Fluid depolarized battery with improved automatic valve

• US 5,449,569 A
• Filed: 01/19/1994
• Issued: 09/12/1995
• Est. Priority Date: 05/20/1992
• Status: Expired due to Term

• Current Assignee: Brooke Schumm III, Brooke Schumm Jr, Elizabeth Schumm, Kari J. Schumm
• Original Assignee: Brooke Schumm Jr
• Inventors: Schumm, Brooke Jr.
• Primary Examiner(s): Willis, Jr., Prince
• Assistant Examiner(s): NUZZOLILLO, MARIA
• Application Number:
  US08/183,651
• Time in Patent Office: 601 Days
• Field of Search: 429/27, 429/33, 429/34, 429/39
• US Class Current: 429/402
• CPC Class Codes: F15C 5/00 Manufacture of fluid circuit elements; Manufacture of assemblages of such elements integrated circuits
• CPC Class Codes: H01M 10/05 Accumulators with non-aqueous electrolyte H01M10/39 takes precedence
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 12/06 with one metallic and one gaseous electrode
• CPC Class Codes: H01M 2200/10 Temperature sensitive devices
• CPC Class Codes: H01M 50/119 Metals
• CPC Class Codes: H01M 50/317 Re-sealable arrangements
• CPC Class Codes: H01M 50/375 Vent means sensitive to or responsive to temperature
• CPC Class Codes: H01M 50/583 in response to current, e.g. fuses
• CPC Class Codes: H01M 6/103 Cells with electrode of only one polarity being folded or wound
• CPC Class Codes: H01M 6/16 with organic electrolyte H01M6/18 takes precedence
• CPC Class Codes: H01M 6/50 Methods or arrangements for servicing or maintenance, e.g. for maintaining operating temperature constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

This invention contemplates using semiconductor microactuators as small valves in combination with electric appliances powered by fluid depolarized electrochemical batteries, especially zinc-air cells, or in combination with fluid depolarized electrochemical batteries themselves, all to regulate fluid flow into the batteries. The purpose is to prevent degradation of the batteries when idle, yet permit fluid flow when operating and only when operating. The valves are proposed to be modified to use them as movement devices and valves, using the traditional moving part of the semiconduictor microactuator to move a slide. To increase the area available for fluid flow, the invention proposes to use grids of aperatures for structural integrity, which when the grids are aligned, allows for fluid flow, and when "unaligned" in the normally closed position, block fluid flow. Pressure relief characteristics, corrosion protection, control circuitry, circulation means, and other advantages and methods are also claimed.

Claims

1. A fluid depolarized electrochemical battery having at least one cell comprising:

at least one semiconductor microactuator valve means for being the sole means for admitting depolarizing fluid into said battery, said valve means having a case, two terminals, a closed position, an interior, inlet means for admitting depolarizing gas to said interior, an outlet from said valve means to said battery, slide means for occluding fluid flow disposed to cover said inlet means, and means for flexing upon application of heat to said means for flexing;

said slide means having at least two parallel, juxtaposed grids of apertures and having an open position wherein said grids of apertures are aligned to admit depolarizing fluid and a closed position wherein said grids of apertures are aligned to occlude fluid flow;

means for disposing said at least one valve means on said battery;

said case having one of said grids of apertures of said slide means disposed across and affixed to said inlet means on said case adjacent to said interior;

electrical resistance means for heating said means for flexing;

means for coupling said means for flexing to said other at least one grid of apertures to admit depolarizing fluid in said open position;

means for electrically connecting said electrical resistance means to said two terminals in series with said battery for heating said electrical resistance means, so that upon operation of said battery, said electrical resistance means is heated, causing said means for flexing to flex, causing said other at least one grid of apertures to align with said one of said grids of apertures across said inlet means in said open position, thus admitting depolarizing fluid into said battery.

2. The fluid depolarized electrochemical battery as in claim 1 wherein said at least one valve means acts as a pressure relief valve to allow excess pressure to exit said battery at a predetermined level.

3. The fluid depolarized electrochemical battery as in claim 2 further comprising recharging means for connection to said battery for recharging said battery.

4. The fluid depolarized electrochemical battery as in claim 3 further comprising measurement means and control means responsive to said measurement means for connection to said battery for preventing overcharging of said battery.

5. The fluid depolarized electrochemical battery as in claim 4 further comprising means for insulating a heating element located inside of said at least one valve means from said at least one valve means'"'"' body in order for said heating element to fail if overcurrent flows through said at least one valve means.

6. The fluid depolarized electrochemical battery as in claim 5 further comprising control means having a microprocessor for being connected to said battery in order to optimize said battery'"'"'s performance for a given electrical load.

7. The fluid depolarized electrochemical battery as in claim 6 further comprising fluid circulation means and fluid circulation control means for connection to said battery to circulate fluid through said battery.

8. The fluid depolarized electrochemical battery as in claim 7 wherein said valve means and said actuation means cooperate to cause said battery to cease to operate upon leakage of corrosive fluid from said battery to minimize damage to said electrical device which said battery is powering.

9. A fluid depolarized electrochemical battery having at least one cell comprising:

at least one semiconductor microactuator valve means, said valve means having a closed position, having two terminals, and containing means for occluding fluid flow, said means for occluding fluid flow being made of two juxtaposed parallel grids of apertures;

means for disposing said at least one valve means on said battery as the sole means for admitting depolarizing fluid into said battery;

electrical resistance means on one of said at least two means for occluding fluid flow;

means for electrically connecting said electrical resistance means to said two terminals in series with said at least one battery for heating said electrical resistance means, so that operation of said battery causes said one of said at least two means for occluding fluid flow to flex so that said grids of apertures are no longer juxtaposed which unseals said valve means allowing depolarizing fluid to be admitted into said case through at least one of said grids of apertures.

