Multilayered electrolyte and electrochemical cells using same

• US 5,449,576 A
• Filed: 10/26/1994
• Issued: 09/12/1995
• Est. Priority Date: 11/26/1993
• Status: Expired due to Fees

• Current Assignee: Google Technology Holdings LLC (Alphabet Inc.)
• Original Assignee: Motorola, Inc. (Motorola Solutions, Inc.)
• Inventors: Anani, Anaba A.
• Primary Examiner(s): Kalafut, Stephen
• Assistant Examiner(s): NUZZOLILLO, MARIA
• Application Number:
  US08/329,601
• Time in Patent Office: 321 Days
• Field of Search: 429/191, 429/192, 429/193
• US Class Current: 429/323
• CPC Class Codes: H01M 10/05 Accumulators with non-aqueous electrolyte H01M10/39 takes precedence
• CPC Class Codes: H01M 10/0562 Solid materials
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A thin film multi-layered electrolyte for a rechargeable electrochemical cell, and a rechargeable electrochemical cell including said electrolyte. The multi-layered electrolyte consists of a primary electrolyte material having at least one secondary electrolyte material disposed on one surface thereof. The secondary electrolyte material should be selected so as to have a potential stability window sufficient to prevent decomposition of the primary electrolyte, while preventing chemical reactions leading to the formation of ionically non-conducting materials on the surface of the electrodes of the electrochemical cell. A rechargeable electrochemical cell is made by disposing the multi-layered electrolyte material between a positive and negative electrode.

Claims

1. A multilayer electrolyte for use in an electrochemical cell, comprising a primary electrolyte including polymer substrate and an active ingredient impregnated therein;

and

a secondary electrolyte disposed on at least one side of said primary electrolyte, said secondary electrolyte being fabricated of a lithium ion conducting glass.

2. An electrolyte as defined in claim 1, wherein said lithium ion conducting glass comprises a lithium conducting salt, a glass former, and a glass modifier.

3. An electrolyte as defined in claim 2, wherein said salt is selected from the group of LiI, LiBr, LiCl, LiF, and combinations thereof.

4. An electrolyte as defined in claim 2, wherein said modifier is selected from the group consisting of Li₂ O, Li₂ S, and combinations thereof.

5. An electrolyte as defined in claim 2, wherein said glass former is selected from the group consisting of B₂ S₃, SiS₂, P₂ S₅, B₂ O₃, SiO₂, P₂ O₅, and combinations thereof.

6. An electrolyte as defined in claim 2, further comprising a stabilizing material.

7. An electrolyte as defined in claim 6, wherein said stabilizing material is selected from the group of Al₂ O₃, Al₂ S₃, Ga₂ S₃, and combinations thereof.

8. An electrolyte as defined in claim 1, wherein said lithium ion conducting glass is a ternary combination having the formula LiI+Li₂ S+SiS₂ +B₂ O₃.