All purpose cleaning composition

• US 5,454,984 A
• Filed: 01/23/1995
• Issued: 10/03/1995
• Est. Priority Date: 04/19/1993
• Status: Expired due to Term

• Current Assignee: Reckitt Benckiser LLC (Reckitt Benckiser Group PLC)
• Original Assignee: Reckitt & Colman Inc. (Reckitt Benckiser Group PLC)
• Inventors: Streit, Allan L., Sachs, Ernest J., Beronio, Carol A., Graubart, Beth T. G.
• Primary Examiner(s): Lieberman, Paul
• Assistant Examiner(s): HARRIMAN, ERIN M
• Application Number:
  US08/376,682
• Time in Patent Office: 253 Days
• Field of Search: 252/547, 252/548, 252/153, 252/174.27, 252/174.22
• US Class Current: 510/384
• CPC Class Codes: C11D 1/523 Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
• CPC Class Codes: C11D 1/526 Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 are polyalkoxylated
• CPC Class Codes: C11D 1/62 Quaternary ammonium compounds
• CPC Class Codes: C11D 1/645 Mixtures of compounds all of which are cationic
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/75 Amino oxides
• CPC Class Codes: C11D 1/835 Mixtures of non-ionic with cationic compounds
• CPC Class Codes: C11D 3/2068 Ethers
• CPC Class Codes: C11D 3/3707 Polyethers, e.g. polyalkyleneoxides

Abstract

A synergistic cleaning composition has been discovered comprising an aqueous solution a quaternary ammonium compound component; a nonionic surfactant component; and a glycol ether solvent. Surprisingly, the combination of the quaternary ammonium compound component, the nonionic surfactant component, and glycol ether solvent provides a synergistic effect where the cleaning composition functions with a low level of quaternary ammonium compound component while still maintaining at least one of the following desirable properties, as follows: an acceptable cleaning efficacy; a low level irritation or toxicity profile; and/or a broad spectrum antimicrobial activity.

Claims

1. A cleaning composition comprising an aqueous solution of about 0.08 to about 1.10 weight percent of a quaternary ammonium compound component;

about 4 to about 8 weight percent of a nonionic surfactant component wherein said nonionic surfactant component is a combination of an alkoxylated alkanolamide, an ethoxylated alcohol, and an alkyl di(lower alkyl) amine oxide in which said alkyl group has from 10 to 20 carbon atoms, wherein said nonionic surfactants are present in a ratio of 1 to about 95 parts ethoxylated alcohol;

from about 98.99 to about 1 parts alkoxylated alkanolamide; and

from about 0.01 to about 4.5 parts amine oxide, based on 100 parts nonionic surfactant; and

about 3.5 to about 10 weight percent of a glycol ether solvent, said weight percentages based on the total weight of the composition.

2. A composition according to claim 1 wherein said nonionic surfactant compounds are present in a ratio of 70 to 90 parts ethoxylated alcohol;

from 29 to 10 parts alkoxylated alkanolamide; and

from 1 to 4 parts amine oxide, based on 100 parts nonionic surfactant.

3. A composition according to claim 2 wherein said alkoxylated alkanolamide is represented by the following formula:

space="preserve" listing-type="equation">R.sub.5 -CO-NH-R.sub.6 -OH

wherein R₅ is a branched or straight chain C₁₂ -C₁₄ alkyl radical, and R₆ is an ethyl radical;

said ethoxylated alcohol is a secondary ethoxylated alcohol, and said amine oxide is an alkyl di(lower alkyl) amine oxide in which the alkyl group has 12-16 carbon atoms, wherein said nonionic surfactants are present in a ratio of 78 to 82 parts secondary ethoxylated alcohol;

from 19 to 15 parts alkoxylated alkanolamide; and

from 3 to 4 parts amine oxide, based on 100 parts nonionic surfactant.

4. A composition according to claim 3 wherein said glycol ether solvent is represented by a structure R₉ -O-R₁₀ -OH, wherein R₉ is an alkoxy of 1 to 20 carbon atoms, or aryloxy of at least 6 carbon atoms, and R₁₀ is an ether condensate of propylene glycol and/or ethylene glycol having from one to ten glycol monomer units, wherein said glycol ether component is present in an amount ranging from 4 to 8 weight percent, based on the total weight of the aqueous composition.

5. A composition according to claim 4 wherein said glycol ether component is selected from the group consisting of ethylene glycol n-butyl ether, diethylene glycol n-butyl ether, and mixtures thereof.

6. A composition according to claim 5 wherein said glycol ether is a diethylene glycol n-butyl ether present in an amount ranging from 4.5 to 8 weight percent, based on the total weight of the aqueous composition.

7. A composition according to claim 6 wherein said quaternary ammonium component is a combination of a dialkyl dimethyl ammonium chloride and an alkyl dimethyl benzyl ammonium chloride.

8. A composition according to claim 7 wherein the ratio of said quaternary ammonium combination is from 30 to 13 dialkyl dimethyl ammonium chloride and from 70 to 87 alkyl dimethyl benzyl ammonium chloride.

9. A composition according to claim 8 wherein said ratio of said quaternary ammonium combination is from 20 to 25 dialkyl dimethyl ammonium chloride and from 80 to 75 alkyl dimethyl benzyl ammonium chloride.

10. A composition according to claim 9 wherein said quaternary ammonium combination is present in an amount ranging from 1.04 to 1.06 weight percent, based on the total weight of the aqueous composition.

11. A composition according to claim 1 wherein said quaternary ammonium compounds component is present in an amount ranging from 1.04 to 1.06 and comprises more than one quaternary ammonium compound.

12. A composition according to claim 1 wherein:

(1) said quaternary ammonium compound comprises;

(a) a dialkyl dimethyl ammonium chloride; and

(b) a alkyl dimethyl benzyl ammonium chloride;

(2) said nonionic surfactant component comprises;

(c) a secondary alcohol ethoxylate;

(d) an alkyl di(lower alkyl) amine oxide in which the alkyl group has 12-16 carbon atoms;

(e) an ethoxylated alkanolamide; and

(3) said glycol ether solvent is

(f) a diethylene glycol monobutyl ether, wherein,

said (a) is present in a range 87 to about 70 parts, based on a total sum of 100 parts of said (a)+(b) and said (b) is present in a range of from 20 to 25 parts, based on a total of 100 parts of said (a) and (b); and

the total weight percent of said (a) and (b) together falls within the range of from 1.04 to 1.06 weight percent, based on the total weight of the aqueous composition;

said (c) is present in a range of from 78 to 82 parts, based on a total sum of 100 parts of said (c)+(d)+(e) and said (d) is present in a range of from 19 to 15 parts, based said sum of (c)+(d)+(e), and said (e) is present in a range of from 3 to 4 parts; and

the total weight percent of said (c)+(d)+(e) together falls within the range of from 6 to 7 weight percent, based on the total weight of the aqueous composition; and

said (f) is present in a range and 4.5 to 5.5 weight percent, based on the total weight of the aqueous composition.

13. A composition according to claim 1 further comprising a fragrance and a dye.