Pulsing remediation method

• US 5,445,474 A
• Filed: 01/27/1994
• Issued: 08/29/1995
• Est. Priority Date: 01/27/1994
• Status: Expired due to Fees

• Current Assignee: Union Oil Company of California (Chevron Corp.)
• Original Assignee: Union Oil Company of California (Chevron Corp.)
• Inventors: Lundegard, Paul D., Flint, Carl E., Chaffee, Brent F.
• Primary Examiner(s): Taylor, Dennis L.
• Application Number:
  US08/189,152
• Time in Patent Office: 579 Days
• Field of Search: 405/128, 405/129, 405/258, 166/248, 166/267, 175/206, 175/66, 588/249, 588/209, 588/213, 588/216, 588/220, 588/228, 588/234, 588/240, 588/245
• US Class Current: 405/128.45
• CPC Class Codes: B09C 1/002 involving in-situ ground water treatment
• CPC Class Codes: B09C 1/10 microbiologically, biologically or by using enzymes
• CPC Class Codes: B09C 2101/00 In situ
• CPC Class Codes: E21B 43/00 Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells applicable only to water E03B
• CPC Class Codes: E21B 49/00 Testing the nature of borehole walls; Formation testing; Methods or apparatus for obtaining samples of soil or well fluids, specially adapted to earth drilling or wells

Abstract

A process for cyclically operating injection and withdrawal wells penetrating contaminated zones. A high flowrate portion of the cycle time preferably does not exceed a transient response period for in-situ formation fluids to achieve a quasi-steady state conditions. A low flowrate portion of the cycle time limits fluid flowrate which allows in-situ formation fluids to at least partially return to the zone affected by the high flowrate portion of the cycle. The cyclic operation produces improved remediation when compared to continuous operation of wells at similar operating conditions.

Claims

1. A process for bioremediating a contaminated zone by pulsing air into an underground formation containing an in-situ fluid, said process comprising:

drilling and completing a well which penetrates said contaminated zone;

injecting an air pulse through said well into said contaminated zone at a flowrate of at least about 0.25 SCFM for a first period of time lasting no more than 720 hours at a first average air flowrate;

substantially reducing said average air flowrate to a second average air flowrate during a second recovery period of time following said first period, said second recovery period lasting from about 1 to 720 hours; and

injecting another air pulse at a third average air flowrate greater than said second average flowrate into said contaminated zone for a third period of time following said second recovery period, said third period lasting no more than 720 hours.

2. The process of claim 1 wherein said third average air flowrate is substantially the same as said first average air flowrate and said process also comprises the steps of:

withdrawing fluid from said zone through said well during a withdrawal period of time after said third period; and

injecting air at a fourth average air flowrate which is substantially the same as said third average air flowrate for a fourth period of time following said withdrawal period, said fourth period lasting no more than 720 hours.

3. The process of claim 2 wherein said first average air flowrate is less than about 100 SCFM.

4. The process of claim 3 which also comprises:

numerically simulating said process and calculating saturation levels within said underground formation, said numerical simulation allowing calculation of in-situ fluid saturation levels within said underground formation over a calculated period of time; and

calculating a first calculated period of time which does not allow said calculated saturation levels of said in-situ fluid to be reduced below a lower threshold limit at a reference underground location.

5. The process of claim 4 wherein said first period of time is no more than about said first calculated period of time.

6. The process of claim 5 wherein said numerically simulating step uses a finite difference, grid simulation model of said formation and wherein a minimum dimension of each element of said grid is set to be no greater than one meter.

7. The process of claim 6 wherein the instantaneous flowrate does not substantially decline during said first period.

8. The process of claim 7 wherein the instantaneous flowrate generally rises during said first period.

9. The process of claim 8 wherein said first period of time lasts no more than about 72 hours.

10. A process for flowing a remediating fluid within a contaminated underground zone containing an in-situ fluid, said process comprising:

drilling a well which provides a conduit for fluid flow to and from said underground zone;

flowing said remediating fluid into said underground zone at a first average fluid flowrate for a first period of time which is no greater than 2160 hours, wherein at least some of said in-situ fluid is displaced during said first period of time by said remediating fluid; and

substantially reducing said average fluid flowrate to a second average fluid flowrate during a second period of time following said first period, wherein said second period of time is at least 0.5 hours.

