Storable liquid cementitious slurries for cementing oil and gas wells

• US 5,447,197 A
• Filed: 01/25/1994
• Issued: 09/05/1995
• Est. Priority Date: 01/25/1994
• Status: Expired due to Term

• Current Assignee: BJ Services Company
• Original Assignee: BJ Services Company
• Inventors: Rae, Philip, Johnston, Neil
• Primary Examiner(s): Suchfield, George A.
• Application Number:
  US08/186,719
• Time in Patent Office: 588 Days
• Field of Search: 166/285, 166/292, 166/293, 106/728, 106/730, 106/819, 106/823
• US Class Current: 166/293
• CPC Class Codes: C04B 14/102 Attapulgite clay
• CPC Class Codes: C04B 14/104 Bentonite, e.g. montmorillonite
• CPC Class Codes: C04B 2103/0082 Segregation-preventing agents; Sedimentation-preventing agents
• CPC Class Codes: C04B 2103/12 Set accelerators
• CPC Class Codes: C04B 2103/22 Set retarders
• CPC Class Codes: C04B 2103/408 Dispersants
• CPC Class Codes: C04B 2111/00146 Sprayable or pumpable mixtures
• CPC Class Codes: C04B 22/06 Oxides, Hydroxides C04B22/0013 takes precedence
• CPC Class Codes: C04B 24/32 Polyethers, e.g. alkylphenol polyglycolether
• CPC Class Codes: C04B 24/38 Polysaccharides or derivatives thereof C04B24/243 takes precedence
• CPC Class Codes: C04B 28/08 Slag cements
• CPC Class Codes: C04B 40/0032 Controlling the process of mixing, e.g. adding ingredients in a quantity depending on a measured or desired value B28C7/00 takes precedence
• CPC Class Codes: C04B 40/0658 Retarder inhibited mortars activated by the addition of accelerators or retarder-neutralising agents
• CPC Class Codes: C04B 7/02 Portland cement
• CPC Class Codes: C09K 8/46 containing inorganic binders, e.g. Portland cement
• CPC Class Codes: Y10S 106/04 Bentonite

Abstract

In the method of the invention, a storable hydraulically-active cementitious slurry is made and used to cement within subterranean foundations for oil and gas wells. The slurry is made from hydraulically-active, cementitious material suitable for oil field purposes and can be stored until needed. During storage, the slurry remains liquid. The slurry is activated when needed for cementing. After pumping the activated slurry into the wellbore, the set cement has properties acceptable for well cementing.

Claims

1. A method of cementing within a subterranean formation for an oil or gas well, the method comprising the steps of:

formulating a storable, hydraulically-active, cementitious slurry by mixing together a hydraulically-active cementitious material of a type suitable for cementing within subterranean formations for oil and gas wells, a set retarder, a suspending agent and water, wherein the storable slurry'"'"'s set characteristics upon activation are minimally changed after storage;

storing the storable slurry until required for cementing;

activating the storable slurry by mixing together an activator and the storable slurry;

pumping the activated slurry into the subterranean formation;

allowing the activated slurry to set;

wherein the set retarder is present in an effective amount to allow the storage of the slurry with a minimal change of the slurry'"'"'s set characteristics upon activation and to allow the reversal of the retardation after adding an effective amount of an activator to the slurry prior to cementing, the suspending agent maintains the slurry with minimal separation of the cementitious material; and

wherein an effective amount of activating agent is used to overactivate the slurry and an additional set retarder is added to the slurry to achieve the desired setting time.

2. The method of claim 1, wherein the set retarder is selected from the group consisting of:

hydroxycarboxylic acids, glucoheptonates, lignin sulfonates, gluconates, phosphonates, and sugars.

3. The method of claim 1, wherein the suspending agent is selected from the group consisting of:

welan gum, xanthan gum, carboxymethyl cellulose, polyanionic cellulose, carboxymethylhydroxyethyl cellulose, guar, starch, polyethylene oxide and succinoglycan.

4. The method of claim 1, wherein the suspending agent is bentonite or attapulgite.

5. The method of claim 1, wherein the slurry further contains a dispersant.

6. The method of claim 5, wherein the dispersant is selected from the group consisting of:

melamine sulfonic acid polymer, sodium polyacrylate, naphthalene sulfonic acid polymer, and sulfonated-styrene maleic anhydride polymer.

