Slide blank, and process for producing a slide therefrom

• US 5,451,478 A
• Filed: 04/12/1994
• Issued: 09/19/1995
• Est. Priority Date: 04/12/1994
• Status: Expired due to Term

• Current Assignee: Intellectual Ventures I LLC (Intellectual Ventures LLC)
• Original Assignee: Polaroid Corporation (PLR IP Holdings LLC)
• Inventors: Telfer, Stephen J., Zuraw, Michael J., Lindholm, Edward P., Conturie, Yves G., Slafer, Warren D., Boggs, Roger A.
• Primary Examiner(s): Bowers, Jr., Charles L.
• Assistant Examiner(s): McPherson, John A.
• Application Number:
  US08/226,657
• Time in Patent Office: 525 Days
• Field of Search: 430/338, 430/332, 430/333, 430/496, 430/11, 430/17, 40/158.1, 40/159.2
• US Class Current: 430/11
• CPC Class Codes: B41M 5/323 Organic colour formers, e.g. leuco dyes
• CPC Class Codes: B41M 5/3275 Fluoran compounds
• CPC Class Codes: B41M 5/38214 Structural details, e.g. multilayer systems composition of individual layers B41M5/42
• CPC Class Codes: B41M 5/465 Infrared radiation-absorbing materials, e.g. dyes, metals, silicates, C black

Abstract

A slide blank comprises a support at least part of which is essentially transparent; an imageable layer superposed on one face of the support, the imageable layer not being substantially photosensitive but comprising a color-forming composition, which, upon imagewise exposure to actinic radiation, forms a colored material, thereby forming in the imageable layer an image which can be viewed in transmission; and a protective layer superposed on the imageable layer on the opposed side thereof from the support, at least part of the protective layer being essentially transparent; the support, imageable layer and protective layer being secured together to form a slide blank having a thickness of at least about 0.8 mm, and the thickness of the protective layer being such that no part of the imageable layer containing the color-forming composition is more than about 0.2 mm from one external surface of the slide blank. This slide blank can be imaged to produce a ready-mounted slide.

Claims

1. A slide blank comprising:

a support at least part of which is essentially transparent;

an imageable layer superposed on one face of the support, the imageable layer not being substantially sensitive to visible radiation but comprising a color-forming composition, which, upon imagewise exposure to actinic radiation, forms a colored material, thereby forming in the imageable layer an image which can be viewed in transmission; and

a protective layer superposed on the imageable layer on the opposed side thereof from the support, at least part of the protective layer being essentially transparent;

the support, imageable layer and protective layer being secured together to form a slide blank having a thickness of at least about 0.8 mm, and the thickness of the protective layer being such that no part of the imageable layer containing the color-forming composition is more than about 0.2 mm from one external surface of the slide blank.

2. A slide blank according to claim 1 wherein the thickness of the protective layer is such that no part of the imageable layer containing the color-forming composition is more than about 0.15 mm from one external surface of the slide blank.

3. A slide blank according to claim 2 wherein the thickness of the protective layer is such that no part of the imageable layer containing the color-forming composition is more than about 0.10 mm from one external surface of the slide blank.

4. A slide blank according to claim 1 wherein the thickness of the protective layer is at least about 10 μ

m.

5. A slide blank according to claim 4 wherein the thickness of the protective layer is at least about 20 μ

m.

6. A slide blank according to claim 1 wherein the support, imageable layer and protective layer are of substantially the same dimensions in the plane of the imageable layer and are secured together so that the protective layer and the imageable layer extend across substantially the whole area of the support.

7. A slide blank according to claim 6 in the form of a flat lamina having two substantially planar major surfaces on opposed sides thereof.

8. A slide blank according to claim 7 in the form of a substantially square lamina having an edge length of from about 40 to about 70 mm and a thickness of from about 0.8 to about 1.7 mm.

9. A slide blank according to claim 8 having a thickness of at least about 1 mm and a protective layer of such thickness that no part of the imageable layer containing the color-forming composition is more than about 0.15 mm from one external surface of the slide blank.

10. A slide blank according to claim 1 wherein the color-forming composition comprises a radiation absorber capable of absorbing actinic radiation and a leuco dye which, upon absorption of radiation by the radiation absorber, forms the colored material.

11. A slide blank according to claim 10 wherein, upon absorption of the actinic radiation, the radiation absorber generates heat within the imageable layer, and the leuco dye undergoes a thermal reaction to form the colored material.

