Electrochemical mercerization, souring, and bleaching of textiles

• US 5,456,809 A
• Filed: 02/06/1995
• Issued: 10/10/1995
• Est. Priority Date: 02/06/1995
• Status: Expired due to Term

• Current Assignee: Lawrence Livermore National Security LLC (Government of the United States of America)
• Original Assignee: Regents of the University of California (University of California)
• Inventors: Cooper, John F.
• Primary Examiner(s): Niebling, John
• Assistant Examiner(s): Phasge, Arun S.
• Application Number:
  US08/384,082
• Time in Patent Office: 246 Days
• Field of Search: 204/132, 204/133, 204/84, 204/254, 204/255, 204/256, 204/257, 204/258, 204/263, 204/265, 8/930, 8/931
• US Class Current: 205/689
• CPC Class Codes: C25B 1/30 Peroxides
• CPC Class Codes: D06L 4/50 by irradiation or ozonisation
• CPC Class Codes: D06M 10/06 Inorganic compounds or elements
• CPC Class Codes: D06M 11/40 combined with, or in absence of, mechanical tension, e.g. slack mercerising
• CPC Class Codes: D06M 11/50 with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
• CPC Class Codes: D06M 23/00 Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
• CPC Class Codes: Y10S 8/93 Pretreatment before dyeing
• CPC Class Codes: Y10S 8/931 Washing or bleaching

Abstract

Economical, pollution-free treatment of textiles occurs in a low voltage electrochemical cell that mercerizes (or scours), sours, and optionally bleaches without effluents and without the purchase of bulk caustic, neutralizing acids, or bleaches. The cell produces base in the cathodic chamber for mercerization and an equivalent amount of acid in the anodic chamber for neutralizing the fabric. Gas diffusion electrodes are used for one or both electrodes and may simultaneously generate hydrogen peroxide for bleaching. The preferred configuration is a stack of bipolar electrodes, in which one or both of the anode and cathode are gas diffusion electrodes, and where no hydrogen gas is evolved at the cathode.

Claims

1. A method for mercerizing textile materials, using an electrochemical cell, comprising:

producing a base for mercerization by reducing oxygen at a gas diffusion cathode in a cathodic chamber filled with an electrolyte solution in an electrochemical cell;

producing an acid for neutralization by oxidizing water at an anode in an anodic chamber filled with a second electrolyte solution in the cell;

maintaining separation of the electrolyte solutions in the anodic and cathodic chambers; and

moving a textile material through the cathodic chamber where the material is in contact with the base and then through the anodic chamber where the material is in contact with the acid.

2. The method as recited in claim 1, further comprising:

producing hydrogen peroxide for bleaching or sterilizing the material by reducing oxygen gas at the cathode.

3. The method as recited in claim 1, further comprising:

producing hydrogen peroxide for bleaching or sterilizing the material by oxidizing oxygen gas at the anode.

4. The method as recited in claim 1, further comprising:

producing oxygen gas at the anode.

5. The method as recited in claim 1, wherein the cathode and anode produce substantially equivalent amounts of base and acid, respectively.

6. The method as recited in claim 1, wherein hydrogen gas is not produced at the cathode.

7. An electrochemical cell for mercerizing textile materials, comprising:

a cathode, wherein oxygen is reduced at the cathode to form a base for mercerizing a textile material;

an anode, wherein water is oxidized at the anode to form an acid for neutralizing the material;

wherein at least one of the cathode and anode is a gas diffusion electrode;

a separator situated between the anode and cathode, defining a cathodic chamber bounded by the cathode on one side and the separator on another side, and an anodic chamber bounded by the anode on one side and the separator on another side; and

means for moving the textile material through the cathodic chamber and through the anodic chamber.

8. A cell as recited in claim 7, wherein the cathode comprises a catalyst for producing hydrogen peroxide at the cathode in addition to base.

9. A cell as recited in claim 7, wherein the anode comprises a catalyst for producing hydrogen peroxide at the anode in addition to acid.

10. A cell as recited in claim 7, wherein both the cathode and the anode are gas diffusion electrodes.

11. A cell as recited in claim 7, wherein the cathode and anode are monopolar electrodes.

12. A cell as recited in claim 7, wherein the cathode and anode comprise a bipolar electrode.

13. A cell as recited in claim 12, further comprising a plurality of bipolar electrodes.

14. A cell as recited in claim 12, wherein the anode is an electrolyte-impervious anode.

15. A cell as recited in claim 12, wherein the cathode and anode are gas diffusion electrodes.

16. A cell as recited in claim 7, wherein an electrolyte solution occupies each of the chambers, and wherein the separator is porous or ion-conducting and prevents mixing of the electrolyte solutions between the anodic and cathodic chambers.

17. A cell as recited in claim 16, wherein the means of moving the material comprises rollers that prevent mixing of the electrolyte solutions between the anodic and cathodic chambers.

18. A cell as recited in claim 7, wherein the cell has a required voltage of less than about 1.5 V.