Gas spectroscopy

• US 5,448,071 A
• Filed: 04/16/1993
• Issued: 09/05/1995
• Est. Priority Date: 04/16/1993
• Status: Expired due to Fees

• Current Assignee: Bruce W. Mccaul
• Original Assignee: Bruce W. Mccaul
• Inventors: Doggett, David E., McCaul, Bruce W., Thorson, Eric K.
• Primary Examiner(s): Dzierzynski, Paul M.
• Assistant Examiner(s): HANIG, RICHARD E
• Application Number:
  US08/049,474
• Time in Patent Office: 872 Days
• Field of Search: 250/343, 250/340, 250/341, 250/352, 250/341.1, 356/319
• US Class Current: 250/343
• CPC Class Codes: G01N 2021/399 Diode laser
• CPC Class Codes: G01N 21/274 Calibration, base line adjustment, drift correction
• CPC Class Codes: G01N 21/39 using tunable lasers
• CPC Class Codes: G02B 6/4207 with optical elements reducing the sensitivity to optical feedback anti-reflection devices specially adapted for lasers, see H01S3/0064
• CPC Class Codes: G02B 6/4209 Optical features
• CPC Class Codes: G02B 6/4246 Bidirectionally operating package structures
• CPC Class Codes: H01S 5/0064 Anti-reflection components, e.g. optical isolators
• CPC Class Codes: H01S 5/06216 Pulse modulation or generation

Abstract

A spectroscopy device comprises a laser diode/lens assembly driven by a periodic stepped laser diode drive current. Each period of the stepped laser diode drive current has a plurality of constant current intervals: a left baseline interval, a left skirt interval, a peak interval, a right skirt interval, and a right baseline interval. The left and right skirt constant current intervals are used to lock the laser radiation emitted from the laser diode onto a preselected absorption line. The left and right baseline constant current intervals are used to subtract baseline absorption measurements from peak constant current interval absorption measurements. A high frequency common mode noise rejection circuit rejects noise common to a monitor radiation detector and a radiation detector which detects radiation passing through a sample cell. A serial line locking cell is provided to allow locking when little or no absorbing material is present in the sample cell. A heated sample cell is provided to allow for the measurement of oxygen concentration in human breath. The pressure and temperature of the gas in the sample cell are detected to account for pressure and temperature dependencies of the absorption measurement. Techniques are disclosed for minimizing the effects of unwanted reflections off various surfaces of a spectroscopy device which otherwise would reflect back into the laser diode.

Claims

1. A spectroscopy device, comprising:

a laser diode; and

a circuit which generates a laser diode driving current, said laser diode driving current having a periodic waveform comprising a plurality of constant current intervals, a first current magnitude being generated during one of said constant current intervals of a period, a second current magnitude being generated during another of said constant current intervals of said period, a third current magnitude being generated during another of said constant current intervals of said period, said laser diode driving current being supplied to said laser diode.

2. The spectroscopy device of claim 1, wherein at least one period of said waveform is a stepped waveform comprising substantially only constant current intervals and brief current switching episodes, one of said brief current switching episodes separating each respective two constant current intervals of said period.

3. The spectroscopy device of claim 2, wherein each respective one of said constant current intervals of said stepped waveform of said at least one period represents a greater laser diode driving current than the previous constant current interval of said at least one period.

4. The spectroscopy device of claim 2, wherein each respective one of said constant current intervals of said stepped waveform of said at least one period represents a smaller laser diode driving current than the previous constant current interval of said at least one period.

5. The spectroscopy device of claim 2, wherein said stepped waveform of said at least one period comprises a first sequence of constant current intervals of increasing magnitudes and a second sequence of constant current intervals of decreasing magnitudes.

6. The spectroscopy device of claim 2, wherein said stepped waveform of said at least one period comprises a first sequence of constant current intervals of decreasing magnitudes and a second sequence of constant current intervals of increasing magnitudes.

7. The spectroscopy device of claim 2, wherein a first constant current interval of said at least one period causes said laser diode to generate laser radiation of a first wavelength, and wherein a second constant current interval of said at least one period causes said laser diode to generate laser radiation of a second wavelength, said laser radiation of said first and second wavelengths passing through a material having an electromagnetic radiation absorption line, said electromagnetic radiation absorption line having an absorption line peak wavelength and a absorption line width, an average of said first and second wavelengths substantially equalling said absorption line peak wavelength.

8. The spectroscopy device of claim 7, wherein said first and second wavelengths differ in wavelength by approximately said absorption line width.

9. The spectroscopy device of claim 8, wherein a third constant current interval of said at least one period causes said laser diode to generate laser radiation of a third wavelength, said third wavelength being approximately equal to said absorption line peak wavelength.

10. The spectroscopy device of claim 9, wherein said first wavelength is smaller than said second wavelength, wherein a fourth constant current interval of said at least one period causes said laser diode to generate laser radiation of a fourth wavelength, and wherein a fifth constant current interval of said at least one period causes said laser diode to generate laser radiation of a fifth wavelength, said fourth wavelength being at least several linewidths greater in wavelength than said first wavelength, said fifth wavelength being at least several linewidths smaller in wavelength than said second wavelength.

11. The spectroscopy device of claim 7, further comprising:

a pressure sensor, said circuit adjusting said first current of said first constant current interval and/or said second current of said second constant current interval based on a pressure detected by said pressure sensor.

12. The spectroscopy device of claim 11, wherein said circuit corrects for pressure dependent absorbance effects and determines a concentration of said material in a sample cell.

