Apparatus for purifying a liquid effluent containing pollutants

• US 5,447,629 A
• Filed: 11/18/1993
• Issued: 09/05/1995
• Est. Priority Date: 11/23/1992
• Status: Expired due to Fees

• Current Assignee: Commissariat a L'Energie Atomique (AES Corporation)
• Original Assignee: Commissariat a L'Energie Atomique (AES Corporation)
• Inventors: Gudin, Claude, Chaumont, Daniel, Thepenier, Catherine
• Primary Examiner(s): Silverman, Stanley S.
• Assistant Examiner(s): GREEN, THEODORE
• Application Number:
  US08/153,971
• Time in Patent Office: 656 Days
• Field of Search: 47/1.4, 210/94, 210/96.1, 210/177, 210/197, 210/205, 210/602, 210/606, 210/610, 210/615, 210/616, 210/617, 210/150, 210/151, 435/314, 435/286
• US Class Current: 210/96.1
• CPC Class Codes: C02F 1/30 by irradiation
• CPC Class Codes: C02F 2101/006 Radioactive compounds
• CPC Class Codes: C02F 2101/20 Heavy metals or heavy metal compounds
• CPC Class Codes: C02F 3/06 using submerged filters
• CPC Class Codes: C02F 3/10 Packings; Fillings; Grids packing elements in general B01J19/30, B01J19/32
• CPC Class Codes: C02F 3/32 characterised by the animals or plants used, e.g. algae
• CPC Class Codes: C02F 3/327 characterised by animals and plants
• CPC Class Codes: C12M 21/02 Photobioreactors culturing algae A01G33/00, A01H4/001, C12N1/12
• CPC Class Codes: C12M 23/02 Form or structure of the vessel large containers B65D88/00
• CPC Class Codes: C12M 23/34 Internal compartments or partitions
• CPC Class Codes: C12M 25/14 Scaffolds; Matrices in general C12N5/0068
• CPC Class Codes: C12M 29/02 Percolation
• CPC Class Codes: C12M 31/10 by light emitting elements located inside the reactor, e.g. LED or OLED
• CPC Class Codes: C12M 41/10 Filtering the incident radiation
• CPC Class Codes: C12M 41/26 of pH
• CPC Class Codes: C12M 41/34 of gas
• CPC Class Codes: Y02W 10/10 Biological treatment of water, waste water, or sewage

Abstract

The invention relates to an apparatus for the purification of a liquid effluent containing pollutants, particularly metals and/or radionuclides, as well as to a process for purifying the effluent.

An object of the invention is to provide a continuously functioning purifying apparatus.

This object is achieved with the aid of an apparatus incorporating a confinement enclosure containing a support in which are immobilized living cells of photosynthetic microorganisms. The support is made from a material transparent to light rays. The apparatus also incorporates a mechanism for introducing and circulating the effluent to be treated and a culture medium within the enclosure.

Claims

1. An apparatus for the purification of liquid effluent containing pollutants, particularly metals and/or radionuclides, the apparatus comprising:

a confinement enclosure for receiving cells of microorganisms able to trap the pollutants;

means for introducing the effluent to be treated into said enclosure;

means for circulating said effluent through said enclosure; and

means for sampling the treated, liquid effluent and means for sampling the pollutants;

wherein;

the micro-organism cells are living photosynthetic cells immobilized on a support which at least partly occupies an interior of the enclosure and is traversed by the effluent to be treated, the enclosure comprising walls such that the walls of the enclosure and the support of the cells are made from a material which is transparent to light rays;

the apparatus further comprising;

means for introducing CO₂ into the enclosure;

means for introducing and means for circulating a liquid nutrient culture medium through said support, the circulating means for the effluent and the circulating means for the culture medium incorporating an injector connected to an air reservoir and to a CO₂ reservoir and permitting an injection of air bubbles containing CO₂ into a lower part of the enclosure; and

connected in series, a sensor for measuring a pH within a confinement enclosure, a pH analyzer, a pH regulator and a valve acting on the CO₂ reservoir, so as to control a release of CO₂ within said enclosure.

2. A purifying apparatus according to claim 1, wherein the circulating means for the culture medium and the circulating means of the effluent ensure a displacement of the effluent and the culture medium from a bottom to a top of the support, said support only extends over part of a total height of the enclosure, so as to provide a free lower space and a free upper space within said enclosure, and a well forming an overflow is provided in the support for interconnecting said two free spaces, the culture medium and the effluent overflowing into said well after reaching the upper free space.

3. A purifying apparatus according to claim 2, wherein the well comprises walls, such that the walls of the well are duplicated, so that a circulation of a thermal regulation fluid is possible between the same.

4. A purifying apparatus according to claim 2, wherein at least one tube is placed within the confinement enclosure and completely traverses the enclosure, said tube permitting a passage of light rays from outside the enclosure.

5. A purifying apparatus according to claim 4, wherein a lamp is placed within said tube.

6. A purifying apparatus according to claim 4, wherein a film which makes it possible to select a passage of predetermined wavelengths covers inner walls of the tube.

7. A purifying apparatus according to claim 4, wherein the well forming an overflow is placed in a center of the confinement enclosure, and at least two tubes are uniformly distributed around it.

8. A purifying apparatus according to claim 2, wherein the sampling means for the liquid effluent are connected by a pipe equipped with a pump to the upper free space of the confinement enclosure.

9. A purifying apparatus according to claim 1, wherein the injector connected to the CO₂ reservoir permits the injection of air containing 1 to 10% CO₂.

10. A purifying apparatus according to claim 1, wherein the treated liquid effluent sampling means comprise a pour-over pipe at a top of the confinement enclosure.

11. A purifying apparatus according to claim 1, wherein the support comprises polyurethane foam fragments.

12. A purifying apparatus according to claim 1, wherein the photosynthetic microorganism is a microalgal species, a bacteria or a cell isolated from higher plants.

13. A purifying apparatus according to claim 12, wherein the microalgal species is Porphyridium cruentum and produces an exocellular polysaccharide.