11. The process of claim 10 wherein said remediating fluid comprises air and said in-situ fluid is water, and wherein said first and second average flowrates are substantially periodically cycled for at least two cycles and said first period is not equal to said second period.

12. The process of claim 11 wherein said first average flowrate is substantially equal to a mathematical average of instantaneous well flowrates during said first period and said instantaneous well flowrates do not substantially decline during said first period, said process also comprising the steps of:

flowing a fluid through said well at a third average flowrate for a third period of time after said second period of time, wherein said third average flowrate is

substantially larger than said second average flowrate and said third period of time is no more than 720 hours; and

substantially reducing said average flowrate to a fourth average flowrate after said third period.

13. The process of claim 12 which also comprises:

numerically simulating said process and calculating in-situ fluid saturation levels over time at a reference location; and

calculating a first calculated period of time during which a first calculated average flowrate flows into said contaminated zone, wherein said first calculated period does not allow said calculated in-situ fluid saturation level to be reduced to below a lower threshold limit; and

calculating a second calculated quiescent period of time after said first calculated period, wherein said second calculated period allows said calculated in-situ fluid saturation levels to rise significantly.

14. The process of claim 13 wherein said first period is no longer than said first calculated period and said second period is at east as long as said second calculated period.

15. The process of claim 14 wherein said first average flowrate is injected into a plurality of underground zones.

16. The process of claim 15 wherein said numerically simulating step also calculates relative permeabilities at a plurality of locations, said relative permeabilities being dependant upon said calculated in-situ fluid saturation levels.

17. A pulsing process for remediating an underground contaminated zone during a remediation period of time which comprises:

flowing a remediating fluid into said underground zone at a first nominal fluid flowrate during a pulse time period which lasts no longer than 720 hours; and

significantly changing said nominal flowrate at the end of said pulse time period, wherein at least three pulse time periods occur over said remediation period.

18. The process of claim 17 wherein at least 4 pulse periods occur over said remediation period.

19. The process of claim 18 wherein at least 6 pulse periods occur over said remediation period.

20. The process of claim 19 wherein at least 10 pulse periods occur over said remediation period.

21. A process for treating an in-situ fluid with a remediating fluid using a fluid conduit penetrating an underground contaminated zone having a relative permeability to said in-situ fluids, said process comprising:

calculating a transient period during which a first average flowrate of said remediating fluid displaces a portion of said in-situ fluid within said contaminated zone and reduces said relative permeability at a reference location within said contaminated zone, said transient period lasting until said relative permeability essentially stabilizes;

flowing said remediating fluid at about said first average flowrate during a first period which is no greater than about twice said transient period; and

flowing said remediating fluid at a reduced average flowrate during a second period following said first period, wherein said reduced average flowrate allows said relative permeability to increase.

22. An apparatus for treating an in-situ fluid with a remediating fluid within an underground contaminated zone having a relative permeability to said in-situ fluids, said apparatus comprising:

a fluid conduit from a surface location to said underground contaminated zone containing said in-situ fluid;

means for calculating a transient period during which a first average flowrate of said remediating fluid within said contaminated zone displaces a portion of said in-situ fluid and reduces said relative permeability at a reference location within said contaminated zone, said transient period lasting until said relative permeability essentially achieves a steady state condition;

means for flowing said remediating fluid to said underground contaminated zone at about said first average flowrate during a first period;

means for controlling the duration of said first period such that said first period is no more than twice said transient period; and

means for flowing said remediating fluid at a reduced average flowrate after said first period, wherein said reduced average flowrate allows said relative permeability to increase.

23. The apparatus of claim 22 wherein said means for calculating comprises a finite difference, numerical grid simulator.

24. The apparatus of claim 23 wherein said means for flowing said remediating fluid comprises a pump attached to said conduit.

25. The apparatus of claim 24 wherein said means for calculating also comprises an electronic data processing system.

26. In a process of remediating a portion of an underground aquifer by flowing a remediating fluid into said aquifer at a nominal fluid flowrate, the improvement comprising the steps of:

significantly reducing said nominal flowrate over a first quiescent period after a first operating time period which lasts no more than 720 hours, wherein said first quiescent period lasts at least 0.5 hours and said first operating time and said first quiescent period form the first of a pulsing series; and

pulsing said flowrate at least three times.

27. The process of claim 26 wherein the remediating fluid comprises ambient air.