal bath; and

c) a perforate support liner located between the injection tube and the perforate refractory tube and supporting the perforate refractory tube, the perforate support liner and the injection tube defining an annulus for conducting a coolant from a coolant source and through the annulus to perforations defined by the perforate support liner and the perforate refractory tube, whereby coolant can be directed through said perforations and into the molten metal bath, thereby cooling the lance during submerged injection of the feed composition through the injection tube into the molten metal bath.

2. A lance of claim 1 wherein the perforate refractory tube is composed of a porous material.

3. A lance of claim 2 wherein the perforate support liner is composed of a porous metal.

4. A lance of claim 3 further including a hydrocarbon inlet at an unsubmerged end of the injection tube.

5. A lance of claim 4 further including a coolant gas inlet at a top portion of the annulus.

6. A lance of claim 5 further including an oxygen gas inlet at the injection tube and proximate to the hydrocarbon inlet.

7. A lance of claim 6 further including means for heating the feed composition near the inlet of said lance.

8. A lance of claim 7 wherein said means for heating includes an oxyfuel burner.

9. A lance of claim 7 wherein said means for heating includes a plasma torch.

10. A lance of claim 8 further including means for retracting the lance from the molten metal bath.

11. A lance of claim 1 for which the ratio of the outside diameter of the lance to the inside diameter of a reactor for containing the molten metal bath is in the range of between about 0.05 and 0.9.

12. A lance of claim 1 further including a median tube placed within the annulus between the injection tube and the perforate support liner, said median tube extending along at least a substantial portion of the lance and defining a conduit, whereby said coolant is conducted within said conduit adjacent to a substantial portion of the length of the injection tube and then adjacent to the perforate support liner, at least a portion of the coolant being discharged from the conduit through the perforation of the support liner and the perforate refractory tube into the molten metal bath.

13. A method for cooling a lance for submerged injection of a feed composition into a molten metal bath, comprising the steps of:

a) directing the feed composition through an injection tube of the lance into the molten metal bath; and

b) directing a coolant from a coolant source and through an annulus defined by the injection tube and a perforate support liner, said perforate support liner being substantially coaxial to the injection tube and located between the injection tube and a perforate refractory tube and supporting said refractory tube, said perforate refractory tube defining the perforations and shielding the injection tube from the molten metal bath during partial submersion of the lance in the molten metal bath, whereby coolant is directed through perforations of the perforate support liner and the perforate refractory tube, and into the molten metal bath, thereby cooling the lance during submerged injection of the feed composition through the injection tube into the molten metal bath.

14. A method of claim 13 wherein the coolant includes an inert gas.

15. A method of claim 14 wherein the coolant includes a hydrocarbon.

16. A method of claim 14 wherein the coolant includes a gas with entrained liquid droplets.

17. A method of claim 14 wherein an oxidizing agent and hydrocarbon gas are directed with the feed composition into an upper end of said lance, and wherein the feed composition is preheated by reacting the hydrocarbon gas at said upper end.

18. A method of claim 17 wherein the molten metal bath has a temperature in the range of between about 1,300°

and 1,700°

C.

19. A method of claim 18 wherein the feed composition is an organic composition.

20. A method of claim 19 wherein the organic composition includes a hydrocarbon.

21. A method of claim 20 wherein the hydrocarbon includes coal.

22. A method of claim 21 wherein the organic composition is comminuted.

23. In a lance for submerged injection of a feed composition into a molten metal bath, said lance including an injection tube, for conducting the feed composition through the lance and into the molten metal bath, and a perforate refractory tube which extends substantially coaxially about the injection tube for shielding the injection tube from the molten metal bath during partial submersion of the lance into the molten metal bath:

the improvement comprising a perforate support liner between the injection tube and the perforate refractory tube and supporting the refractory tube, the perforate support liner and the injection tube defining an annulus for conducting a coolant from a coolant source and through the annulus to perforations defined by the perforate support liner and the perforate refractory tube, whereby coolant can be directed through said perforations and into the molten metal bath, thereby cooling the lance during submerged injection of the feed composition through the injection tube into the molten metal bath.

24. A lance for submerged injection of a waste composition into a molten metal bath, comprising:

a) means for heating the waste composition proximate to the inlet of the lance;

b) an injection tube for conducting the waste composition through the lance and into the molten metal bath; and

c) a perforate refractory tube which extends substantially coaxially about the injection tube for shielding the injection tube from the molten metal bath during partial submersion of the lance into the molten metal bath and defining between the injection tube and the perforate refractory tube an annulus for conducting a coolant from a coolant source and through the annulus to perforations defined by the perforate refractory tube, whereby coolant can be directed through said perforations and into the molten metal bath, thereby cooling the lance during submerged injection of the waste composition through the injection tube into the molten metal bath.

25. A lance of claim 24 wherein said means for heating includes an oxyfuel burner.

26. A lance of claim 24 wherein said means for heating includes a plasma torch.

27. A method for protecting the structural and chemical integrity of a lance for submerged injection of a hazardous material into a molten metal bath, comprising the steps of:

a) directing the hazardous material through an injection tube of the lance into the molten metal bath; and

b) directing a coolant from a coolant source and through an annulus defined by the injection tube and a perforate support liner, said perforate support liner being substantially coaxial to the injection tube and located between the injection tube and a perforate refractory tube and supporting said perforate refractory tube, said perforate refractory tube shielding the injection tube from the molten metal bath during partial submersion of the lance into the molten metal bath, whereby coolant is directed through perforations which are defined by the perforate support liner and the perforate refractory tube, and into the molten metal bath, thereby protecting the structural and chemical integrity of the lance by forming an accretion on the surface of the partially submerged lance during submerged injection of the hazardous material through the injection tube into the molten metal bath.