Landfill gas treatment system

• US 5,451,249 A
• Filed: 06/14/1994
• Issued: 09/19/1995
• Est. Priority Date: 06/14/1994
• Status: Expired due to Term

• Current Assignee: Doosan Fuel Cell America, Inc. (Doosan Corporation), International Fuel Cells LLC (Rtx Corporation), United States Environmental Protection Agency
• Original Assignee: International Fuel Cells LLC (Rtx Corporation)
• Inventors: Sandelli, Gregory J., Lesieur, Roger R., Healy, Herbert C., Sederquist, Richard A., Trocciola, John C., Spiegel, Ronald J.
• Primary Examiner(s): SPITZER, ROBERT H
• Application Number:
  US08/241,113
• Time in Patent Office: 462 Days
• Field of Search: 96/121, 96/122, 96/126, 96/127, 96/130-137, 96/142-144, 96/146, 55/267-269, 95/90, 95/117-120, 95/135, 95/136, 95/137, 95/148
• US Class Current: 95/117
• CPC Class Codes: B01D 53/75 Multi-step processes
• CPC Class Codes: C10L 3/10 Working-up natural gas or synthetic natural gas
• CPC Class Codes: Y02E 50/30 Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

The gas stream which emanates from landfills is treated to produce a purified gas which is essentially a hydrocarbon such as methane which can be used as the fuel source in a fuel cell power plant, or can be used in other power plants which use natural gas as a fuel. The landfill gas passes through a system which removes essentially all of the hydrogen sulfide; water; organic sulfur and halogen compounds; and solid contaminants from the gas stream. The resultant purified gas stream can be cleanly flared; used to power an energy plant; or put to other useful purposes.

Claims

1. A method for treating a raw landfill gas stream to form a treated methane-based gas which may be used in lieu of natural gas as a fuel gas, said method comprising the steps of:

a) passing said landfill gas stream through a hydrogen sulfide adsorption bed to reduce hydrogen sulfide content of the raw landfill gas stream to about five ppm or less;

b) cooling a resultant gas stream emanating from said adsorption bed to a temperature which is operable to condense water vapor and heavier hydrocarbon fractions in the resultant gas stream;

c) adsorbing condensed water vapor and heavier hydrocarbon fractions from the resultant gas stream to form a dried gas stream;

d) removing hydrocarbon contaminants from the dried gas stream by passing the dried gas stream through an activated carbon bed; and

e) removing contaminant particules from the dried gas stream.

2. The system of claim 1 comprising the step of removing a condensed water fraction from the resultant gas stream, and reducing the dew point of the resultant gas stream to a temperature which is below the freezing point of water.

3. The method of claim 2 wherein said removing and reducing step is performed by passing the resultant gas stream through an activated alumina and/or molecular sieve component in which the condensed water fraction is adsorbed from the resultant gas stream.

4. The method of claim 2 wherein said resultant gas stream is cooled to a temperature in the range of about 0°

F. to about minus 20°

F.

5. A system for treating a raw landfill gas stream to form a treated methane-based gas which may be used in lieu of natural gas as a fuel gas, said system comprising:

a) a hydrogen sulfide adsorption bed for receiving the raw landfill gas stream, said hydrogen sulfide adsorption bed being operable to reduce hydrogen sulfide content of the landfill gas stream to about five ppm or less;

b) a cooler condenser adsorption bed station for receiving an essentially hydrogen sulfide-free gas stream and cooling said hydrogen sulfide-free gas stream to a temperature which is operable to condense and adsorb water vapor and heavier hydrocarbon fractions from the gas stream;

c) an activated carbon bed for receiving an essentially dry gas stream from the cooler condenser adsorption bed station, said carbon bed being operable to remove hydrocarbon contaminants from the gas stream;

d) a particulate filter station for removing contaminant particles from the gas stream; and

e) a gas stream line for transferring the treated gas to a fuel-consumption device which can produce environmentally-clean energy from the treated gas.

6. The system of claim 5 further comprising a parallel hydrocarbon adsorption and removal station for the raw landfill gas stream;

and a line for directing a regeneration portion of the treated gas through said parallel hydrocarbon adsorption and removal station to regenerate activated carbon in said parallel hydrocarbon adsorption and removal station.

7. The system of claim 6 further comprising a combustion station operable to flare a gas stream emitted from said parallel hydrocarbon adsorption and removal station.

8. The system of claim 6 further comprising a parallel dehydration station which provides a second condensed water removal station for the raw landfill gas stream;

and a line for directing said regeneration portion of the treatment gas stream through said parallel dehydration station to regenerate said second condensed water removal station for further gas stream water removal.

9. The system of claim 8 further comprising a combustion station operable to flare a gas stream emitted from said parallel dehydration station.

10. The system of claim 8 further comprising a heater which heats regeneration gas provided to said parallel hydrocarbon adsorption and removal station, and to said parallel dehydration station.

11. The system of claim 5 further comprising a dehydration station operable to remove a condensed water fraction from the gas stream, and to reduce the dew point of the gas stream to a temperature which is below the freezing point of water.

12. The system of claim 11 wherein said dehydration station consists of an activated alumina and/or molecular sieve component in which the condensed water fraction is adsorbed from the gas stream.

13. The system of claim 12 further comprising a cooler station which is adjacent to said dehydration station and through which the gas stream passes, said cooler station operating at a temperature below the freezing point of water.

14. The system of claim 13 wherein said cooler station operates at a temperature in the range of about 0°

F. to about minus 20°

F.