13. The spectroscopy device of claim 7, further comprising:

a temperature sensor, said circuit controlling a temperature of said material having said electromagnetic radiation absorption line based on a temperature detected by said temperature sensor.

14. The spectroscopy device of claim 13, wherein said temperature sensor is disposed in thermal contact with a wall of a sample cell.

15. The spectroscopy device of claim 13, wherein said circuit corrects for temperature dependent absorbance effects and determines a concentration of said material in a sample cell.

16. The spectroscopy device of claim 1, further comprising:

a thermoelectric cooler in thermal contact with said laser diode; and

said circuit controlling a current flow through said thermoelectric cooler.

17. The spectroscopy device of claim 16, wherein said circuit detects a forward voltage drop across said laser diode.

18. The spectroscopy device of claim 9, said circuit further comprising a detector, said circuit using a current output from said detector during said first and second constant current intervals to center said third wavelength substantially on said absorption line peak wavelength.

19. The spectroscopy device of claim 18, wherein said circuit controls the magnitudes of said laser diode driving current during said first constant current interval and during said second constant current interval such that the currents output from said detector during said first and second constant current intervals are substantially equal.

20. The spectroscopy device of claim 9, wherein said circuit comprises a baseline null integrator.

21. The spectroscopy device of claim 9, wherein said circuit comprises an absorption integrator.

22. An absorption spectroscopy device, comprising:

a laser diode;

a detector; and

means for supplying a periodic laser diode driving current to said laser diode, each period of said periodic laser diode driving current having a first constant current interval, a second constant current interval, and a third constant current interval, a first constant current magnitude being supplied to said laser diode during said first constant current interval, a second constant current magnitude being supplied to said laser diode during said second constant current interval, a third constant current magnitude being supplied to said laser diode during said third constant current interval, said means also being for controlling said first constant current and said second constant current such that a current output by said detector during said first constant current interval substantially equals a current output by said detector during said second constant current interval.

23. The absorption spectroscopy device of claim 22, wherein said third constant current magnitude is greater than said first constant current magnitude and less than said second constant current magnitude.

24. The absorption spectroscopy device of claim 23, wherein said third constant current interval has a longer duration than either said first constant current interval or said second constant current interval.

25. The absorption spectroscopy device of claim 23, wherein said periodic laser diode driving current further comprises a fourth constant current interval and a fifth constant current interval, said laser diode emitting laser radiation of a first wavelength during said first constant current interval, laser radiation of a second wavelength during said second constant current interval, laser radiation of a fourth wavelength during said fourth constant current interval, and laser radiation of a fifth wavelength during said fifth constant current interval, the difference in wavelength between said first and second wavelengths being approximately equal to an absorption line width of a gas through which said laser radiation passes, said fourth wavelength being greater than each of said first, second, and fifth wavelengths by substantially more than said absorption line width, said fifth wavelength being smaller than each of said second, first and fourth wavelengths by substantially more than said absorption line width.

26. The absorption spectroscopy device of claim 25, wherein said absorption line width is a line width of a spectral absorption line of oxygen.

27. A method, comprising:

increasing an accumulated voltage on a node during a sequence of a plurality of constant current intervals until said accumulated voltage exceeds a predetermined voltage, an increase in said accumulated voltage during each interval of said plurality of intervals being indicative of an absorbance of laser radiation absorbed in a sample cell during said interval;

generating a digital value from said accumulated voltage using an analog-to-digital converter after said accumulated voltage exceeds said predetermined voltage; and

zeroing said accumulated voltage after said accumulated voltage exceeds said predetermined voltage.

28. The method of claim 27, wherein said increasing, generating, and zeroing are repeated so that successive zeroings of said accumulated voltage are separated by different numbers of constant current intervals.

29. The method of claim 27, wherein said laser radiation is generated by a laser diode.

30. The method of claim 29, wherein said absorbance is a weak absorbance such as an absorbance of oxygen.

31. An absorption spectroscopy device, comprising:

a sample cell;

a line locking cell;

a beam splitter;

a laser diode which emits laser radiation, a first portion of said laser radiation passing through at least a part of said line locking cell and being reflected off said beam splitter, a second portion of said laser radiation passing through said sample cell without being reflected off said beam splitter; and

a circuit comprising a first detector and a second detector, said circuit supplying a laser diode driving current to said laser diode, said laser diode driving current having a periodic waveform, each period having a stepped waveform comprising substantially only constant current intervals and brief current switching episodes, each period having at least three constant current intervals, each of said three constant current intervals having a different current magnitude.

32. The absorption spectroscopy device of claim 31, wherein said circuit comprises:

a first current path portion comprising said first detector, said first current path portion being coupled to a node;

a second current path portion comprising said second detector, said second current path portion being coupled to said node, said second current path portion having a control terminal which controls a current flow either to or from said node; and

an amplifier circuit having an input lead, said input lead being coupled to said node.

33. The absorption spectroscopy device of claim 32, wherein said circuit further comprises:

a baseline nulling circuit having an output lead, said output lead being coupled to said control terminal of said of said second current path portion.

34. The absorption spectroscopy device of claim 33, wherein said second current path portion comprises:

said second detector;

a first bipolar transistor having a collector coupled to said node, a base coupled being said control terminal, and an emitter coupled to a lead of said second detector; and

a second bipolar transistor having a base, said base being coupled to a collector of said second bipolar transistor, said second bipolar transistor also having an emitter which is coupled to said emitter of said first bipolar transistor.