7. The method of claim 1, wherein the activating agent is sodium silicate.

8. A method of cementing within a subterranean formation for an oil or gas well, the method comprising the steps of:

formulating a storable, hydraulically-active, cementitious slurry by mixing together a hydraulically-active cementitious material of a type suitable for cementing within subterranean formations for oil or gas wells, a set retarder, a suspending agent and water, wherein the storable slurry'"'"'s set characteristics minimally change upon activation after storage;

storing the storable slurry until required for cementing;

redispersing slurry particles during storage;

measuring the density of the storable slurry;

activating the storable slurry by mixing together an activator, additional water and the slurry;

adjusting the density of the activated slurry to a desired density;

pumping the density adjusted, activated slurry into the subterranean formation;

allowing the activated slurry to set;

wherein the set retarder is present in an effective amount to allow the storage of the slurry with a minimal change of the slurry'"'"'s set characteristics upon activation after storage and to allow the reversal of the retardation after adding an effective amount of an activator to the slurry prior to cementing,

the suspending agent maintain the slurry with minimal separation of the cementitious material; and

wherein an effective amount of activating agent is used to overactive the slurry and an additional set retarder is added to the slurry to achieve the desired setting time.

9. The method of claim 8, wherein the set retarder is selected from the group consisting of:

hydroxycarboxylic acids, glucoheptonates, lignin sulfonates, gluconates, phosphonates, and sugars.

10. The method of claim 8, wherein the suspending agent is selected from the group consisting of:

welan gum, xanthan gum, carboxymethyl cellulose, polyanionic cellulose, carboxymethylhydroxyethyl cellulose, guar, starch, polyethylene oxide and succinoglycan.

11. The method of claim 8, wherein the suspending agent is bentonite or attapulgite.

12. The method of claim 8, wherein the slurry further contains a dispersant.

13. The method of claim 8, wherein the dispersant is selected from the group consisting of:

melamine sulfonic acid polymer, sodium polyacrylate, naphthalene sulfonic acid polymer, and sulfonated-styrene maleic anhydride polymer.

14. The method of claim 8, wherein the activating agent is sodium silicate.

15. A method of cementing within a subterranean formation for an oil or gas well, the method comprising the steps of:

formulating a stable, hydraulically active, cementitious slurry at a first location by mixing together a hydraulically-active cementitious material of a type suitable for cementing within subterranean formations for oil or gas wells, a set retarder, a suspending agent and water, wherein the slurry'"'"'s set characteristics minimally change upon activation;

.

transferring the formulated slurry to a second location;

activating the pumped stable slurry by mixing together an activator and the transferred stable slurry at the second location;

immediately pumping the activated slurry into the subterranean formation;

allowing the activated slurry to set;

wherein the set retarder is present in an effective amount to allow the storage of the slurry with a minimal change of the slurry'"'"'s set characteristics upon activation and to allow the reversal of the retardation after adding an effective amount of an activator to the slurry prior to cementing,

the suspending agent maintains the slurry with minimal separation of the cementitious material; and

wherein an effective amount of activating agent is used to overactivate the slurry and an additional set retarder is added to the slurry to achieve the desired setting time.

16. A method of cementing within a subterranean formation for an oil or gas well, the method comprising the steps of:

formulating a stable, hydraulically-active, cementitious slurry at a first location by mixing together a hydraulically-active cementitious material of a type suitable for cementing within subterranean formations for oil or gas wells, a set retarder, a suspending agent and water, wherein the slurry'"'"'s set characteristics minimally change upon activation;

measuring the density of the stable slurry;

after measuring the density of the slurry, transferring the formulated slurry to a second location;

storing the transferred stable slurry at the second location;

activating the transferred stable slurry by mixing together an activator, additional water and the slurry and adjusting the density of the activated slurry to a desired density;

immediately pumping the density adjusted, activated slurry into the subterranean formation;

allowing the activated slurry to set;

wherein the set retarder is present in an effective amount to allow the storage of the slurry with a minimal change of the slurry'"'"'s set characteristics upon activation and to allow the reversal of the retardation after adding an effective amount of an activator to the slurry prior to cementing,

the suspending agent maintains the slurry with minimal separation of the cementitious material; and

wherein an effective amount of activating agent is used to overactivate the slurry and an additional set retarder is added to the slurry to achieve the desired setting time.

17. The method of claim 16, wherein the set retarder is selected from the group consisting of:

hydroxycarboxylic acids, glucoheptonates, lignin sulfonates, gluconates, phosphonates, and sugars.

18. The method of claim 16, wherein the suspending agent is selected from the group consisting of:

welan gum, xanthan gum, carboxymethyl cellulose, polyanionic cellulose, carboxymethylhydroxyethyl cellulose, guar, starch, polyethylene oxide and succinoglycan.

19. The method of claim 16, wherein the suspending agent is bentonite or attapulgite.

20. The method of claim 16, wherein the slurry further contains a dispersant.

21. The method of claim 20, wherein the dispersant is selected from the group consisting of:

melamine sulfonic acid polymer, sodium polyacrylate, naphthalene sulfonic acid polymer, and sulfonated-styrene maleic anhydride polymer.

22. The method of claim 16, wherein the activating agent is sodium silicate.