12. A slide blank according to claim 10 wherein the leuco dye comprises any one of:

a. an organic compound capable of undergoing, upon heating, an irreversible unimolecular fragmentation of at least one thermally unstable carbamate moiety, this organic compound initially absorbing radiation in the visible or the non-visible region of the electromagnetic spectrum, the unimolecular fragmentation visibly changing the appearance of the organic compound;

b. a substantially colorless di- or triarylmethane imaging compound possessing within its di- or triarylmethane structure an aryl group substituted in the ortho position to the meso carbon atom with a moiety ring-closed on the meso carbon atom to form a 5- or 6-membered ring, the moiety possessing a nitrogen atom bonded directly to the meso carbon atom and the nitrogen atom being bound to a group with a masked acyl substituent that undergoes fragmentation upon heating to liberate the acyl group for effecting intramolecular acylation of the nitrogen atom to form a new group in the ortho position that cannot bond to the meso carbon atom, whereby the di- or triarylmethane compound is rendered colored;

c. a colored di- or triarylmethane imaging compound possessing within its di- or triarylmethane structure an aryl group substituted in the ortho position to the meso carbon atom with a thermally unstable urea moiety, the urea moiety undergoing a unimolecular fragmentation reaction upon heating to provide a new group in the ortho position that bonds to the meso carbon atom to form a ring having 5 or 6 members, whereby the di- or triarylmethane compound becomes ring-closed and rendered colorless;

d. in combination, a substantially colorless di- or triarylmethane compound possessing on the meso carbon atom within its di- or triarylmethane structure an aryl group substituted in the ortho position with a nucleophilic moiety which is ring-closed on the meso carbon atom, and an electrophilic reagent which upon heating and contacting the di- or triarylmethane compound undergoes a bimolecular nucleophilic substitution reaction with the nucleophilic moiety to form a colored, ring-opened di- or triarylmethane compound;

e. a compound of the formula ##STR12## wherein M'"'"' has the formula;

##STR13## wherein R is alkyl;

--SO₂ R¹ wherein R¹ is alkyl;

phenyl;

naphthyl;

or phenyl substituted with alkyl, alkoxy, halo, trifluoromethyl, cyano, nitro, carboxyl, --CONR² R³ wherein R² and R³ each are hydrogen or alkyl, --CO₂ R⁴ wherein R⁴ is alkyl or phenyl, --COR⁵ wherein R⁵ is amino, alkyl or phenyl, --NR⁶ R⁷ wherein R⁶ and R⁷ each are hydrogen or alkyl, --SO₂ NR⁸ R⁹ wherein R⁸ and R⁹ each are hydrogen, alkyl or benzyl;

Z'"'"' has the formula;

##STR14## wherein R'"'"' is halomethyl or alkyl;

X is --N═

, --SO₂ -- or --CH₂ --;

D taken with X and M'"'"' represents the radical of a color-shifted organic dye;

q is 0 or 1; and

p is a whole number of at least 1;

Z'"'"' being removed from M'"'"' upon the application of heat to effect a visually discernible change in spectral absorption characteristics of the dye;

f. a substantially colorless di- or triarylmethane compound of the formula;

##STR15## wherein ring B represents a carbocyclic aryl ring or a heterocyclic aryl ring;

C₁ represents the meso carbon atom of the di- or triarylmethane compound;

X represents --C(═

O)--;

--SO₂ -- or --CH₂ -- and completes a moiety ring-closed on the meso carbon atom, the moiety including the nitrogen atom bonded directly to the meso carbon atom;

Y represents --NH--C(═

O)--L, wherein L is a leaving group that departs upon thermal fragmentation to unmask --N═

C═

O for effecting intramolecular acylation of the nitrogen atom to open the N-containing ring and form a new group in the ortho position of ring B that cannot bond to the meso carbon atom;

