Integrated process for upgrading middle distillate production

• US 5,447,621 A
• Filed: 01/27/1994
• Issued: 09/05/1995
• Est. Priority Date: 01/27/1994
• Status: Expired due to Term

• Current Assignee: MW Kellogg Limited (KBR Incorporated)
• Original Assignee: MW Kellogg Limited (KBR Incorporated)
• Inventors: Hunter, Michael G.
• Primary Examiner(s): Pal, Asok
• Assistant Examiner(s): GRIFFIN, WALTER DEAN
• Application Number:
  US08/187,923
• Time in Patent Office: 586 Days
• Field of Search: 208/58, 208/60, 422/188, 422/190
• US Class Current: 208/58
• CPC Class Codes: C10G 49/22 Separation of effluents
• CPC Class Codes: C10G 65/12 including cracking steps and other hydrotreatment steps

Abstract

An integrated middle distillate upgrading process and unit are disclosed. A middle distillate side-stream of a conventional single stage hydrocracking process is circulated to a hydrotreating stage such as an aromatics saturation reactor and/or a catalytic dewaxing reactor to effect middle distillate upgrade. The upgraded product is then finished in a fractionation stage side-stripper column. The integrated hydrotreating reactor can share the duty of existing hydrocracker stage equipment and take advantage of existing process heat to eliminate the need for much of the equipment generally required by a stand-alone hydrotreating reactor of the prior art.

Claims

1. A process for hydrotreating a petroleum feedstock comprising the steps of:

(a) catalytically hydrocracking a petroleum feedstock in the presence of hydrogen at a pressure ranging from 5 to 21 MPa;

(b) cooling and separating effluent from the hydrocracking step (a) into vapor and liquid streams;

(c) recycling the vapor stream from step (b) to the hydrocracking step (a);

(d) distilling the liquid stream from step (b) in a fractionation column into petroleum distillate streams including first and second middle distillate streams characterized by a bubble point temperature ranging from about 177°

C. to about 357°

C. and an API density at 15°

C. ranging from about 30°

to about 45°

;

(e) catalytically hydrotreating the first middle distillate stream from step (d) in the presence of hydrogen;

(f) separating effluent from the hydrotreatment step (e) into a vapor stream containing hydrogen and a liquid stream essentially free of hydrogen;

(g) recycling the hydrogen-containing vapor stream from step (f) to the hydrocracking step (a); and

(h) steam stripping the liquid stream from step (f) with the second middle distillate stream from step (d), in a side stripping column integrated with the fractionation column in distilling step (d) to return overhead vapor from the side stripping column to the fractionation column, to form an upgraded middle distillate product stream.

2. The process of claim 1 further comprising the steps of:

(i) compressing make-up hydrogen in a first stage of a multistage compressor;

(j) supplying compressed hydrogen from step (i) to the hydrotreatment step (e);

(k) compressing the hydrogen-containing vapor stream from step (f) in a second stage of the multistage compressor for the recycling step (g).

3. The process of claim 2, wherein the separation step (f) comprises:

(1) a primary cooling step for partially condensing liquid from the effluent from the hydrotreatment step (e);

(2) a primary separating step for separating condensate formed from the primary cooling step (1);

(3) a secondary cooling step for condensing additional liquid in remaining vapor from the primary separation step (2); and

(4) a secondary separating step for separating condensate formed from the secondary cooling step (3) to form the hydrogen-containing stream for the second-stage compression step (k).

4. The process of claim 3, wherein said step (j) supplies a first portion of the compressed hydrogen from step (i) to the hydrotreatment step (e), and further comprising a step (l) for discharging a second portion of the compressed hydrogen from step (i) into the effluent from the hydrotreatment step (e) prior to cooling of the resulting mixture in at least the secondary cooling step (f)(3).

5. The process of claim 1, wherein the hydrotreatment step (e) consists of dewaxing, aromatics saturation or a combination thereof.

6. The process of claim 1, wherein the hydrotreatment step (e) is at a pressure from 1 to 10 MPa.

7. The process of claim 1, wherein the distillation step (d) is at a pressure up to 2 MPa.

8. The process of claim 1, comprising heating the middle distillate stream from the fractionation step (d) for feed to the hydrotreatment step (e), by heat exchange in series against the effluents from the hydrotreatment step (e) and the hydrocracking step (a).