10. A fluid depolarized electrochemical battery according to claim 9, further comprising:

an additional plate juxtaposed parallel to said means for occluding fluid flow made of two Juxtaposed parallel grids of apertures, said means for occluding fluid flow having one said grid immediately adjacent to said additional plate;

means for connecting said additional plate through said one said grid immediately adjacent to said additional plate to said grid not adjacent to said additional plate;

said at least one semiconductor microactuator valve means containing a liquid and having electrical resistance means for heating said liquid;

means for disposing said liquid within said valve means adjacent to and sealed by said additional plate for heating by said electrical resistance means to cause said liquid to be heated and to expand upon operation of said apparatus, causing said additional plate, through said means for connecting said additional plate, to flex said grid not adjacent to said additional plate so that said grids of apertures are no longer juxtaposed which unseals said valve means allowing depolarizing fluid to be admitted into said battery through said at least one of said grids of apertures.

11. The fluid depolarized electrochemical battery as in claim 10 wherein said at least one valve means acts as a pressure relief valve to allow excess pressure to exit said battery at a predetermined level.

12. The fluid depolarized electrochemical battery as in claim 11 further comprising recharging means for connection to said battery for recharging said battery.

13. The fluid depolarized electrochemical battery as in claim 12 further comprising measurement means and control means responsive to said measurement means for connection to said battery for preventing overcharging of said battery.

14. The fluid depolarized electrochemical battery as in claim 13 further comprising means for insulating a heating element located inside of said at least one valve means from said at least one valve means'"'"' body in order for said heating element to fail if overcurrent flows through said at least one valve means.

15. The fluid depolarized electrochemical battery as in claim 14 further comprising control means having a microprocessor for being connected to said battery in order to optimize said battery'"'"'s performance for a given electrical load.

16. The fluid depolarized electrochemical battery as in claim 15 further comprising fluid circulation means and fluid circulation control means for connection to said battery to circulate fluid through said battery.

17. The fluid depolarized electrochemical battery as in claim 16 wherein said valve means and said actuation means cooperate to cause said battery to cease to operate upon leakage of corrosive fluid from said battery to minimize damage to said electrical device which said battery is powering.

18. A fluid depolarized electrochemical battery comprising:

at least two terminals on a sealed case containing at least one fluid depolarized electrochemical cell with at least one inlet means in said case for funnelling depolarizing fluid into said at least one cell wherein each of said at least one cell has at least two electrodes wherein at least one of said at least two electrodes is an active cathode;

at least one resealable, electrically activated and thermally responsive valve means disposed to allow entry of depolarizing fluid into said at least one cell through said inlet means into said at least one cell'"'"'s interior only when said battery is operating to supply energy to an electrical device which said battery is connected to as a power source, said valve means being comprised of electrical resistance means between two terminals to cause a means for deforming to deform upon application of power to said electrical resistance means, said at least one valve being connected in series to one of said terminals of said battery; and

means for actuating said at least one valve means by closing an electrical circuit which includes said battery to permit entry of depolarizing fluid to said battery.

19. The battery as in claim 18 wherein said at least one valve means acts as a pressure relief valve to allow excess pressure to exit said cell at a predetermined level.

20. The battery as in claim 19 further comprising recharging means for connection to said battery for recharging said battery.

21. The battery as in claims 20 further comprising measurement means and control means responsive to said measurement means for connection to said battery for preventing overcharging of said battery.

22. The battery as in claim 21 further comprising means for insulating a heating element located inside of said at least one valve means from said at least one valve means'"'"' body in order for said heating element to fail if overcurrent flows through said at least one valve means.

23. The battery as in claim 22 further comprising control means having a microprocessor for being connected to said battery in order to optimize said battery'"'"'s performance for a Given electrical load.

24. The battery as in claim 23 further comprising fluid circulation means and fluid circulation control means for connection to said battery to circulate fluid through said battery.

25. The battery as in claim 24 wherein said valve means and said actuation means cooperate to cause said battery to cease to operate upon leakage of corrosive fluid from said battery to minimize damage to said electrical device which said battery is powering.

26. A method of regulating fluid flow into a battery having at least one fluid depolarized electrochemical cell comprising:

positioning within said battery at least one resealable, micromachined, electrically activated and thermally responsive valve means for regulating flow of depolarizing fluid into said battery'"'"'s interior and said cell'"'"'s interior through inlet means in said battery and said cell, respectively, and through said valve means only when said battery is operating to supply energy to an electrical device which said battery is connected to as a power source; and

electrically connecting said at least one valve means to an actuator means for sealing said inlet means in said battery to prevent depolarizing fluid from entering said battery and said at least one cell when said battery is not operating to supply energy to a device to which said battery is connected as a power source.

27. The method as in claim 26, further comprising:

applying a pressure to mechanically or electromechanically open said at least one valve means at a predetermined level.

28. The method as in claim 27, further comprising:

connecting a recharging means to said battery for recharging said cell.

29. The method as in claim 28, further comprising:

connecting measurement means and control means responsive to said measurement means to said battery for preventing overcharging of said cell.

30. The method as in claim 29, further comprising:

connecting shunt resistance means to said at least one valve means.

31. The method as in claim 30, further comprising:

connecting control means having a microprocessor to said battery for optimizing said battery'"'"'s performance under a given electrical load.

32. The method as in claim 31, further comprising:

circulating fluid through said battery via fluid circulation means and fluid circulation control means.

33. The method as in claim 32, further comprising:

disposing an additive oxidizer in said active cathode of said at least one cell of said battery.

34. The method as in claim 33, further comprising:

disposing means for insulating a heating element located inside said at least one valve means from said at least one valve means'"'"' body so that said heating element fails if overcurrent flows through said at least one valve.