E is hydrogen, an electron-donating group, an electron-withdrawing group or a group, either an electron-donating group or an electron-neutral group that undergoes fragmentation upon heating to liberate an electron-withdrawing group;

s is 0 or 1; and

Z and Z'"'"' taken individually represent the moieties to complete the auxochromic system of a diarylmethane or triarylmethane dye when the N-containing ring is open, and Z and Z'"'"' taken together represent the bridged moieties to complete the auxochromic system of a bridged triarylmethane dye when the N-containing ring is open;

g. a colorless precursor of a preformed image dye substituted with (a) at least one thermally removable protecting group that undergoes fragmentation from the precursor upon heating and (b) at least one leaving group that is irreversibly eliminated from the precursor upon heating, provided that neither the protecting group nor the leaving group is hydrogen, the protecting and leaving groups maintaining the precursor in its colorless form until heat is applied to effect removal of the protecting and leaving groups whereby the colorless precursor is converted to an image dye;

h. mixed carbonate ester of a quinophthalone dye and a tertiary alkanol containing not more than about 9 carbon atoms;

i. a leuco dye represented by;

##STR16## wherein;

E represents a thermally removable leaving group;

tM represents a thermally migratable acyl group;

Q, Q'"'"' and C taken together represent a dye-forming coupler moiety wherein C is the coupling carbon of the coupler moiety;

and, (Y) taken together with N represents an aromatic amino color developer,

one of Q, Q'"'"' and (Y) containing an atom selected from the atoms comprising Group 5A/Group 6A of the Periodic Table, the groups E and tM maintaining the leuco dye in a substantially colorless form until the application of heat causes the group E to be eliminated from the leuco dye and the group tM to migrate from the N atom to the Group 5A/Group 6A atom thereby forming a dye represented by;

##STR17## wherein the dotted lines indicate that the tM group is bonded to the Group 5A/Group 6A atom in one of Q, Q'"'"' and (Y).

13. A slide blank according to claim 10 wherein, upon absorption of the actinic radiation, the radiation absorber generates acid within the imageable layer, and, upon exposure to this acid, the leuco dye forms the colored material.

14. A slide blank according to claim 13 wherein the color-forming composition further comprises a superacid precursor capable of being decomposed, by radiation of a wavelength shorter than that of the actinic radiation absorbed by the radiation absorber, to form a superacid, the superacid precursor, in the absence of the radiation absorber, not being decomposed by the actinic radiation absorbed by the radiation absorber but, in the presence of the radiation absorber and the actinic radiation absorbed by the radiation absorber, decomposing to form a protonated product derived from the radiation absorber, the color-forming composition further comprising a secondary acid generator capable of being thermally decomposed to form a second acid, the thermal decomposition of the secondary acid generator being catalyzed in the presence of the superacid derived from the superacid precursor.

15. A slide blank according to claim 10 having a plurality of imageable layers, each of the imageable layers being capable of generating a different color, each of the imageable layers having a radiation absorber capable of absorbing actinic radiation of a wavelength different from that of the radiation absorbed by the radiation absorber present in each of the other imageable layers.

16. A slide blank according to claim 1 further comprising a mask layer having a substantially transparent central portion and a non-transparent peripheral portion surrounding the central portion, the support, imageable layer and protective layer extending across essentially the entire transparent central portion of the mask layer with the transparent portions of the support and the protective layer being disposed adjacent the transparent central portion of the mask layer.

17. A slide blank according to claim 16 wherein the mask layer is disposed on the opposed side of the support from the imageable layer.

18. A slide blank according to claim 17 wherein the two major surfaces of the mask layer differ in color.

19. A slide comprising:

a support at least part of which is essentially transparent;

an image layer superposed on one face of the support and comprising an imagewise distribution of a colored material forming an image which can be viewed in transmission; and

a protective layer superposed on the image layer on the opposed side thereof from the support, at least part of the protective layer being essentially transparent;

the support, image layer and protective layer being secured together to form a slide having a thickness of at least about 0.8 mm, and the thickness of the protective layer being such that no part of the image layer containing the colored material which forms the image is more than about 0.2 mm from one external surface of the slide.

20. A slide according to claim 19 wherein the thickness of the protective layer is such that no part of the image layer containing the colored material which forms the image is more than about 0.15 mm from one external surface of the slide.

21. A slide according to claim 20 wherein the thickness of the protective layer is such that no part of the image layer containing the colored material which forms the image is more than about 0.10 mm from one external surface of the slide.

22. A slide according to claim 19 wherein the thickness of the protective layer is at least about 10 μ

m.

23. A slide according to claim 22 wherein the thickness of the protective layer is at least about 20 μ

m.

24. A slide according to claim 19 wherein the support, image layer and protective layer are of substantially the same dimensions in the plane of the image layer and are secured together so that the image layer and protective layer extend across substantially the whole area of the support.

25. A slide according to claim 24 in the form of a flat lamina having two substantially planar major surfaces on opposed sides thereof.

