Plasma nitrided titanium and titanium alloy products

• US 5,443,663 A
• Filed: 04/29/1994
• Issued: 08/22/1995
• Est. Priority Date: 06/30/1992
• Status: Expired due to Fees

• Current Assignee: Board of Supervisors of Louisiana State University Agricultural & Mechanical College (Louisiana State University System)
• Original Assignee: Board of Supervisors of Louisiana State University Agricultural & Mechanical College (Louisiana State University System)
• Inventors: Meletis, Efstathius
• Primary Examiner(s): Roy, Upendra
• Application Number:
  US08/235,171
• Time in Patent Office: 480 Days
• Field of Search: 148/222, 148/238, 148/537, 427/250, 427/248
• US Class Current: 148/222
• CPC Class Codes: C23C 8/24 Nitriding
• CPC Class Codes: C23C 8/36 using ionised gases, e.g. ionitriding

Abstract

The present invention relates to ion nitriding of pure titanium or titanium-containing alloys at low pressure by intensifying the glow discharge. Plasma intensification was produced by thermionic emission in conjunction with a triode glow discharge system. Effective ion nitriding can be achieved by employing the present invention at relatively low temperatures (480° C.) and with significantly enhanced compound layer growth kinetics compared to the conventional nitriding techniques. Processed Ti and Ti-6Al-4V developed a surface layer of TiN followed by a Ti₂ N layer and an interstitial nitrogen diffusion zone. Processed specimens showed a three fold increase in surface hardness. Surface roughness was found to be a function of the degree of plasma intensification. Processing of Ti-6Al-4V resulted in a higher wear, corrosion and wear-corrosion resistance. The present invention indicates that ion nitriding with intensified glow discharge has a great potential as a surface modification method for Ti and Ti alloys. Materials nitriding by the present invention having the properties defined above are suitable for use as orthopaedic implant devices as well as other applications of titanium and titanium alloys requiring resistance to wear and corrosion.

Claims

1. A product having improved wear and corrosion-resistance characteristics comprising a surface nitrided titanium or titanium-containing alloy having been prepared by an intensified nitriding process, said process comprising plasma nitriding the surface of said product with a plasma nitriding glow discharge source while simultaneously intensifying said glow discharge with a thermionic emission source and maintaining the temperature of said surface at about 300°

C. to about 600°

C.

2. The product according to claim 1 wherein the titanium is essentially pure.

3. The product according to claim 1 wherein the titanium-containing alloy is selected from the group consisting of alloys containing α

, β and

α

-β

phases.

4. The product according to claim 1 having a surface hardness from about 500 to about 1200 HV.

5. The product according to claim 1 having a surface roughness from about 0.2 to about 1.40 μ

m.

6. An orthopaedic implant device comprising the product of claim 1.

7. The product according to claim 3 wherein the titanium-containing alloy is Ti-6-Al-4V.

8. An orthopaedic implant device comprising the product of claim 4.

9. An orthopaedic implant device comprising the product of claim 5.