26. A slide according to claim 25 in the form of a substantially square lamina having an edge length of from about 40 to about 70 mm and a thickness of from about 0.8 to about 1.7 mm.

27. A slide according to claim 26 having a thickness of at least about 1 mm and wherein the thickness of the protective layer is such that no part of the image layer containing the colored material which forms the image is more than about 0.15 mm from one external surface of the slide.

28. A slide according to claim 19 wherein the image layer comprises a radiation absorber capable of absorbing infra-red radiation having a wavelength in the range of about 700 to about 1200 nm.

29. A slide according to claim 19 further comprising a mask layer having a substantially transparent central portion and a non-transparent peripheral portion surrounding the central portion, the support, image layer and protective layer extending across essentially the entire transparent central portion of the mask layer with the transparent portions of the support and the protective layer being disposed adjacent the transparent central portion of the mask layer.

30. A slide according to claim 29 wherein the mask layer is disposed on the opposed side of the support from the imageable layer.

31. A slide according to claim 29 wherein the two major surfaces of the mask layer differ in color.

32. A slide according to claim 29 wherein the image has a legend portion lying adjacent the peripheral, non-transparent portion of the mask layer so that the legend portion of the image can be viewed in reflection against the mask layer.

33. A process for producing a slide, the process comprising:

providing a slide blank comprising a support at least part of which is essentially transparent;

an imageable layer superposed on one face of the support, the imageable layer not being substantially sensitive to visible radiation but comprising a color-forming composition, which, upon imagewise exposure to actinic radiation, forms a colored material, thereby forming in the imageable layer an image which can be viewed in transmission; and

a protective layer superposed on the imageable layer on the opposed side thereof from the support, at least part of the protective layer being essentially transparent;

the support, imageable layer and protective layer being secured together to form a slide blank having a thickness of at least about 0.8 mm, and the thickness of the protective layer being such that no part of the imageable layer containing the color-forming composition is more than about 0.2 mm from one external surface of the slide blank; and

exposing the slide blank to actinic radiation, and thus forming in the imageable layer an image which can be viewed in transmission, thereby producing a slide.

34. A process according to claim 33 wherein the color-forming composition comprises a radiation absorber capable of absorbing actinic radiation and a leuco dye which, upon absorption of radiation by the radiation absorber, forms the colored material.

35. A process according to claim 34 wherein the slide blank comprises a plurality of color-forming layers, each of these color-forming layers comprising a color-forming composition which, upon exposure to actinic radiation, forms a colored material, each of the color-forming compositions comprising a radiation absorber capable of absorbing actinic radiation, and a leuco dye which, upon absorption of radiation by the radiation absorber, forms the colored material, the leuco dyes in the plurality of color-forming layers forming colored materials having differing colors, and the radiation absorbers in the plurality of color-forming layers absorbing at differing wavelengths, and wherein the formation of the image is effected by exposing the slide blank to actinic radiation having a plurality of wavelengths, thereby forming color in each of the color-forming layers.

36. A process according to claim 33 wherein the slide blank further comprises a mask layer having a substantially transparent central portion and a non-transparent peripheral portion surrounding the central portion, the support, imageable layer and protective layer extending across essentially the entire transparent central portion of the mask layer with the transparent portions of the support and the protective layer being disposed adjacent the transparent central portion of the mask layer.

37. A process according to claim 36 wherein the color-forming layer is disposed between the protective layer and the mask layer and wherein the actinic radiation used to form the image is passed through the protective layer.

38. A process according to claim 36 wherein at least one part of the image formed extends beyond the portion of the imageable layer adjacent the transparent central portion of the mask layer.

39. A process according to claim 38 wherein the image comprises a legend portion lying adjacent the peripheral, non-transparent portion of the mask layer so that the legend portion of the image can be viewed in reflection against the mask layer, the legend portion comprising at least one identifying indicium relating to the portion of the image which can be viewed in transmission through the transparent central portion of the mask layer.

40. A process according to claim 36 wherein at least one portion of the imageable layer adjacent the periphery of the transparent central portion of the mask layer is rendered substantially opaque during formation of the image, so that the image as seen in transmission differs in at least one of size, shape and aspect ratio from the transparent central portion of the mask layer.

41. A process according to claim 33 wherein the slide blank is deformed so that the imageable layer has substantially the form of part of the surface of a cylinder during the exposure to the actinic radiation.